Citation: LI Jian-Sheng, GU Juan, LING Xiao-Feng, SUN Xiu-Yun, SHEN Jin-You, HAN Wei-Qing, WANG Lian-Jun. Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1772-1776. doi: 10.3866/PKU.WHXB20110613 shu

Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization

1.
School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Received Date: 27 December 2010
Available Online: 27 April 2011
Fund Project: 国家自然科学基金(51078184) (51078184) 高等学校科技创新工程重大项目培育项目(708049) (708049) 江苏省自然科学基金(BK2009392) (BK2009392)南京理工大学自主科研专项计划项目(2010ZDJH03)资助 (2010ZDJH03)

We report a one-step method for the synthesis of M(Fe, Co, Ni) nanocrystals supported by ordered mesoporous carbon (OMC) materials. M/OMC composites were obtained by the soft templating route under acidic conditions using resorcinol and formaldehyde as carbon precursors, triblock copolymer Pluronic F127 as a template and Fe, Co, Ni nitrates as metal precursors. The as-synthesized materials were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and N₂ adsorption. Characterization revealed that the as-synthesized materials possessed an ordered hexa nal mesoporous structure similar to SBA-15. The specific surface areas of the Fe/OMC, Co/OMC, and Ni/OMC composites were found to be 586, 626, and 698 m²·g^-1, respectively. The fact that the metal species were present as highly dispersed nanocrystals in the OMC matrix was confirmed by XRD and high-resolution TEM.
- Ordered mesoporous carbon
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