Citation: LU Dong-Fei, DI You-Ying, HE Dong-Hua. Crystal Structure and Thermochemical Properties of Bis(n-Nonylammonium) Tetrachlorozincate[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1319-1324. doi: 10.3866/PKU.WHXB20110526 shu

Crystal Structure and Thermochemical Properties of Bis(n-Nonylammonium) Tetrachlorozincate

1.
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China

Received Date: 26 January 2011
Available Online: 13 April 2011
Fund Project: 国家自然科学基金(20673050, 20973089)资助项目 (20673050, 20973089)

We synthesized crystalline bis(n-nonylammonium) tetrachlorozincate (C₉H₁₉NH₃)₂ZnCl₄(s) (C₉Zn(s)). X-ray single crystal diffraction, chemical analysis, and elemental analysis were used to determine the crystal structure and composition of the complex. The lattice potential energy U_POT was calculated to be 952.94 kJ·mol^-1 from crystallographic data. The molar enthalpies of C₉Zn(s) dissolution using various molalities were measured in double-distilled water by an isoperibol solution-reaction calorimeter at 298.15 K. According to Pitzer's electrolyte solution theory the molar enthalpy of dissolution of C₉Zn(s) at infinite dilution (Δ_sΗ_m^∞ )] was calculated to be 20.09 kJ·mol^-1 and the sums of Pitzer's parameters (4β_{C₉H₁₉NH₃,Cl}^(0)L+2β_Zn,Cl^(0)L+θ_{C₉H₁₉NH₃,Zn}^L) and (2β_{C₉H₁₉NH₃,Cl}^(1)L+β_Zn,Cl^(1)L) were obtained.
- Bis(n-nonylammonium) tetrachlorozincate,
- Lattice potential energy,
- Molar enthalpy of dissolution at infinite dilution,
- Pitzer’s parameter,
- Pitzer’s theory
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沈阳化工大学材料科学与工程学院沈阳 110142