Citation: ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun. Controlled Synthesis and Characterization of the Structure and Property of Fe3O4 Nanoparticle-Graphene Oxide Composites[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1261-1266. doi: 10.3866/PKU.WHXB20110512 shu

Controlled Synthesis and Characterization of the Structure and Property of Fe3O4 Nanoparticle-Graphene Oxide Composites

  • Received Date: 3 January 2011
    Available Online: 31 March 2011

    Fund Project: 国家自然科学基金(20873090, 21073224)资助项目 (20873090, 21073224)

  • Fe3O4 nanoparticle-graphene oxide (M ) composites were prepared by chemically binding carboxylic acid-modified Fe3O4 nanoparticles to polyethylenimine-functionalized graphene oxide ( ). The structure, morphology, and magnetic properties of the composites were characterized by transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), and vibrating sample magnetometry (VSM). The results show that the Fe3O4 nanoparticle content in the M composites can be easily controlled by changing the ratio of Fe3O4 nanoparticles to in the reaction mixture. The M composites obtained are superparamagnetic with high saturation magnetization, which can potentially be applied in magnetic targeted drug delivery, gene transport, magnetic resonance imaging, bioseparation, and magnetic guided removal of aromatic contaminants in waste water and in other fields.

  • 加载中
    1. [1]

      (1) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.

    2. [2]

      (2) Shen, J. F.; Hu, Y. Z.; Shi, M.; Li, N.; Ma, H. W.; Ye, M. X. J. Phys. Chem. C 2010, 114, 1498.

    3. [3]

      (3) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science 2004, 306, 666.

    4. [4]

      (4) Berger, C.; Song, Z. M.; Li, T. B.; Li, X. B.; Ogbazghi, A. Y.; Feng, R.; Dai, Z. T.; Marchenkov, A. N.; Conrad, E. H. J. Phys. Chem. B 2004, 108, 19912.

    5. [5]

      (5) Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Nature 2006, 442, 282.

    6. [6]

      (6) Di, C. A.; Wei, D. C.; Yu, G.; Liu, Y. Q.; Guo, Y. L.; Zhu, D. B. Adv. Mater. 2008, 20, 3289.

    7. [7]

      (7) Wu, J. S.; Pisula, W.; Mullen, K. Chem. Rev. 2007, 107, 718.

    8. [8]

      (8) Huang, J.; Zhang, L. M.; Chen, B.; Ji, N.; Chen, F. H.; Zhang, Y.; Zhang Z. J. Nanoscale 2010, 2, 2733.

    9. [9]

      (9) Zhang, X. Y.; Yang, X. Y.; Ma, Y. F.; Huang, Y.; Chen, Y. S. Journal of Nanoscience and Nanotechnology 2010, 10, 2984.

    10. [10]

      (10) Yang, X. Y.; Zhang, X. Y.; Ma, Y. F.; Huang, Y.; Wangand, Y. S.; Chen, Y. S. J. Mater. Chem. 2009, 19, 2710.

    11. [11]

      (11) Zhang, L. M.; Xia, J. G.; Zhao, Q. H.; Liu, L. W.; Zhang, Z. J. Small 2010, 6, 537.

    12. [12]

      (12) Si, Y. C.; Samulski, E. T. Chem. Mater. 2008, 20, 6792.

    13. [13]

      (13) Muszynski, R.; Seger, B.; Kamat, P. V. J. Phys. Chem. C 2008, 112, 5263.

    14. [14]

      (14) Xu, C.; Wang, X.; Zhu, J. W. J. Phys. Chem. C 2008, 112, 19841.

    15. [15]

      (15) Cong, H. P.; He, J. J.; Lu, Y.; Yu, S. H. Small 2010, 6, 169.

    16. [16]

      (16) He, F.; Fan, J. T.; Ma, D.; Zhang, L. M.; Leung, C. W.; Chan, H. L. Carbon 2010, 48, 3139.

    17. [17]

      (17) Zhang, Y.; Chen, B.; Zhang, L. M.; Huang, J.; Chen, F. H.; Yang, Z. P.; Yao. J. L.; Zhang, Z. J. Nanoscale, published online: 07 Feb, 2011, DOI: 10.1039/C0NR00776E.

    18. [18]

      (18) Sun, S. H.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.; Wang, S. X.; Li, G. X. J. Am. Chem. Soc. 2004, 126, 273.

    19. [19]

      (19) Chen, Z. P.; Zhang, Y.; Xu, K.; Xu, R. Z.; Liu, J. W.; Gu, N. Journal of Nanoscience and Nanotechnology 2008, 8, 12.

    20. [20]

      (20) Hummers, W.; Offeman, R. J. Am. Chem. Soc. 1958, 80, 1339.

    21. [21]

      (21) Zhu, C. X.; Peng, D. F. Speciality Petrochemicals 2010, 27, 57.

    22. [22]

      (22) Paredes, J. I.; Villar-Rodil, S.; Solis-Fernandez, P.; Martinez-Alonso, A.; Tascon, J. M. D. Langmuir 2009, 25, 5957.

    23. [23]

      (23) Bourlinos, A. B.; urnis, D.; Petridis, D.; Szabo, T.; Szeri, A.; Dekany, I. Langmuir 2003, 19, 6050.

    24. [24]

      (24) Stankovich, S. S.; Piner, R. D.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2006, 44, 3342.

    25. [25]

      (25) Chin, S. F.; Iyer, K. S.; Raston, C. L. Lab. Chip. 2008, 8, 439.

    26. [26]

      (26) Rocchiccioli-Deltche, C.; Franck, R.; Cabuil, V.; Massart, R. J. Chem. Res. 1987, 5, 126.

    27. [27]

      (27) Popplewell, J.; Sakhnini, L. J. Magn. Mater. 1995, 142, 72.


  • 加载中
    1. [1]

      Zhuo WANGJunshan ZHANGShaoyan YANGLingyan ZHOUYedi LIYuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    2. [2]

      Zhanggui DUANYi PEIShanshan ZHENGZhaoyang WANGYongguang WANGJunjie WANGYang HUChunxin LÜWei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    3. [3]

      Zhihuan XUQing KANGYuzhen LONGQian YUANCidong LIUXin LIGenghuai TANGYuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    4. [4]

      Xiangyu CAOJiaying ZHANGYun FENGLinkun SHENXiuling ZHANGJuanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270

    5. [5]

      Zeyu XUAnlei DANGBihua DENGXiaoxin ZUOYu LUPing YANGWenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099

    6. [6]

      Siyu HOUWeiyao LIJiadong LIUFei WANGWensi LIUJing YANGYing ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

    7. [7]

      Peng XUShasha WANGNannan CHENAo WANGDongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

    8. [8]

      Jiahong ZHENGJiajun SHENXin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

    9. [9]

      Yongming Guo Jie Li Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057

    10. [10]

      Min LIXianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065

    11. [11]

      Yaping ZHANGTongchen WUYun ZHENGBizhou LIN . Z-scheme heterojunction β-Bi2O3 pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256

    12. [12]

      Meng Lin Hanrui Chen Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

    13. [13]

      Yunting Shang Yue Dai Jianxin Zhang Nan Zhu Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050

    14. [14]

      Yuanchao LIWeifeng HUANGPengchao LIANGZifang ZHAOBaoyan XINGDongliang YANLi YANGSonglin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    15. [15]

      Limei CHENMengfei ZHAOLin CHENDing LIWei LIWeiye HANHongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    16. [16]

      Haiyu Nie Chenhui Zhang Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055

    17. [17]

      Hao BAIWeizhi JIJinyan CHENHongji LIMingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    18. [18]

      Xinyuan Shi Chenyangjiang Changyu Zhai Xuemei Lu Jia Li Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr3 Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019

    19. [19]

      Kai Yang Gehua Bi Yong Zhang Delin Jin Ziwei Xu Qian Wang Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045

    20. [20]

      Zunyuan Xie Lijin Yang Zixiao Wan Xiaoyu Liu Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137

Metrics
  • PDF Downloads(2452)
  • Abstract views(3632)
  • HTML views(55)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return