Citation: SUN Du, YIN Peng-Gang, GUO Lin. Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1543-1550. doi: 10.3866/PKU.WHXB20110619 shu

Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure

1.
School of Chemistry and Environment, Beijing University of Aeronautics & Astronautics, Beijing 100191, P. R. China

Received Date: 4 March 2011
Available Online: 3 May 2011
Fund Project: 国家重点基础研究发展规划(973) (2010CB934700) (973) (2010CB934700) 国家自然科学基金(50725208, 20973019) (50725208, 20973019)高等学校博士学科点专项科研基金(20091102110035)资助项目 (20091102110035)

Structural engineering of nanocrystals is of great importance to control the properties of semiconductor oxides. Here, we present a mild wet chemical reduction route to obtain a sub-micron porous jujube-like Cu₂O hierarchy structure. Sodium dodecylbenzene sulfonate (SDBS) is crucial in structural regulation and it acts as a soft template and a capping agent. The jujube-like particle consists of crystal grains less than 10 nm in size as verified by transmission electron microscopy (TEM) and X-ray diffraction (XRD). A set of time control experiments were carried out to study the evolution of the jujube-like structure. Interestingly, we found that altering the amount of added HCl resulted in a size-tuning effect of changing the size of the particles from approximately 300 to 900 nm. Based on these results, we propose a possible growth-etching competition mechanism to explain the formation of the hollow interior and its porous nature, which also agrees with the sizing-tuning effect. The optical properties were analyzed using Raman spectroscopy. By comparison with a conventional sub-micron solid polyhedral we found a novel Raman property for the porous jujube-like Cu₂O. Our research complements the library of Cu₂O Raman spectra, which is meaningful for the nondestructive examination of pigments on the surface of antiques by Raman techniques.
- Nanomaterial,
- Sodium dodecylbenzene sulfonate,
- Cuprous oxide,
- Hierarchy structure,
- Raman spectroscopy
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis and Raman Property of Porous Jujube-Like Cu₂O Hierarchy Structure