Citation: CHEN Lang, RAO Mu-Min, LI Wei-Shan, XU Meng-Qing, LIAO You-Hao, TAN Chun-Lin, YI Jin. Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1689-1694. doi: 10.3866/PKU.WHXB20110712 shu

Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent

CHEN Lang ¹ ,
RAO Mu-Min ¹ ,
LI Wei-Shan ^1,2,3, ,
XU Meng-Qing ^1,2,3 ,
LIAO You-Hao ¹ ,
TAN Chun-Lin ^1,2,3 ,
YI Jin ¹

1.
1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006, P. R. China;
2. Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, South China Normal University, Guangzhou 510006, P. R. China;
3. Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (MOE), South China Normal University, Guangzhou 510006, P. R. China

Received Date: 18 January 2011
Available Online: 20 May 2011
Fund Project: 国家自然科学基金(20873046) (20873046)广东省自然科学基金(10351063101000001)资助项目 (10351063101000001)

Poly(acrylonitrile-methyl methacrylate-styrene) (PAMS) was synthesized by emulsion polymerization and a polyethylene (PE)-supported membrane was prepared using urea as foaming agent (PE-PAMS-U). The structure and performance of the PAMS copolymer, PE-PAMS-U membrane and corresponding gel polymer electrolyte (GPE) were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetry (TG), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS) and by a charge/discharge test. We found that the performance of the PE-PAMS-U based GPE could be improved when using urea as a foaming agent. With the use of urea the pore size of the membrane becomes uniform, the ionic conductivity of the GPE improves from 1.1×10^-3 to 2.15×10^-3 S·cm^-1 at room temperature and the interfacial resistance between the GPE and lithium is reduced from 480 to 250 Ω·cm². The GPE is stable up to 5.0 V (vs Li/Li⁺) at room temperature and the battery made using the Li/PE-supported GPE/LiCoO₂ shows a od rate and od cycle performance.
- Lithium ion battery,
- Gel polymer electrolyte,
- Poly((acrylonitrile-methyl methacrylate-styrene),
- Urea,
- Foaming agent
1. [1]
  
  (1) Liao, Y. H.; Zhou, D. Y.; Rao, M. M.; Li,W. S.; Cai, Z. P.; Liang, Y.; Tan, C. L. J. Power Sources 2009, 189, 139.
2. [2]
  (2) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359.
3. [3]
  (3) Subba, C. V. R.;Wu, G. P.; Zhao, C. X.; Zhu, Q. Y.; Chen,W.; Kalluru Rajamohan, R. J. Non-Cryst. Solids 2007, 353, 440.
4. [4]
  (4) Sundaram, N. T. K.; Subramania, A. J. Membr. Sci. 2007, 289, 1.
5. [5]
  (5) Zuo, X. X.; Xu, M. Q.; Li,W. S.; Su, D. G.; Liu, J. S. Electrochem. Solid-State Lett. 2006, 9, A196.
6. [6]
  (6) Jeon, J. D.; Kim, M. J.; Kwak, S. Y. J. Power Sources 2006, 162, 1304.
7. [7]
  (7) Xie, H.; Tang, Z. Y.; Li, Z. Y.; He, Y. B.; Liu, Y.;Wang, H. J. Solid State Electrochem. 2008, 12, 1497.
8. [8]
  (8) Chen-Yang, Y.W.; Chen, H. C.; Lin, F. J.; Chen, C. C. Solid State Ionics 2002, 150, 327.
9. [9]
  (9) Pu,W. H.; He, X. M.;Wang, L.; Tian, Z.; Jiang, C. Y.;Wan, C. R. J. Membr. Sci. 2006, 280, 6.
10. [10]
  (10) Zhang, G. Q.; Ma, L.;Wu, Z. J.; Zhang, H. Y.; Ni, P. Acta Phys. -Chim. Sin. 2009, 25, 555. [张国庆, 马莉, 吴忠杰, 张海燕, 倪佩. 物理化学学报, 2009, 25, 555.]
11. [11]
  (11) Ahmad, A.; Rahman, M. Y. A.; Su'ait, M. S. Physica B 2008, 403, 4128.
12. [12]
  (12) Reddy, C. V. S.; Zhu, Q. Y.; Mai, L. Q.; Chen,W. J. Solid State Electrochem. 2007, 11, 543.
13. [13]
  (13) Stephan, A. M.; Nahm, K. S. Polymer 2006, 47, 5952.
14. [14]
  (14) Kim, D.W.; Oh, B.; Park, J. H.; Sun, Y. K. Solid State Ionics 2000, 138, 41.
15. [15]
  (15) Song, M. K.; Kim, Y. T.; Cho, J. Y.; Cho, B.W.; Popov, B. N.; Rhee, H.W. J. Power Sources 2004, 125, 10.
16. [16]
  (16) Rao, M. M.; Liu, J. S.; Li,W. S.; Liao, Y. H.; Liang, Y.; Zhao, L. Z. J. Solid State Electrochem. 2010, 14, 255.
17. [17]
  (17) Liao, Y. H.; Rao, M. M.; Li,W. S.; Tan, C. L.; Yi, J.; Chen, L. Electrochim. Acta 2009, 54, 6396.
18. [18]
  (18) Liao, Y. H.; Rao, M. M.; Li,W. S.; Yang, L. T.; Zhu, B. K.; Xu, R.; Fu, C. H. J. Membr. Sci. 2010, 352, 95.
19. [19]
  (19) Li, Z. H.; Cheng, C.; Zhan, X. Y.;Wu, Y. P.; Zhou, X. D. Electrochim. Acta 2009, 54, 4403.
20. [20]
  (20) Rao, M. M.; Liu, J. S.; Li,W. S.; Liang, Y.; Zhou, D. Y. J. Membr. Sci. 2008, 322, 314.
21. [21]
  (21) Liang, Y. H.;Wang, C. C.; Chen, C. Y. J. Power Sources 2005, 148, 55.
22. [22]
  (22) Wang, Z. L.; Tang, Z. Y. Electrochim. Acta 2004, 49, 1063.
23. [23]
  (23) Yang, M. J.; Li,W. L.;Wang, G. G.; Zhang, J. Q. Solid State Ionics 2005, 176, 2829.
24. [24]
  (24) Liu, H. R.; Du, J. H. Solid State Sci. 2006, 8, 526.
25. [25]
  (25) Zhang, H. P.; Zhang, P.; Li, Z. H.; Sun, M.;Wu, Y. P.;Wu, H. Q. Electrochem. Commun. 2007, 9, 1700.
26. [26]
  (26) Yang, C. C. Mater. Lett. 2004, 58, 33.
27. [27]
  (27) Miao, R. Y.; Liu, B.W.; Zhu, Z. Z.; Liu, Y.; Li, J. L.;Wang, X. D.; Li, F. Q. J. Power Sources 2008, 184, 420.
28. [28]
  (28) Nookala, M.; Kumar, B.; Rodrigues, S. J. Power Sources 2002, 111, 165.
29. [29]
  (29) Lee, Y. G.; Park, J. K.; Moon, S. I. Electrochim. Acta 2000, 46, 533.
30. [30]
  (30) Chaix, N.; Alloin, F.; Bélières, J. P.; Saunier, J.; Sanchez, J. Y. Electrochim. Acta 2002, 47, 1327.
31. [31]
  (31) Rao, M. M.; Liu, J. S.; Li,W. S.; Liang, Y.; Liao, Y. H.; Zhao, L. Z. J. Power Sources 2009, 189, 711.
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