Citation: MAI Li-Qiang, YANG Shuang, HAN Chun-Hua, XU Lin, XU Xu, PI Yu-Qiang. Chemical Lithiation and Electroactivity of Nanomaterials[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1551-1559. doi: 10.3866/PKU.WHXB20110710 shu

Chemical Lithiation and Electroactivity of Nanomaterials

MAI Li-Qiang ^1,2, ,
YANG Shuang ¹ ,
HAN Chun-Hua ¹ ,
XU Lin ¹ ,
XU Xu ¹ ,
PI Yu-Qiang ¹

1.
1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, WUT-Harvard Joint Nano Key Laboratory, Wuhan University of Technology, Wuhan 430070, P. R. China;
2. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA

Received Date: 9 February 2011
Available Online: 19 May 2011
Fund Project: 国家自然科学基金(50702039, 51072153) (50702039, 51072153) 教育部新世纪优秀人才计划(NCET-10-0661) (NCET-10-0661)中央高校基本科研业务费专项基金(2010-II-016)资助 (2010-II-016)

High capacity and od cycling stability of the electrode materials are the key points to develop high-performance lithium ion battery. Based on the latest research over the world, especilly from our group, in this paper we summarized the progress in chemical lithiation and electroactivity of nanomaterials. Firstly, we introduced the preparation of high capacity nanomaterials (molybdenum oxide, vanadium oxides, selenium hydrates, etc) and the chemical problems in lithiation process. Then we summed up the progress in assembly, chemical lithiation and electroactivity of single nanowire devices and nanowire lithium ion battery. Finally, we pointed out that assembly of single nanowire (nanobelts, nanotubes, etc.) device, in situ probe of lithium ion transport, design and construction of ordered array and complex structure, investigation of lithiation mechanism, electrostatic coupling, interface interaction, etc. are effective methods to deeper exploration of the relationship between chemical lithiation and electroactivity of nanomaterials and main directions of nanoscale lithium ion battery research field.
- Lithium ion battery,
- Electrochemistry,
- Nanomaterials,
- Chemical lithiation,
- Nanodevice
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