Citation: WANG Lian-Yan, LU Feng, WU Fu-Quan, GU Ren-Ao, YAO Jian-Lin, ZHANG Hai-Lu, DENG Zong-Wu. Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1451-1456. doi: 10.3866/PKU.WHXB20110628 shu

Electrosynthesis and Characterization of Metal Chelate Imprinted Poly-o-Phenylenediamine Films

1.
1. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China;
2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu Province, P. R. China;
3. Suzhou Environmental Monitor Centre, Suzhou 215004, Jiangsu Province, P. R. China

Received Date: 14 January 2011
Available Online: 9 May 2011
Fund Project: 国家自然科学基金(21073226) (21073226)苏州市科技计划项目(SS0852)资助 (SS0852)

Novel molecularly imprinted polymers (MIPs) were synthesized by the electrochemical polymerization of o-phenylenediamine (o-PD) using cyclic voltammetry in the presence of Cu(II)- ethylenediaminetetraacetate chelate (Cu(II)-EDTA), which acted as a template. The resultant polymers were characterized by UV-Vis spectroscopy, X-ray photoelectron spectroscopy (XPS), differential pulse voltammetry (DPV), and quartz crystal microbalance (QCM). UV-Vis spectral analysis indicated that a higher degree poly-o-phenylenediamine (PoPD) was obtained at pH≥5.0. XPS analysis clearly showed the successful embedding of a Cu(II)-EDTA chelate in the PoPD film and, therefore, hydrogen bonding was a major interaction between the template and the PoPD film. DPV analysis confirmed the successful removal of the template from the PoPD film. The QCM test showed that the Cu(II)-EDTA imprinted PoPD film had od Cu(II)-EDTA chelate sensitivity.
- o-Phenylenediamine,
- Chelate,
- Molecularly imprinted polymer,
- Cyclic voltammetry,
- Quartz crystal microbalance
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