Citation: ZHANG Zi-Yu, HU Zhong-Ai, YANG Yu-Ying, WANG Huan-Wen, CHANG Yan-Qin, CHEN Yan-Li, LEI Zi-Qiang. Ce-Doped Mn₃O₄ and Its Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1673-1678. doi: 10.3866/PKU.WHXB20110709 shu

Ce-Doped Mn₃O₄ and Its Electrochemical Capacitive Behavior

1.
Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China

Received Date: 14 January 2011
Available Online: 19 May 2011
Fund Project: 国家自然科学基金(20963009) (20963009) 甘肃省自然科学基金(0803RJ2A005) (0803RJ2A005)

Mn₃O₄ and Ce doped Mn₃O₄ were synthesized via a sol-gel route using metal nitrates as raw materials and citric acid as the chelating agent. The gel precursors were calcined at 300 ℃ for 12 h in a muffle furnace. Their morphology and structure were characterized using powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Their electrochemical performance as a supercapacitor electrode material was investigated comparatively by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge. The experimental results indicated that Ce- doping did not change the structure of Mn₃O₄ but greatly affected the morphology and considerably enhanced the electrochemical performance of Mn₃O₄. A specific capacitance of 477 F·g^-1 was obtained when the mole ratio of Ce ion to total metal ions was 3%, which was 43.7% higher than that of the undoped material. Moreover, Ce-doping significantly improved the capacitance retention ability.
- Sol-gel,
- Mn₃O₄,
- Ce,
- Dope,
- Electrochemical capacitance
1. [1]
  
  (1) Conway, B. E. J. Electrochem. Soc. 1991, 138, 1539.
2. [2]
  (2) Köz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483.
3. [3]
  (3) Simon, P.; tsi, Y. Nat. Mater. 2008, 7, 845.
4. [4]
  (4) Gao, Q.; Liu, Y. F.; Hu, Z. H.; Zheng, X.W.;Wen, Z. B. Acta Phys. -Chim. Sin. 2009, 25, 229. [高强, 刘亚菲, 胡中华, 郑祥伟, 温祖标. 物理化学学报, 2009, 25, 229.]
5. [5]
  (5) Zheng, J. P.; Cygan, P. J.; Jow, T. R. J. Electrochem. Soc. 1995, 142, 2699.
6. [6]
  (6) Wang, H. Q.; Li, Z. S.; Yang, J. H.; Li, Q. Y.; Zhong, X. X. J. Power Sources 2009, 194, 1218.
7. [7]
  (7) Lee, M. T.; Chang, J. K.; Tsai,W. T. J. Electrochem. Soc. 2007, 154, 875.
8. [8]
  (8) Devaraj, S.; Munichandraiah, N. J. Phys. Chem. C 2008, 112, 4406.
9. [9]
  (9) Tang, Z. Y.; Geng, X.;Wang, Z. L.; Xue, J. J. Chin. J. Appl. Chem. 2002, 19, 936. [唐致远, 耿新, 王占良, 薛建军. 应用化学, 2002, 19, 936.]
10. [10]
  (10) Malankar, H.; Umare, S. S.; Singh, K. Mater. Lett. 2009, 63, 2016.
11. [11]
  (11) Pang, X.; Ma, Z. Q.; Zuo, L. Acta Phys. -Chim. Sin. 2009, 25, 2433. [庞旭, 马正青, 左列. 物理化学学报, 2009, 25, 2433.]
12. [12]
  (12) Kumagai, N.; Komaba, S.; Abe, K.; Yashiro, H. J. Power Sources 2005, 146, 310.
13. [13]
  (13) He, X. M.; Li, J. J.; Cai, Y.; Jiang, C. Y.;Wan, C. R. Mater. Chem. Phys. 2006, 95, 105.
14. [14]
  (14) Jiao, F.; Bruce, P. G. Adv. Mater. 2007, 19, 657.
15. [15]
  (15) Li, P.; Nan, C. Y.;Wei, Z.; Lu, J.; Peng, Q.; Li, Y. D. Chem. Mater. 2010, 22, 4232.
16. [16]
  (16) Dubal, D. P.; Dhawale, D. S.; Salunkhe, R. R.; Pawar, S. M.; Lokhande, C. D. Appl. Surf. Sci. 2010, 256, 4411.
17. [17]
  (17) Dubal, D. P.; Dhawale, D. S.; Salunkhe, R. R.; Fulari, V. J.; Lokhande, C. D. J. Alloy. Compd. 2010, 497, 166.
18. [18]
  (18) Xing, S. T.; Zhou, Z. C.; Ma, Z. C.;Wu, Y. S. Mater. Lett. 2011, 65, 517.
19. [19]
  (19) Ma, J. M.; Lu, J. Q.;Wang, Y. J.; Bao, M. M.; Luo, M. F. Chem. J. Chin. Univ. 2007, 28, 2112. [马静萌, 鲁继青, 王月娟, 包明敏, 罗孟飞. 高等学校化学学报, 2007, 28, 2112.]
20. [20]
  (20) Shi, L. M.; Chu,W.; Qu, F. F.; Hu, J. Y.; Li, M. M. J. Rare Earths 2008, 26, 836.
21. [21]
  (21) Delimaris, D.; Ioannides, T. Appl. Catal. B-Environ. 2008, 84, 303.
22. [22]
  (22) Rao, T.; Shen, M. Q.; Jia, L.W.; Hao, J. J.;Wang, J. Catal. Commun. 2007, 8, 1743.
23. [23]
  (23) Ye, Q.; Xu, B. Q. Acta Phys. -Chim. Sin. 2006, 22, 345. [叶青,徐柏庆. 物理化学学报, 2006, 22, 345.]
24. [24]
  (24) Arumugam, D.; Paruthimal Kalaignan, G. J. Electroanal. Chem. 2010, 648, 54.
25. [25]
  (25) Lu, H. Q.;Wu, F.; Su, Y. F.; Li, N.; Chen, S.; Bao, L. Y. Acta Phys. -Chim. Sin. 2010, 26, 51. [卢华权, 吴锋, 苏岳锋, 李宁, 陈实, 包丽颖. 物理化学学报, 2010, 26, 51.]
26. [26]
  (26) Ghaemi, M.; Ataherian, F.; Zolfaghari, A.; Jafari, S. M. Electrochim. Acta 2008, 53, 4607.
27. [27]
  (27) Xie, L. J.; Jin, X. Q.; Fu, G. R.; Xie, Y. L.;Wang, Y. X.; Hu, Z. A. Chem. J. Chin. Univ. 2010, 31, 353. [谢莉婧, 金小青, 付国瑞, 解玉龙, 王耀先, 胡中爱. 高等学校化学学报, 2010, 31, 353.]
28. [28]
  (28) Chen,W. C.;Wen, T. C. J. Power Sources 2003, 117, 273.
29. [29]
  (29) Girija, T. C.; Sangaranarayanan, M. V. J. Power Sources 2006, 156, 705.
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沈阳化工大学材料科学与工程学院沈阳 110142

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Ce-Doped Mn₃O₄ and Its Electrochemical Capacitive Behavior