Citation:
YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica,
;2011, 27(05): 1122-1127.
doi:
10.3866/PKU.WHXB20110433
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Nano TiO2 films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH2)3CH3)4 as a precursor. The properties of the TiO2 films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO2 films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO2 films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO2 prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.
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-
-
[1]
(1) Bartók, M.; Molnár, Á. The Chemistry of Double-Bonded Functional Groups (Suppl. A3), Patai, S. Ed.; Wiley: New York, 1997; p 843.
-
[2]
(2) Gallezot, P.; Richard, D. Catal. Rev.-Sci. Eng. 1998, 40, 81.
-
[3]
(3) Ponec, V. Appl. Catal. A 1997, 149, 27.
-
[4]
(4) Hirschl, R.; Delbecq, F.; Sautet, P.; Hafner, J. J. Catal. 2003, 217, 354.
-
[5]
(5) Claus, P.; Brückner, A.; Mohr, C.; Hofmeister, H. J. Am. Chem. Soc. 2000, 122, 11430.
-
[6]
(6) Loffreda, D.; Delbecq, F.; Vigné, F.; Sautet, P. J. Am. Chem. Soc. 2006, 128, 1316.
-
[7]
(7) Milone, C.; In glia, R.; Schipilliti, L.; Crisafulli, C.; Neri, G.; Galvagno, S. J. Catal. 2005, 236, 80.
-
[8]
(8) Milone, C.; Crisafulli, C.; In glia, R.; Schipilliti, L.; Galvagno, S. Catal. Today 2007, 122, 341.
-
[9]
(9) Yang, Q. Y.; Zhu, Y.; Tian, L.; Pei, Y.; Qiao, M. H.; Fan, K. N. Acta Phys. -Chim. Sin. 2009, 25, 1853. [杨秋芸, 朱 渊, 田莉, 裴 燕, 乔明华, 范康年. 物理化学学报, 2009, 25, 1853.]
-
[10]
(10) Baillie, J. E.; Hutching, G. J. Chem. Commun. 1999, No. 21, 2151.
-
[11]
(11) Okumura, M.; Akita, T.; Haruta, M. Catal. Today 2002, 74, 265.
-
[12]
(12) Schimpf, S.; Lucas, M.; Mohr, C.; Rodemerck, U.; Brückner, A.; Radnik, J.; Hofmeister, H.; Claus, P. Catal. Today 2002, 72, 63.
-
[13]
(13) Pei, Y.; Guo, P. J.; Zhu, L. J.; Yan, S. R.; Qiao, M. H.; Fan, K. N. Stud. Surf. Sci. Catal. 2007, 170, 1174.
-
[14]
(14) Yang, Q. Y.; Zhu, Y.; Tian, L.; Xie, S. H.; Pei, Y.; Li, H.; Li, H. X.; Qiao, M. H.; Fan, K. N. Appl. Catal. A 2009, 369, 67.
-
[15]
(15) Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
-
[16]
(16) Zhang, L. X.; Yu, C. C.; Zhao, W. R.; Hua, Z. L.; Chen, H. R.; Li, L.; Shi, J. L. J. Non-Cryst. Solids 2007, 353, 4055.
-
[17]
(17) Chastain, J. andbook of X-ray Photoelectron Spectroscopy; Perkin Elmer Corporation: Eden Prairie, 1992; p 182.
-
[18]
(18) Zanella, R.; Louis, C.; Giorgio, S.; Touroude, R. J. Catal. 2004, 223, 328.
-
[19]
(19) Bailie, J. E.; Abdullah, H. A.; Anderson, J. A.; Rochester, C. H.; Richardson, N. V.; Hodge, N.; Zhang, J. G.; Burrows, A.; Kiely, C. J.; Hutchings, G. J. Phys. Chem. Chem. Phys. 2001, 3, 4113.
-
[20]
(20) Mohr, C.; Hofmeister, H.; Radnik, J.; Claus, P. J. Am. Chem. Soc. 2003, 125, 1905.
-
[21]
(21) Delbecq, F.; Sautet, P. J. Catal. 1995, 152, 217.
-
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