Citation: LI Yi, ZOU Ai-Hua, YE Ru-Qiang, MU Bo-Zhong. Effects of Molecular Structure on Surfactin Micellization Activity[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1128-1134. doi: 10.3866/PKU.WHXB20110436 shu

Effects of Molecular Structure on Surfactin Micellization Activity

1.
Institute of Applied Chemistry, East China University of Science and Technology, Shanghai 200237

Received Date: 15 November 2010
Available Online: 17 March 2011
Fund Project: 博士点新教师基金项目(200802511024) (200802511024)上海市国际合作项目(071607014)资助 (071607014)

We produced a group of surfactin isoforms using Bacillus subtilis HSO121. The micellization activity properties such as surface and interfacial tensions, micropolarity, micelle size distribution and morphology of this group of surfactin micellar solutions were investigated by surface and interfacial tension, fluorescence, dynamic light-scattering (DLS), and freeze-fracture transmission electron microscopy (FF-TEM) measurements. With an increase in the chain length, we found that the surface and interfacial activities of the surfactins increased and the surfactins tended to form larger micelle aggregates.
- Surfactin,
- Micelle,
- Fluorescence,
- Dynamic light-scattering,
- Freeze-fracture transmission electron microscopy
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沈阳化工大学材料科学与工程学院沈阳 110142