Citation: YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1122-1127. doi: 10.3866/PKU.WHXB20110433 shu

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization

1.
1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. Key Laboratory of Shanghai Colleges and Universities for Electric Power Corrosion Control and Applied Electrochemistry, Department of Energy Source and Environment Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R. China

Received Date: 7 December 2010
Available Online: 17 March 2011
Fund Project: 国家自然科学基金(50571085, 20773100, 21003089) (50571085, 20773100, 21003089)国家高技术研究发展专项(2009AA03Z327)资助项目 (2009AA03Z327)

Nano TiO₂ films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH₂)₃CH₃)₄ as a precursor. The properties of the TiO₂ films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO₂ films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO₂ films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO₂ prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.
- Hydrothermal crystallization,
- Anatase TiO₂,
- Corrosion and protection
1. [1]
  
  (1) Bartók, M.; Molnár, Á. The Chemistry of Double-Bonded Functional Groups (Suppl. A3), Patai, S. Ed.; Wiley: New York, 1997; p 843.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev.-Sci. Eng. 1998, 40, 81.
3. [3]
  (3) Ponec, V. Appl. Catal. A 1997, 149, 27.
4. [4]
  (4) Hirschl, R.; Delbecq, F.; Sautet, P.; Hafner, J. J. Catal. 2003, 217, 354.
5. [5]
  (5) Claus, P.; Brückner, A.; Mohr, C.; Hofmeister, H. J. Am. Chem. Soc. 2000, 122, 11430.
6. [6]
  (6) Loffreda, D.; Delbecq, F.; Vigné, F.; Sautet, P. J. Am. Chem. Soc. 2006, 128, 1316.
7. [7]
  (7) Milone, C.; In glia, R.; Schipilliti, L.; Crisafulli, C.; Neri, G.; Galvagno, S. J. Catal. 2005, 236, 80.
8. [8]
  (8) Milone, C.; Crisafulli, C.; In glia, R.; Schipilliti, L.; Galvagno, S. Catal. Today 2007, 122, 341.
9. [9]
  (9) Yang, Q. Y.; Zhu, Y.; Tian, L.; Pei, Y.; Qiao, M. H.; Fan, K. N. Acta Phys. -Chim. Sin. 2009, 25, 1853. [杨秋芸, 朱渊, 田莉, 裴燕, 乔明华, 范康年. 物理化学学报, 2009, 25, 1853.]
10. [10]
  (10) Baillie, J. E.; Hutching, G. J. Chem. Commun. 1999, No. 21, 2151.
11. [11]
  (11) Okumura, M.; Akita, T.; Haruta, M. Catal. Today 2002, 74, 265.
12. [12]
  (12) Schimpf, S.; Lucas, M.; Mohr, C.; Rodemerck, U.; Brückner, A.; Radnik, J.; Hofmeister, H.; Claus, P. Catal. Today 2002, 72, 63.
13. [13]
  (13) Pei, Y.; Guo, P. J.; Zhu, L. J.; Yan, S. R.; Qiao, M. H.; Fan, K. N. Stud. Surf. Sci. Catal. 2007, 170, 1174.
14. [14]
  (14) Yang, Q. Y.; Zhu, Y.; Tian, L.; Xie, S. H.; Pei, Y.; Li, H.; Li, H. X.; Qiao, M. H.; Fan, K. N. Appl. Catal. A 2009, 369, 67.
15. [15]
  (15) Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
16. [16]
  (16) Zhang, L. X.; Yu, C. C.; Zhao, W. R.; Hua, Z. L.; Chen, H. R.; Li, L.; Shi, J. L. J. Non-Cryst. Solids 2007, 353, 4055.
17. [17]
  (17) Chastain, J. andbook of X-ray Photoelectron Spectroscopy; Perkin Elmer Corporation: Eden Prairie, 1992; p 182.
18. [18]
  (18) Zanella, R.; Louis, C.; Giorgio, S.; Touroude, R. J. Catal. 2004, 223, 328.
19. [19]
  (19) Bailie, J. E.; Abdullah, H. A.; Anderson, J. A.; Rochester, C. H.; Richardson, N. V.; Hodge, N.; Zhang, J. G.; Burrows, A.; Kiely, C. J.; Hutchings, G. J. Phys. Chem. Chem. Phys. 2001, 3, 4113.
20. [20]
  (20) Mohr, C.; Hofmeister, H.; Radnik, J.; Claus, P. J. Am. Chem. Soc. 2003, 125, 1905.
21. [21]
  (21) Delbecq, F.; Sautet, P. J. Catal. 1995, 152, 217.
1. [1]
  Shuyong Zhang , Shu'e Song . Ideological and Political Case Design of Experiment of Corrosion and Protection Linking with National Major Projects. University Chemistry, 2024, 39(2): 57-60. doi: 10.3866/PKU.DXHX202304078
2. [2]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
3. [3]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
4. [4]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
5. [5]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
6. [6]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
7. [7]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
8. [8]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
9. [9]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
10. [10]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
11. [11]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
12. [12]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
13. [13]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
14. [14]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
15. [15]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
16. [16]
  Jiatong Li , Linlin Zhang , Peng Huang , Chengjun Ge . Carbon bridge effects regulate TiO₂–acrylate fluoroboron coatings for efficient marine antifouling. Chinese Chemical Letters, 2025, 36(2): 109970-. doi: 10.1016/j.cclet.2024.109970
17. [17]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
18. [18]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
19. [19]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
20. [20]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

Get Citation

PDF

XML

Metrics

PDF Downloads(1453)
Abstract views(2268)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization

Metrics

通讯作者: 陈斌, bchen63@163.com

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization