Citation: ZHANG Xiao-Jie, TANG Chang-Qing, JIN Zhi-Liang, LV ng-Xuan, LI Shu-Ben. Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO₂ Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1143-1148. doi: 10.3866/PKU.WHXB20110511 shu

Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO₂ Catalysts

1.
1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China;
2Department of Metallurgical and Chemical Engineering, Jiyuan Vocational and Technical Collage, Jiyuan, 454650, Henan Province, P. R. China

Received Date: 13 December 2010
Available Online: 31 March 2011
Fund Project: 国家重点基础研究发展规划 (973)(2007CB613305, 2009CB220003)资助项目 (973)(2007CB613305, 2009CB220003)

A novel efficient photoscatalytic system Eosin Y/Pt/SiO₂ for photocatalytic reduction of water to hydrogen under visible light irradiation was constructed. The effects of parameters, such as the surface physical property of SiO₂ (i.e., specific surface area), method of mixing Eosin Y and SiO₂, and light intensity on catalyst properties for hydrogen evolution were investigated systemically. With increase of SiO₂ specific surface area, the rate of hydrogen evolution increased. Either over high or low intensive irradiation is detrimental to obtain high quantum efficiency for hydrogen evolution. Compared to the Eosin Y adsorbed on SiO₂ by an impregnation method, the composite system in which Eosin Y mixed with SiO₂ physically in situ displayed higher rate and superior stability of hydrogen evolution.
- Eosin Y,
- Photosensitized hydrogen evolution,
- Silicon dioxide,
- Visible light
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沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO2 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO₂ Catalysts