Citation: ZHAO Xing, ZHUANG Quan-Chao, QIU Xiang-Yun, XU Shou-Dong, SHI Yue-Li, CUI Yong-Li. Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1666-1672. doi: 10.3866/PKU.WHXB20110715 shu

Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries

1.
Li-ion Batteries Laboratory, School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, P. R. China

Received Date: 24 February 2011
Available Online: 23 May 2011
Fund Project: 中央高校基本科研业务费专项资金(2010LKHX03、2010QNB04、2010QNB05) (2010LKHX03、2010QNB04、2010QNB05)中国矿业大学科技攀登计划(ON090237)资助项目 (ON090237)

The Cr₂O₃/TiO₂ composite material was prepared by a high-temperature solid-state reaction and its structure, morphology, and electrochemical performance were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), charge-discharge test, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). We found that TiO₂ doping significantly improved the cyclic performance of Cr₂O₃ and the reversible capacity of the Cr₂O₃/TiO₂ composite material was 454 mAh·g^-1 after 22 charge-discharge cycles, therefore, it has a capacity retention of 73.6% and this is mainly due to TiO₂ doping that significantly increases the conductivity of Cr₂O₃. Our results revealed that the initial large irreversible capacity and the capacity fading could be attributed to an increase in the thickness of the solid electrolyte interface (SEI) film and a reduction in the conductivity of the materials. This was caused by a volume expansion of the Cr₂O₃/TiO₂ electrode during the first discharge process.
- Lithium ion battery,
- Cr₂O₃/TiO₂ composite material,
- Conversion reaction,
- Conductivity,
- Solid electrolyte interface film
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沈阳化工大学材料科学与工程学院沈阳 110142

Electrochemical Performance of Cr2O3/TiO2 Composite Material for Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Cr₂O₃/TiO₂ Composite Material for Lithium Ion Batteries