Citation: YUAN Xiao-Ling, LU Chun-Mei, ZHU Wan-Chun, JIA Ming-Jun, LIU Gang, WANG Zhen-Lü, ZHANG Wen-Xiang. Adsorption Performance of Hg(II) Ions on Amine-Modified Nanoporous Carbon Materials[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1181-1187. doi: 10.3866/PKU.WHXB20110519 shu

Adsorption Performance of Hg(II) Ions on Amine-Modified Nanoporous Carbon Materials

1.
1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin Uinversity, Changchun 130012, P. R. China;
2. Jilin Entry-Exit Inspection and Quarantine Bureau, Changchun 130062, P. R. China

Received Date: 19 January 2011
Available Online: 7 April 2011
Fund Project: 国家自然科学基金(20773050, 21003059) (20773050, 21003059)教育部博士点基金新教师项目(20090061120024)资助 (20090061120024)

The adsorption performance of nanoporous carbon (NC) and ethylenediamine-modified nanoporous carbon (NC-EDA) toward Hg²⁺ ions was investigated in an aqueous solution. The NC material exhibited a relatively high adsorption capacity for Hg²⁺ ions, and the adsorption capacity was improved significantly by ethylenediamine modification. After thermal-treatment at 873 K, the adsorption capacity of the NC-EDA material was still relatively high. Based on various characterization results, we propose that the presence of abundant functional groups (i.e., －COOH, －OH) on the surface of the NC materials is beneficial for the introduction of a large number of amino functional groups resulting in the presence of abundant basic N-containing species on the surface of the NC materials. These basic species can interact with mercury ions and thus significantly improve the adsorption capacity of the carbon material.
- Nanoporous carbon,
- Adsorption,
- Ethylenediamine,
- Mercury ion,
- Alkalinity
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