Citation: WANG Sen-Lin, ZHANG Yi. Preparation and Electrocatalytic Performance of Ni-Mo/LaNi₅ Porous Composite Electrode toward Hydrogen Evolution Reaction[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1417-1423. doi: 10.3866/PKU.WHXB20110510 shu

Preparation and Electrocatalytic Performance of Ni-Mo/LaNi₅ Porous Composite Electrode toward Hydrogen Evolution Reaction

WANG Sen-Lin ,
ZHANG Yi

1.
Department of Applied Chemistry, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China

Received Date: 6 December 2010
Available Online: 31 March 2011

A Ni-Mo/LaNi₅ porous composite electrode was successfully prepared by composite electrodeposition and dissolution with a concentrated alkali solution. We found that the electrode consisted of two phases and a porous structure using scanning electron microscopy (SEM) and X-ray diffraction (XRD). In a 20% (w) NaOH solution the electrocatalytic properties toward hydrogen evolution reaction (HER) of the electrode was evaluated using electrochemical steady-state polarization curve and electrochemical impendence spectroscopy (EIS). As a result, the porous composite electrode had od electrocatalytic activity toward HER. We also found that the control step in the HER was the electrochemical de-absorption of hydrogen. The stability of the porous composite electrode was investigated by cycle voltammetry, discontinuity constant potential electrolysis over a long time, and differential scanning calorimetry (DSC). The results show that the stability of the porous composite electrode is od.
- Ni-Mo/LaNi₅,
- Porous composite electrode,
- Composite electrodeposition,
- Hydrogen evolution reaction,
- Stability
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrocatalytic Performance of Ni-Mo/LaNi5 Porous Composite Electrode toward Hydrogen Evolution Reaction

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通讯作者: 陈斌, bchen63@163.com

Preparation and Electrocatalytic Performance of Ni-Mo/LaNi₅ Porous Composite Electrode toward Hydrogen Evolution Reaction