Citation: ZHANG Hui-Min, HU Rui-Sheng, HU Jia-Nan, ZHANG Yu-Long. Preparation and Catalytic Activities of La₂CoAlO₆ for Methane Combustion[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1169-1175. doi: 10.3866/PKU.WHXB20110502 shu

Preparation and Catalytic Activities of La₂CoAlO₆ for Methane Combustion

1.
1. Key Laboratory of Rare Earth Materials Chemistry and Physics, School of Chemistry and Chemical Engineering, Inner Mon lia University, Hohhot 010021, P. R. China;
2. Western Research Institute, 365 N 9St, Laramie, Wyoming, USA

Received Date: 13 January 2011
Available Online: 24 March 2011
Fund Project: 国家自然科学基金(20763003) (20763003) 教育部春晖计划(Z2007-1-01029) (Z2007-1-01029)内蒙古自然科学基金(2008 0404 MS 0123)资助项目 (2008 0404 MS 0123)

A novel rare earth double perovskite-type catalyst (La₂CoAlO₆) was prepared by the sol-gel method using citric acid as complex agent. The catalyst was characterized by X-ray powder diffraction (XRD), H₂-temperature-programmed reduction (H₂-TPR), specific surface area (BET), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy, and magnetic property measurement. This catalyst was evaluated for methane combustion. The results showed that a single-phase rare earth double perovskite oxide La₂CoAlO₆ could be formed by calcination at 1100 °C for 3 h. La₂CoAlO₆ gives od catalytic activity for methane combustion. It has a light-off temperature (T₁₀) of 434.1 °C and a total conversion temperature (T₉₀) of 657.4 °C. Compared with the single rare earth perovskite-type oxides LaCoO₃ and LaAlO₃, the T₁₀ decreased by 56.5 and 138.2 °C, and T₉₀ decreased by 84.6 and 108.9 °C, respectively. The FT-IR results indicate that all the synthesized oxides possess perovskite-type structures. Furthermore, the La₂CoAlO₆ samples showed excellent catalytic activity for methane combustion, which could be related to the decrease in reduction temperature that was observed in the H₂-TPR experiments. This was probably because of the increased oxygen mobility that was promoted by the presence of aluminum. In addition, the rare earth double perovskite-type oxide La₂CoAlO₆ has a platelet morphology and is resistant to sintering. We also found that the double perovskite oxide La₂CoAlO₆ had special magnetic properties.
- Rare earth,
- Double perovskite,
- Single perovskite,
- Methane catalytic combustion,
- Sol-gel method
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Preparation and Catalytic Activities of La2CoAlO6 for Methane Combustion

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通讯作者: 陈斌, bchen63@163.com

Preparation and Catalytic Activities of La₂CoAlO₆ for Methane Combustion