Citation: CAO Guo-Fei, LIAO Yi, ZHANG Xiao-Hua, CHEN Jin-Hua. Preparation and Characterization of Peasecod-Based Activated Carbons as Electrode Materials for Electrochemical Double-Layer Capacitors[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1679-1684. doi: 10.3866/PKU.WHXB20110623 shu

Preparation and Characterization of Peasecod-Based Activated Carbons as Electrode Materials for Electrochemical Double-Layer Capacitors

1.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

Received Date: 22 November 2010
Available Online: 5 May 2011
Fund Project: 教育部长江学者与创新团队发展计划(PCSIRT)，湖南省自然科学基金(04JJ1008) (PCSIRT)，湖南省自然科学基金(04JJ1008)高等学校博士学科点专项科研基金(20040532006)资助项目 (20040532006)

Activated carbons for electrochemical double-layer capacitor electrodes were prepared from peasecod-based carbons using ZnCl₂ or KOH as activating agents. The pore structures of the prepared activated carbon materials were characterized using N2 adsorption. The specific surface area of the peasecod-based carbon materials increased obviously from 1.69 m²·g^-1 to 2237 m²·g^-1 by KOH activation and to 621 m²·g^-1 by ZnCl₂ treatment. The electrochemical properties of the prepared peasecod-based activated carbon materials were evaluated by cyclic voltammetry and galvanostatic charge-discharge, and a specific capacitance as high as 297.5 F·g^-1 in 6 mol·L^-1 KOH aqueous electrolyte was obtained for the KOH-treated carbon material. Additionally, the KOH-activated peasecod-based carbon material showed excellent long-term charge-discharge cycle stability and a 8.6% decrease in the specific capacitance was observed at a high current density of 5 A·g^-1 after 500 cycles.
- Double-layer capacitor,
- Activated carbon,
- Peasecod,
- Energy storage,
- Agricultural waste
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