Citation: YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1122-1127. doi: 10.3866/PKU.WHXB20110433 shu

Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization

  • Received Date: 7 December 2010
    Available Online: 17 March 2011

    Fund Project: 国家自然科学基金(50571085, 20773100, 21003089) (50571085, 20773100, 21003089)国家高技术研究发展专项(2009AA03Z327)资助项目 (2009AA03Z327)

  • Nano TiO2 films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH2)3CH3)4 as a precursor. The properties of the TiO2 films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO2 films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO2 films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO2 prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.

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