Citation: SUN Du, YIN Peng-Gang, GUO Lin. Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1543-1550. doi: 10.3866/PKU.WHXB20110619 shu

Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure

1.
School of Chemistry and Environment, Beijing University of Aeronautics & Astronautics, Beijing 100191, P. R. China

Received Date: 4 March 2011
Available Online: 3 May 2011
Fund Project: 国家重点基础研究发展规划(973) (2010CB934700) (973) (2010CB934700) 国家自然科学基金(50725208, 20973019) (50725208, 20973019)高等学校博士学科点专项科研基金(20091102110035)资助项目 (20091102110035)

Structural engineering of nanocrystals is of great importance to control the properties of semiconductor oxides. Here, we present a mild wet chemical reduction route to obtain a sub-micron porous jujube-like Cu₂O hierarchy structure. Sodium dodecylbenzene sulfonate (SDBS) is crucial in structural regulation and it acts as a soft template and a capping agent. The jujube-like particle consists of crystal grains less than 10 nm in size as verified by transmission electron microscopy (TEM) and X-ray diffraction (XRD). A set of time control experiments were carried out to study the evolution of the jujube-like structure. Interestingly, we found that altering the amount of added HCl resulted in a size-tuning effect of changing the size of the particles from approximately 300 to 900 nm. Based on these results, we propose a possible growth-etching competition mechanism to explain the formation of the hollow interior and its porous nature, which also agrees with the sizing-tuning effect. The optical properties were analyzed using Raman spectroscopy. By comparison with a conventional sub-micron solid polyhedral we found a novel Raman property for the porous jujube-like Cu₂O. Our research complements the library of Cu₂O Raman spectra, which is meaningful for the nondestructive examination of pigments on the surface of antiques by Raman techniques.
- Nanomaterial,
- Sodium dodecylbenzene sulfonate,
- Cuprous oxide,
- Hierarchy structure,
- Raman spectroscopy
1. [1]
  
  (1) Burda, C.; Chen, X. B.; Narayanan, R.; El-Sayed, M. A. Chem. Rev. 2005, 105, 1025.
2. [2]
  (2) Zhang, H. G.; Zhu, Q. S.; Zhang, Y.;Wang, Y.; Zhao, L.; Yu, B. Adv. Funct. Mater. 2007, 17, 2766.
3. [3]
  (3) Ho, J. Y.; Huang, M. H. J. Phys. Chem. C 2009, 113, 14159.
4. [4]
  (4) Yuhas, B. D.; Yang, P. D. J. Am. Chem. Soc. 2009, 131, 3756.
5. [5]
  (5) Zhang, J. T.; Liu, J. F.; Peng, Q.;Wang, X.; Li, Y. D. Chem. Mater. 2006, 18, 867.
6. [6]
  (6) Bor hain, K.; Murase, N.; Mahamuni, S. J. Appl. Phys. 2002, 92, 1292.
7. [7]
  (7) Yin, M.;Wu, C. K.; Lou, Y. B.; Burda, C.; Koberstein, J. T.; Zhu, Y. M.; O′Brien, S. J. Am. Chem. Soc. 2005, 127, 9506.
8. [8]
  (8) Wang,W. Z.;Wang, G. H.;Wang, X. S.; Zhan, Y. J.; Liu, Y. K.; Zheng, C. L. Adv. Mater. 2002, 14, 67.
9. [9]
  (9) Tan, Y.W.; Xue, X. Y.; Peng, Q.; Zhao, H.;Wang, T. H.; Li, Y. D. Nano Lett. 2007, 7, 3723.
10. [10]
  (10) Ng, C. H. B.; Fan,W. Y. J. Phys. Chem. B 2006, 110, 20801.
11. [11]
  (11) Zhang, D. F.; Zhang, H.; Guo, L.; Zheng, K.; Han, X. D.; Zhang, Z. J. Mater. Chem. 2009, 19, 5220.
12. [12]
  (12) Xu, H.;Wang,W. Angew. Chem. Int. Edit. 2007, 46, 1489.
13. [13]
  (13) Luo, Y. S.; Li, S. Q.; Ren, Q. F.; Liu, J. P.; Xing, L. L.;Wang, Y.; Yu, Y.; Jia, Z. J.; Li, J. L. Cryst. Growth & Des. 2007, 7, 87.
14. [14]
  (14) McShane, C. M.; Choi, K. J. Am. Chem. Soc. 2009, 131, 2561.
15. [15]
  (15) Xu, J.; Tang, Y. B.; Zhang,W. X.; Lee, C. S.; Yang, Z. H.; Lee, S. T. Cryst. Growth & Des. 2009, 9, 4524.
16. [16]
  (16) Burgio, L.; Ciomartan, D. A.; Clark, R. J. Mol. Struct. 1997, 405, 1.
17. [17]
  (17) Burrafato, G.; Calabrese, M.; Cosentino, A.; Gueli, A. M.; Troja, S. O.; Zuccarello, A. J. Raman Spectrosc. 2004, 35, 879.
18. [18]
  (18) Clark, R.; van derWeerd, J. J. Raman Spectrosc. 2004, 35, 279.
19. [19]
  (19) Galli, S.; Mastelloni, M.; Ponterio, R.; Sabatino, G.; Triscari, M. J. Raman Spectrosc. 2004, 35, 622.
20. [20]
  (20) Welter, N.; Schussler, U.; Kiefer,W. J. Raman Spectrosc. 2007, 38, 113.
21. [21]
  (21) Zhang, Y. J.; Or, S.W.;Wang, X. L.; Cui, T. Y.; Cui,W. B.; Zhang, Y.; Zhang, Z. D. Eur. J. Inorg. Chem. 2009, 2009, 168.
22. [22]
  (22) Jia,W. Z.; Reitz, E.; Sun, H.; Li, B.; Zhang, H.; Lei, Y. J. Appl. Phys. 2009, 105, 064917.
23. [23]
  (23) Wang, X. Q.; Xi, G. C.; Xiong, S. L.; Liu, Y. K.; Xi, B. J.; Yu, W. C.; Qian, Y. T. Cryst. Growth & Des. 2007, 7, 930.
24. [24]
  (24) Zhang, Y.; Zhang, Y.;Wang, Z.; Li, D.; Cui, T.; Liu,W.; Zhang, Z. Eur. J. Inorg. Chem. 2008, 2008, 2733.
25. [25]
  (25) Kuo, C.; Huang, M. H. J. Am. Chem. Soc. 2008, 130, 12815.
26. [26]
  (26) Huang, K. Zeitschrift für Physikalische Chemie 1963, 171, 213.
27. [27]
  (27) Balkanski, M.; Nusimovici, M. A.; Reydellet, J. Solid. State Commun. 1969, 7, 815.
28. [28]
  (28) Reydellet, J.; Balkanski, M.; Trivich, D. Phys. Stat. Sol. B 1972, 52, 175.
29. [29]
  (29) Dawson, P.; Hargreave, M. M.;Wilkinson, G. R. J. Phys. Chem. Solids 1973, 34, 2201.
30. [30]
  (30) Zhang, H.; Zhang, D. F.; Guo, L.; Zhang, R.; Yin, P. G.;Wang, R. M. J. Nanosci. Nanotechno. 2008, 8, 6332.
31. [31]
  (31) Solache-Carranco, H.; Juarez-Diaz, G.; Martinez-Juarez, J.; Pena-Sierra, R. Rev. Mex. Fis. 2009, 55, 393.
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure