Citation: YANG Zhi-Qiang, MAO Dong-Sen, WU Ren-Chun, YU Jun, WANG Qian. Preparation of CuO-Ce_0.6Zr_0.4O₂ by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1163-1168. doi: 10.3866/PKU.WHXB20110443 shu

Preparation of CuO-Ce_0.6Zr_0.4O₂ by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation

1.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China

Received Date: 22 December 2010
Available Online: 22 March 2011
Fund Project: 上海市教委重点学科建设项目(J51503)资助 (J51503)

A series of CuO-Ce_0.6Zr_0.4O₂ catalysts with different contents (0-25%, w) of CuO were prepared by microwave heating decomposition and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), N₂ adsorption-desorption (BET), and temperature-programmed reduction with hydrogen (H₂-TPR). The activities of the catalysts for CO oxidation were evaluated using a microreactor-gas chromatograph system. The results show that the CuO-Ce_0.6Zr_0.4O₂ catalyst exhibits the best catalytic activity for CO oxidation at a CuO content of 15%. Three copper species are present in the catalysts, i.e., highly dispersed, small and large CuO particles. The highly dispersed and small CuO particles are responsible for the promotion of catalytic activity while the large CuO particles inhibit catalytic activity.
- Microwave heating,
- Cu(NH₃)₄(OH)₂,
- CuO-Ce_0.6Zr_0.4O₂ catalyst,
- CO oxidation
1. [1]
  
  (1) Liu, Y.; Meng, M.; Yao, J. S.; Zha, Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 641.
2. [2]
  [刘咏, 孟明, 姚金松, 査宇清. 物理化学学报, 2007, 23, 641.]
3. [3]
  (2) Yu, J.; Wu, G. S.; Mao, D. S.; Lu, G. Z. Acta Phys. -Chim. Sin. 2008, 24, 1751.
4. [4]
  [俞俊, 吴贵升, 毛东森, 卢冠忠. 物理化学学报, 2008, 24, 1751.]
5. [5]
  (3) Zheng, X. C.; Wang, X. Y.; Yu, L. H.; Wang, S. R.; Wu, S. H. Prog. Chem. 2006, 18, 159.
6. [6]
  [郑修成, 王向宇, 于丽华, 王淑荣, 吴世华. 化学进展, 2006, 18, 159.]
7. [7]
  (4) Liang, F. X.; Zhu, H. Q.; Qin, Z. F.; Wang, G. F.; Wang, J. G. Prog. Chem. 2008, 20, 1453.
8. [8]
  [梁飞雪, 朱华青, 秦张峰, 王国富, 王建国. 化学进展, 2008, 20, 1453.]
9. [9]
  (5) Wang, S. P.; Zheng, X. C.; Wang, X. Y.; Wang, S. R.; Zhang, S. M.; Yu, L. H.; Huang, W. P.; Wu, S. H. Catal. Lett. 2005, 105, 163.
10. [10]
  (6) Wang, S. P.; Wang, X. Y.; Huang, J.; Zhang, S. M.; Wang, S. R.; Wu, S. H. Catal. Commun. 2007, 8, 231.
11. [11]
  (7) Wang, S. P.; Zhang, T. Y.; Su, Y.; Wang, S. R.; Zhang, S. M.; Zhu, B. L.; Wu, S. H. Catal. Lett. 2008, 121, 70.
12. [12]
  (8) Jiang, X. Y.; Zhou, R. X.; Chen, Y.; Lou, L. P.; Zheng, X. M. J. Zhejiang Univ.: Science Edition 2001, 28, 653.
13. [13]
  [蒋晓原, 周仁贤, 陈煜, 楼莉萍, 郑小明. 浙江大学学报: 理学版, 2001, 28, 653.]
14. [14]
  (9) Jiang, X. Y.; Chen, Y.; Zhou, R. X.; Zheng, X. M. J. Fuel Chem. Technol. 2001, 29(Suppl.), 122.
15. [15]
  [蒋晓原, 陈煜, 周仁贤, 郑小明. 燃料化学学报(增刊), 2001, 29, 122.]
16. [16]
  (10) Wang, S. P.; Wang, X. Y.; Zheng, X. C.; Wang, S. R.; Zhang, S. M.; Huang, W. P.; Wu, S. H. React. Kinet. Catal. Lett. 2006, 89, 37.
17. [17]
  (11) Luo, M. F.; Zheng, X. M. Acta Chem. Scand. 1998, 52, 1183.
18. [18]
  (12) Yang, Z. Q.; Mao, D. S.; Zhu, H. L.; Lu, G. Z. Chin. J. Catal. 2009, 30, 997.
19. [19]
  [杨志强, 毛东森, 朱慧琳, 卢冠忠. 催化学报, 2009, 30, 997.]
20. [20]
  (13) Martinez-Arias, A.; Fernandez-Garcia, M.; Galvez, O.; Coronado, J. M.; Anderson, J. A.; Conesa, J. C.; Soria, J.; Munuera, G. J. Catal. 2000, 195, 207.
21. [21]
  (14) Chen, H. L.; Zhu, H. Y.; Wu, Y.; Gao, F.; Dong, L.; Zhu, J. J. J. Mol. Catal. A 2006, 255, 254.
22. [22]
  (15) Zhu, J.; Zhang, L. L.; Deng, Y.; Liu, B.; Dong, L. H.; Gao, F.; Sun, K. Q.; Dong, L.; Chen, Y. Appl. Catal. B 2010, 96, 449.
23. [23]
  (16) Ayastuy, J. L.; Gurbani, A.; nzalez-Marcos, M. P.; Gutierrez- Ortiz, M. A. Appl. Catal. A 2010, 387, 119.
24. [24]
  (17) Hong, Q. H.; Song, Y. P.; Jia, A. P.; Pu, Z. Y.; Luo, M. F. J. Mol. Catal. (China) 2008, 22, 429.
25. [25]
  [洪庆红, 宋宇鹏, 贾爱平, 普志英, 罗孟飞. 分子催化, 2008, 22, 429.]
26. [26]
  (18) Hong, Q. H.; Lin, H.; Song, Y. P.; Wu, C. S. J. Jinhua Coll. Prof. Technol. 2009, 9, 49.
27. [27]
  [洪庆红, 林鸿, 宋宇鹏, 吴昌胜. 金华职业技术学院学报, 2009, 9, 49.]
28. [28]
  (19) Wang, E. G.; Chen, S. Y. J. Chin. Rare Earth Soc. 2001, 19, 17.
29. [29]
  [王恩过, 陈诵英. 中国稀土学报, 2001, 19, 17.]
30. [30]
  (20) Wang, E. G.; Chen, S. Y. J. Rare Earths 2002, 20, 533.
31. [31]
  (21) Wang, J. P.; Wang, E. G.; Chen, S. Y. Coal Conv. 2000, 23, 88.
32. [32]
  [王建平, 王恩过, 陈诵英. 煤炭转化, 2000, 23, 88.]
33. [33]
  (22) Cao, J. L; Wang, Y.; Zhang, T. Y.; Wu, S. H.; Yuan, Z. Y. Appl. Catal. B 2008, 78, 120.
34. [34]
  (23) Yang, Z. Q.; Mao, D. S.; Guo, Q. S.; Gu, L. Acta Phys.-Chim. Sin. 2010, 26, 3278.
35. [35]
  [杨志强, 毛东森, 郭强胜, 顾蕾. 物理化学学报, 2010, 26, 3278.]
36. [36]
  (24) Yang, Z. Q.; Mao, D. S.; Zhu, H. L.; Lu, G. Z. Chin. J. Inorg. Chem. 2009, 25, 812.
37. [37]
  [杨志强, 毛东森, 朱慧琳, 卢冠忠. 无机化学学报, 2009, 25, 812.]
38. [38]
  (25) Mao, D. S.; Tao, L. H.; Wang, Q.; Guo, Y. L.; Lu, G. Z. Chin. J. Inorg. Chem. 2010, 26, 447.
39. [39]
  [毛东森, 陶丽华, 王倩, 郭杨龙, 卢冠忠. 无机化学学报, 2010, 26, 447.]
40. [40]
  (26) Escribano, V. S.; Martínez, C. H.; López, E. F.; Amores, J. M. G.; Busca, G. Catal. Commun. 2009, 10, 861.
41. [41]
  (27) Cai, C.; Xue, P. J. Ningxia Univ.: Natural Science Edition 2005, 26, 345.
42. [42]
  [蔡超, 薛屏. 宁夏大学学报: 自然科学版, 2005, 26, 345.]
43. [43]
  (28) Guo, X. K.; Jia, H. J.; Fang, Q. Y.; Li, W. Y.; Liu, W. M. Chin. J. Catal. 2009, 30, 124.
44. [44]
  [郭锡坤, 贾海建, 范倩玉, 李文衍, 刘伟明. 催化学报, 2009, 30, 124.]
45. [45]
  (29) Ma, L.; Luo, M. F.; Chen, S. Y. Appl. Catal. A 2003, 242, 151.
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of CuO-Ce0.6Zr0.4O2 by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation

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通讯作者: 陈斌, bchen63@163.com

Preparation of CuO-Ce_0.6Zr_0.4O₂ by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation