Citation: TIAN Li, ZHOU ng-Bing, LI Zhen-Hua, PEI Yan, QIAO Ming-Hua, FAN Kang-Nian. ld Supported on Aminosilane-Functionalized SBA-15 for Chemoselective Hydrogenation of Crotonaldehyde[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 946-952. doi: 10.3866/PKU.WHXB20110434 shu

ld Supported on Aminosilane-Functionalized SBA-15 for Chemoselective Hydrogenation of Crotonaldehyde

1.
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China

Received Date: 17 December 2010
Available Online: 17 March 2011
Fund Project: 国家自然科学基金(21073043, 20803011) (21073043, 20803011) 教育部新世纪优秀人才支持计划(NCET-08-0126) (NCET-08-0126) 上海市科委科技基金(10JC1401800, 08DZ2270500) (10JC1401800, 08DZ2270500)石油化工催化材料与反应工程国家重点实验室(RIPP, SINOPEC)开放基金课题资助项目 (RIPP, SINOPEC)

Three kinds of aminosilane (APTS: 3-aminopropyltrimethoxysilane, TPED: N-[3-(trimethoxysilyl)-propylethylene]diamine, TPDT: trimethoxysilyl propyl diethylenetriamine) functionalized mesoporous SBA- 15 molecular sieves (denoted APTS-SBA-15, TPED-SBA-15 and TPDT-SBA-15) were synthesized by post-grafting. Using the static interaction between the amino group and chloroauric acid followed by chemical reduction, the ld nanoparticles were immobilized into the channels of SBA-15. The Au/aminosilane-SBA-15 catalysts were systematically characterized by N₂ physisorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The liquid phase hydrogenation of crotonaldehyde to crotyl alcohol (CROL) was used to investigate the effect of aminosilanes on the catalytic performance of the Au/amine-SBA-15 catalysts. The results revealed that the electron-donating ability of the aminosilane determines the selectivity towards the hydrogenation of the C＝O bond on the ld catalyst. A stronger aminosilane electron-donating ability results in higher electron density on the ld active sites, which leads to the higher selectivity and yield of CROL.
- Au,
- SBA-15,
- Aminosilane,
- Crotonaldehyde,
- Selective hydrogenation,
- Crotyl alcohol
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