Citation: ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun. Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1261-1266. doi: 10.3866/PKU.WHXB20110512 shu

Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites

ZHANG Yi ^1,2 ,
CHEN Biao ² ,
YANG Zu-Pei ^1, ,
ZHANG Zhi-Jun ^2,

1.
1. School of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, P. R. China;
2. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China

Received Date: 3 January 2011
Available Online: 31 March 2011
Fund Project: 国家自然科学基金(20873090, 21073224)资助项目 (20873090, 21073224)

Fe₃O₄ nanoparticle-graphene oxide (M ) composites were prepared by chemically binding carboxylic acid-modified Fe₃O₄ nanoparticles to polyethylenimine-functionalized graphene oxide ( ). The structure, morphology, and magnetic properties of the composites were characterized by transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), and vibrating sample magnetometry (VSM). The results show that the Fe₃O₄ nanoparticle content in the M composites can be easily controlled by changing the ratio of Fe₃O₄ nanoparticles to in the reaction mixture. The M composites obtained are superparamagnetic with high saturation magnetization, which can potentially be applied in magnetic targeted drug delivery, gene transport, magnetic resonance imaging, bioseparation, and magnetic guided removal of aromatic contaminants in waste water and in other fields.
- Graphene oxide,
- Fe₃O₄ nanoparticle,
- Composite,
- Controlled synthesis,
- Characterization
1. [1]
  
  (1) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
2. [2]
  (2) Shen, J. F.; Hu, Y. Z.; Shi, M.; Li, N.; Ma, H. W.; Ye, M. X. J. Phys. Chem. C 2010, 114, 1498.
3. [3]
  (3) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science 2004, 306, 666.
4. [4]
  (4) Berger, C.; Song, Z. M.; Li, T. B.; Li, X. B.; Ogbazghi, A. Y.; Feng, R.; Dai, Z. T.; Marchenkov, A. N.; Conrad, E. H. J. Phys. Chem. B 2004, 108, 19912.
5. [5]
  (5) Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Nature 2006, 442, 282.
6. [6]
  (6) Di, C. A.; Wei, D. C.; Yu, G.; Liu, Y. Q.; Guo, Y. L.; Zhu, D. B. Adv. Mater. 2008, 20, 3289.
7. [7]
  (7) Wu, J. S.; Pisula, W.; Mullen, K. Chem. Rev. 2007, 107, 718.
8. [8]
  (8) Huang, J.; Zhang, L. M.; Chen, B.; Ji, N.; Chen, F. H.; Zhang, Y.; Zhang Z. J. Nanoscale 2010, 2, 2733.
9. [9]
  (9) Zhang, X. Y.; Yang, X. Y.; Ma, Y. F.; Huang, Y.; Chen, Y. S. Journal of Nanoscience and Nanotechnology 2010, 10, 2984.
10. [10]
  (10) Yang, X. Y.; Zhang, X. Y.; Ma, Y. F.; Huang, Y.; Wangand, Y. S.; Chen, Y. S. J. Mater. Chem. 2009, 19, 2710.
11. [11]
  (11) Zhang, L. M.; Xia, J. G.; Zhao, Q. H.; Liu, L. W.; Zhang, Z. J. Small 2010, 6, 537.
12. [12]
  (12) Si, Y. C.; Samulski, E. T. Chem. Mater. 2008, 20, 6792.
13. [13]
  (13) Muszynski, R.; Seger, B.; Kamat, P. V. J. Phys. Chem. C 2008, 112, 5263.
14. [14]
  (14) Xu, C.; Wang, X.; Zhu, J. W. J. Phys. Chem. C 2008, 112, 19841.
15. [15]
  (15) Cong, H. P.; He, J. J.; Lu, Y.; Yu, S. H. Small 2010, 6, 169.
16. [16]
  (16) He, F.; Fan, J. T.; Ma, D.; Zhang, L. M.; Leung, C. W.; Chan, H. L. Carbon 2010, 48, 3139.
17. [17]
  (17) Zhang, Y.; Chen, B.; Zhang, L. M.; Huang, J.; Chen, F. H.; Yang, Z. P.; Yao. J. L.; Zhang, Z. J. Nanoscale, published online: 07 Feb, 2011, DOI: 10.1039/C0NR00776E.
18. [18]
  (18) Sun, S. H.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.; Wang, S. X.; Li, G. X. J. Am. Chem. Soc. 2004, 126, 273.
19. [19]
  (19) Chen, Z. P.; Zhang, Y.; Xu, K.; Xu, R. Z.; Liu, J. W.; Gu, N. Journal of Nanoscience and Nanotechnology 2008, 8, 12.
20. [20]
  (20) Hummers, W.; Offeman, R. J. Am. Chem. Soc. 1958, 80, 1339.
21. [21]
  (21) Zhu, C. X.; Peng, D. F. Speciality Petrochemicals 2010, 27, 57.
22. [22]
  (22) Paredes, J. I.; Villar-Rodil, S.; Solis-Fernandez, P.; Martinez-Alonso, A.; Tascon, J. M. D. Langmuir 2009, 25, 5957.
23. [23]
  (23) Bourlinos, A. B.; urnis, D.; Petridis, D.; Szabo, T.; Szeri, A.; Dekany, I. Langmuir 2003, 19, 6050.
24. [24]
  (24) Stankovich, S. S.; Piner, R. D.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2006, 44, 3342.
25. [25]
  (25) Chin, S. F.; Iyer, K. S.; Raston, C. L. Lab. Chip. 2008, 8, 439.
26. [26]
  (26) Rocchiccioli-Deltche, C.; Franck, R.; Cabuil, V.; Massart, R. J. Chem. Res. 1987, 5, 126.
27. [27]
  (27) Popplewell, J.; Sakhnini, L. J. Magn. Mater. 1995, 142, 72.
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
3. [3]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
4. [4]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
9. [9]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
10. [10]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
11. [11]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
14. [14]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
15. [15]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
16. [16]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
17. [17]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
18. [18]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
19. [19]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
20. [20]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

Get Citation

PDF

XML

Metrics

PDF Downloads(2452)
Abstract views(3548)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Controlled Synthesis and Characterization of the Structure and Property of Fe3O4 Nanoparticle-Graphene Oxide Composites

Metrics

通讯作者: 陈斌, bchen63@163.com

Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites