Citation: LONG Jin-Xing, GUO Bin, LI Xue-Hui, WANG Fu-Rong, WANG Le-Fu. Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 995-999. doi: 10.3866/PKU.WHXB20110506 shu

Catalytic Decomposition of Cellulose in Cooperative Ionic Liquids

1.
School of Chemistry and Chemical Engineering, Pulp & Paper Engineering State Key Laboratory of China, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 12 January 2011
Available Online: 25 March 2011
Fund Project: 国家自然科学基金(20876055, 21076085) (20876055, 21076085)

Cellulose, the abundant and cost-ineffective resource, is considered to be a perfect alternative for the alleviation of energy crisis and environmental pollution. However, most processes for the treatment of cellulose are ri r currently as it is insoluble in water and conventional organic solvents due to its strong intra and inter-molecular hydrogen bonds, where the phase problem hampers its utilization widely. Here, we built a novel and efficient cooperative ionic liquid pairs system for the low temperature catalytic conversion of cellulose, which was constructed through the combination of an acidic ionic liquid catalyst and a cellulose soluble ionic liquid solvent. The catalytic decomposition behavior of microcrystal cellulose in this vi rous catalytic system was studied intensively by thermogravimetry (TG). Results show that the decomposition temperature of cellulose decreases greatly in all cooperative ionic liquid pairs, cellulose dissolved in ionic liquid solvents can be in situ catalytic decomposed by acidic ionic liquids. Furthermore, the decomposition temperature is dependent on the acidic strength of the ionic liquid catalysts, stronger acidity results in a lower decomposition temperature of the cellulose. Moreover, we found that cellulose can be decomposed at lower temperature when the ionic liquid with higher solubility of cellulose is used.
- Cooperative ionic liquid,
- Cellulose,
- Catalytic decomposition,
- Thermogravimetry,
- Acidic strength
1. [1]
  
  (1) Christensen, C. H.; Rass-Hansen, J.; Marsden, C. C.; Taarning, E.; Egeblad, K. Chemsuschem 2008, 1, 283.
2. [2]
  (2) Himmel, M. E.; Ding, S. Y.; Johnson, D. K.; Adney, W. S.; Nimlos, M. R.; Brady, J. W.; Foust, T. D. Science 2007, 315, 804.
3. [3]
  (3) Hoffert, M. I.; Caldeira, K.; Benford, G.; Criswell, D. R.; Green, C.; Herzog, H.; Jain, A. K.; Kheshgi, H. S.; Lackner, K. S.; Lewis, J. S.; Lightfoot, H. D.; Manheimer, W.; Mankins, J. C.; Mauel, M. E.; Perkins, L. J.; Schlesinger, M. E.; Volk, T.; Wigley, T. M. L. Science 2002, 298, 981.
4. [4]
  (4) Corma, A.; Iborra, S.; Velty, A. Chem. Rev. 2007, 107, 2411.
5. [5]
  (5) Huber, G. W.; Iborra, S.; Corma, A. Chem. Rev. 2006, 106, 4044.
6. [6]
  (6) Alonso, D. M.; Bond, J. Q.; Dumesic, J. A. Green Chem. 2010, 12, 1493.
7. [7]
  (7) Zou, S. P.; Wu, Y. L.; Yang, M. D.; Li, C.; Tong, J. M. Energy Fuels 2009, 23, 3753.
8. [8]
  (8) Balat, M. Energy Sources Part A. 2008, 30, 649.
9. [9]
  (9) Klemm, D.; Heublein, B.; Fink, H. P.; Bohn, A. Angew. Chem. Int. Edit. 2005, 44, 3358.
10. [10]
  (10) Lee, S. H.; Doherty, T. V.; Linhardt, R. J.; Dordick, J. S. Biotechnol. Bioeng. 2009, 102, 1368.
11. [11]
  (11) Swatloski, R. P.; Spear, S. K.; Holbrey, J. D.; Rogers, R. D. J. Am. Chem. Soc. 2002, 124, 4974.
12. [12]
  (12) Li, X. H.; Zhang, L.; Li, Q.; Geng, W. G.; Ye, Y. J.; Wang, L. F. Acta Phys. -Chim. Sin. 2004, 20, 1465.
13. [13]
  [李雪辉, 张磊, 李琼, 耿卫国, 叶玉嘉, 王乐夫. 物理化学学报, 2004, 20, 1465.]
14. [14]
  (13) Zhao, W. T.; Chen, H. X.; Zhou, J. J.; Liu, N. A. Acta Phys. -Chim. Sin. 2009, 25, 1756.
15. [15]
  [赵伟涛, 陈海翔, 周建军, 刘乃安. 物理化学学报, 2009, 25, 1756.]
16. [16]
  (14) Feng, J. L.; Zhang, J. G.; Zhang, T. L.; Cui, Y. Acta Phys. -Chim. Sin. 2010, 26, 2410.
17. [17]
  [冯金玲, 张建国, 张同来, 崔燕. 物理化学学报, 2010, 26, 2410.]
18. [18]
  (15) Meng, G. G.; Kong, D. J.; Qi, X. L.; Xu, Z. Q. Acta Phys. -Chim. Sin. 2010, 26, 3017.
19. [19]
  [蒙根, 孔德金, 祁晓岚, 许中强. 物理化学学报, 2010, 26, 3017.]
20. [20]
  (16) Lin, Y. C.; Cho, J.; Tompsett, G. A.; Westmoreland, P. R.; Huber, G. W. J. Phy. Chem. C 2009, 113, 20097.
21. [21]
  (17) Zhang, H.; Zhao, F. Q.; Yi, J. H.; Zhang, X. H.; Hu, R. Z.; Xu, S. Y.; Ren, X. N. Acta Phys. -Chim. Sin. 2008, 24, 2263.
22. [22]
  [张衡, 赵凤起, 仪建华, 张晓宏, 胡荣祖, 徐司雨, 任晓宁. 物理化学学报, 2008, 24, 2263.]
23. [23]
  (18) Chattopadhyay, J.; Kim, C.; Kim, R.; Pak, D. J. Ind. Eng. Chem. 2009, 15, 72.
24. [24]
  (19) Yu, Z. S.; Ma, X. Q.; Liu, A. Energy Convers. Manage. 2009, 50, 561.
25. [25]
  (20) Gui, J. Z.; Cong, X. H.; Liu, D.; Zhang, X. T.; Hu, Z. D.; Sun, Z. L. Catal. Commun. 2004, 5, 473.
26. [26]
  (21) Wang, W.; Shao, L.; Cheng, W.; Yang, J.; He, M. Catal. Commun. 2008, 9, 337.
27. [27]
  (22) Fei, Z. F.; Zhao, D. B.; Geldbach, T. J.; Scopelliti, R.; Dyson, P. J. Chem. Eur. J. 2004, 10, 4886.
28. [28]
  (23) Wasserscheid, P.; Sesing, M.; Korth, W. Green Chem. 2002, 4, 134.
29. [29]
  (24) Bonhote, P.; Dias, A. P.; Papageorgiou, N.; Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35, 1168.
30. [30]
  (25) Cole, A. C.; Jensen, J. L.; Ntai, I.; Tran, K. L. T.; Weaver, K. J.; Forbes, D. C.; Davis, J. H. J. Am. Chem. Soc. 2002, 124, 5962.
31. [31]
  (26) Adamovsky, O.; Kopp, R.; Hilscherova, K.; Babica, P.; Palikova, M.; Paskova, V.; Navratil, S.; Marsalek, B.; Blaha, L. Environ. Toxicol. Chem. 2007, 26, 2687.
32. [32]
  (27) Handy, S. T.; Okello, M.; Dickenson, G. Org. Lett. 2003, 5, 2513.
33. [33]
  (28) Yoshizawa-Fujita, M.; Johansson, K.; Newman, P.; MacFarlane, D. R.; Forsyth, M. Tetrahedron Lett. 2006, 47, 2755.
34. [34]
  (29) Li, X. H.; Duan, H. L.; Pan, J. T.; Wang, L. F. Chin. J. Anal. Chem. 2006, 34(Suppl. 1) , 192.
35. [35]
  [李雪辉, 段红丽, 潘锦添, 王乐夫. 分析化学, 2006, 34(Suppl. 1), 192.]
36. [36]
  (30) Thornazeau, C.; Olivier-Bourbi u, H.; Magna, L.; Luts, S.; Gilbert, B. J. Am. Chem. Soc. 2003, 125, 5264.
37. [37]
  (31) Kosan, B.; Michels, C.; Meister, F. Cellulose 2008, 15, 59.
38. [38]
  (32) Pinkert, A.; Marsh, K. N.; Pang, S. S.; Staiger, M. P. Chem. Rev. 2009, 109, 6712.
39. [39]
  (33) Ciolacu, D.; Popa, V. I. Cellul. Chem. Technol. 2006, 40, 445.
40. [40]
  (34) Fredlake, C. P.; Crosthwaite, J. M.; Hert, D. G.; Aki, S. N. V. K.; Brennecke, J. F. J. Chem. Eng. Data 2004, 49, 954.
41. [41]
  (35) Vitz, J.; Erdmenger, T.; Haensch, C.; Schubert, U. S. Green Chem. 2009, 11, 417.
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