Citation: ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping. Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H₂SO₄ Electrolytes[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1431-1438. doi: 10.3866/PKU.WHXB20110634 shu

Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H₂SO₄ Electrolytes

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China

Received Date: 28 March 2011
Available Online: 10 May 2011
Fund Project: 山东省优秀中青年科学家科研奖励基金(BS2009NJ014, 2008BS09007)资助项目 (BS2009NJ014, 2008BS09007)

Ordered mesoporous carbon materials were prepared by doping boric acid using a hard- templating method. The capacitive performance of these carbons was investigated in organic and H₂SO₄ electrolytes. As demonstrated by structure analysis the prepared carbons possessed parallel mesoporous channels. The pore size increased from 3.3 to 5.7 nm and the molar fraction of oxygenated groups on the carbon surface increased from 2.0% to 5.2% with an increase in the amount of boric acid doping from 0 to 50% (molar fraction). In the organic electrolyte, the carbons mainly showed typical electric double layer capacitive performance and no visible pseudo-capacitance was induced. In H₂SO₄ electrolytes, BOMC-5 showed the highest specific mass capacitance of 140.9 F·g^-1 and the specific surface capacitance of the prepared carbons increased with an increase in the oxygenated groups and this carbon showed visible pseudo-capacitance because of the rapid redox reactions of the oxygenated groups. The capacitance retention ratio depends on the surface chemical properties, which determines the wettability of the carbon surface and the electrolytes.
- Ordered mesoporous carbon,
- Organic electrolyte,
- H₂SO₄ electrolyte,
- Supercapacitor,
- Surface chemical property
1. [1]
  
  (1) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Chemical Industry Press: Beijing, 2005; translated by Chen, A.,Wu, M. Q., Zhang, X. L., Gao, N.W.
2. [2]
  [Conway, B. E. 电化学超级电容器——科学原理及技术应用. 陈艾, 吴孟强, 张绪礼, 高能武, 译. 北京: 化学工业出版社, 2005.]
3. [3]
  (2) Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk,W. Nat. Mater. 2005, 4, 366.
4. [4]
  (3) Li, L. M.; Liu, E. H.; Li, J.; Yang, Y. J.; Shen, H. J.; Huang, Z. Z.; Xiang, X. X. Acta Phys. -Chim. Sin. 2010, 26, 1521.
5. [5]
  [李利民, 刘恩辉, 李剑, 杨艳静, 沈海杰, 黄铮铮, 向晓霞. 物理化学学报, 2010, 26, 1521.]
6. [6]
  (4) Ji, Q. Q.; Guo, P. Z.; Zhao. X. S. Acta Phys. -Chim. Sin. 2010, 26, 1254.
7. [7]
  [季倩倩, 郭培志, 赵修松. 物理化学学报, 2010, 26, 1254.]
8. [8]
  (5) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157, 11.
9. [9]
  (6) Liu, Y. X.; Li, L. X.; Chen, X. H.; Song, H. H. Acta Phys. -Chim. Sin. 2007, 23, 1399.
10. [10]
  [刘宇林, 李丽霞, 陈晓红, 宋怀河. 物理化学学报, 2007, 23, 1399.]
11. [11]
  (7) Zhou, J.; Yuan, X.; Xing,W.; Si,W.; Zhuo, S. Carbon 2010, 48, 2765.
12. [12]
  (8) Li,W.; Zhou, J.; Xing,W.; Zhuo, S. Lü, Y. Acta Phys. -Chim. Sin. 2011, 27, 620.
13. [13]
  [李文, 周晋, 邢伟, 禚淑萍, 吕忆民. 物理化学学报, 2011, 27, 620.]
14. [14]
  (9) Itoi, H.; Nishihara, H.; Kogure, T.; Kyotani, T. J. Am. Chem. Soc. 2011, 133, 1165.
15. [15]
  (10) Kajdos, A.; Kvit, A.; Jones, F.; Jagiello, J. Yushin, G. J. Am. Chem. Soc. 2010, 132, 3252.
16. [16]
  (11) Daffos, B.; Taberna, P. L.; sti, Y.; Simon, P. Fuel Cell 2010, 10, 819.
17. [17]
  (12) Jin, J.; Tanaka, S.; Egashira, Y.; Nishiyama, N. Carbon 2010, 45, 1985.
18. [18]
  (13) Xing,W.; Huang, C. C.; Zhuo, S. P.; Yuan, X.;Wang, G. Q.; Hulicova-Jurcakova, D.; Yan, Z. F.; Lu, G. Q. Carbon 2009, 47, 1715.
19. [19]
  (14) Kim,W.; Joo, J. B.; Kim, N.; Oh, S.; Kim, P.; Yi, J. Carbon 2009, 47, 1407.
20. [20]
  (15) Fuertes, A. B.; Lota, G.; Centeno, T. A.; Frackowiak, E. Electrochimica Acta 2005, 50, 2799.
21. [21]
  (16) Banham, D.; Feng, F.; Burt, J.; Alsrayheen, E.; Birss, V. Carbon 2010, 48, 1056.
22. [22]
  (17) Jiang, J.; Gao, Q.; Xia, K.; Hu, J. Microporous Mesoporous Mat. 2009, 118, 28.
23. [23]
  (18) Li, L.; Song, H.; Chen, X. Electrochimica Acta 2006, 51, 5715.
24. [24]
  (19) Xing,W.; Qiao, S. Z.; Ding, R. G.; Li, F.; Lu, G. Q.; Yan, Z. F.; Cheng, H. M. Carbon 2006, 44, 216.
25. [25]
  (20) Wang, D.; Li, F; Fang, H. T.; Liu. M.; Lu, G.; Cheng, H. J. Phys. Chem. B 2006, 110, 8570.
26. [26]
  (21) Li, H. Q.; Luo, J.; Zhou, X. F.; Yu, C. Z.; Xia, Y. J. Electrochem. Soc. 2007, 154, A731.
27. [27]
  (22) Wang, D.W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. J. Phys. Chem. C 2008, 112, 9950.
28. [28]
  (23) Jang, I. Y.; Muramatsu, H.; Park, K. C.; Kim, Y. J.; Endo, M. Electrochem. Commun. 2009, 11, 719.
29. [29]
  (24) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548.
30. [30]
  (25) Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.; Ohsuna, T.; Terasaki, O. J. Am. Chem. Soc. 2000, 122, 10712.
31. [31]
  (26) Wang, D.; Li, F.; Liu, M.; Cheng, H. M. New Carbon Materials 2007, 22, 307.
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南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H₂SO₄ Electrolytes