Citation: YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1122-1127. doi: 10.3866/PKU.WHXB20110433 shu

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization

1.
1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. Key Laboratory of Shanghai Colleges and Universities for Electric Power Corrosion Control and Applied Electrochemistry, Department of Energy Source and Environment Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R. China

Received Date: 7 December 2010
Available Online: 17 March 2011
Fund Project: 国家自然科学基金(50571085, 20773100, 21003089) (50571085, 20773100, 21003089)国家高技术研究发展专项(2009AA03Z327)资助项目 (2009AA03Z327)

Nano TiO₂ films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH₂)₃CH₃)₄ as a precursor. The properties of the TiO₂ films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO₂ films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO₂ films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO₂ prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.
- Hydrothermal crystallization,
- Anatase TiO₂,
- Corrosion and protection
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization

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通讯作者: 陈斌, bchen63@163.com

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization