Citation: YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1446-1450. doi: 10.3866/PKU.WHXB20110620 shu

Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 16 December 2010
Available Online: 4 May 2011
Fund Project: 国家自然科学基金(20873114, 20833005) (20873114, 20833005)国家重点基础研究发展计划(2009CB930703)资助项目 (2009CB930703)

Using the Scharifker and Hills model and Heerman and Tarallo model, cyclic voltammetry and chronoamperometry were used to study the nucleation mechanism upon the electrodeposition of a Pd-Ni alloy from an electrolyte. The results show that the electrodeposition of the Pd-Ni alloy onto glassy carbon electrode consisted of nucleation and growth, and the nucleation process according to the Scharifker and Hills model follows three dimension-progressive nucleation, which is controlled by the diffusion of the electroactive species. By applying the Heerman and Tarallo model, the kinetic parameters associated with the crystal nucleation and growth processes were obtained. The nucleation rate constant and the density of active nucleation sites increased from 0.83 to 7.71 s^-1 and from 2.77×10⁴ to 7.09×10⁴ cm^-2, respectively, as the step potential was changed from -0.85 to -0.92 V (vs SCE).
- Pd-Ni alloy,
- Electrocrystallization,
- Cyclic voltammetry,
- Chronoamperometry
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