Citation: YUN Hong, LIN Chang-Jian, DU Rong-Gui. Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1122-1127. doi: 10.3866/PKU.WHXB20110433 shu

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization

1.
1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. Key Laboratory of Shanghai Colleges and Universities for Electric Power Corrosion Control and Applied Electrochemistry, Department of Energy Source and Environment Engineering, Shanghai University of Electric Power, Shanghai 200090, P. R. China

Received Date: 7 December 2010
Available Online: 17 March 2011
Fund Project: 国家自然科学基金(50571085, 20773100, 21003089) (50571085, 20773100, 21003089)国家高技术研究发展专项(2009AA03Z327)资助项目 (2009AA03Z327)

Nano TiO₂ films were applied to the surface of stainless steel (SS) by sol-gel and hydrothermal crystallization using Ti(O(CH₂)₃CH₃)₄ as a precursor. The properties of the TiO₂ films were determined by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Auger electron spectroscopy (AES). The corrosion performance of the TiO₂ films was evaluated by electrochemical impedance spectroscopy (EIS) and polarization measurements. Anatase TiO₂ films prepared by hydrothermal crystallization at 170 °C showed similar crystallization to those prepared by conventional calcination at 450 °C. The TiO₂ prepared by the two methods were, however, obviously different from the surface structure and the material prepared by hydrothermal crystallization showed better anticorrosion performance in 3.5% (w) NaCl solution compared with the material prepared by calcination.
- Hydrothermal crystallization,
- Anatase TiO₂,
- Corrosion and protection
1. [1]
  
  (1) Bartók, M.; Molnár, Á. The Chemistry of Double-Bonded Functional Groups (Suppl. A3), Patai, S. Ed.; Wiley: New York, 1997; p 843.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev.-Sci. Eng. 1998, 40, 81.
3. [3]
  (3) Ponec, V. Appl. Catal. A 1997, 149, 27.
4. [4]
  (4) Hirschl, R.; Delbecq, F.; Sautet, P.; Hafner, J. J. Catal. 2003, 217, 354.
5. [5]
  (5) Claus, P.; Brückner, A.; Mohr, C.; Hofmeister, H. J. Am. Chem. Soc. 2000, 122, 11430.
6. [6]
  (6) Loffreda, D.; Delbecq, F.; Vigné, F.; Sautet, P. J. Am. Chem. Soc. 2006, 128, 1316.
7. [7]
  (7) Milone, C.; In glia, R.; Schipilliti, L.; Crisafulli, C.; Neri, G.; Galvagno, S. J. Catal. 2005, 236, 80.
8. [8]
  (8) Milone, C.; Crisafulli, C.; In glia, R.; Schipilliti, L.; Galvagno, S. Catal. Today 2007, 122, 341.
9. [9]
  (9) Yang, Q. Y.; Zhu, Y.; Tian, L.; Pei, Y.; Qiao, M. H.; Fan, K. N. Acta Phys. -Chim. Sin. 2009, 25, 1853. [杨秋芸, 朱渊, 田莉, 裴燕, 乔明华, 范康年. 物理化学学报, 2009, 25, 1853.]
10. [10]
  (10) Baillie, J. E.; Hutching, G. J. Chem. Commun. 1999, No. 21, 2151.
11. [11]
  (11) Okumura, M.; Akita, T.; Haruta, M. Catal. Today 2002, 74, 265.
12. [12]
  (12) Schimpf, S.; Lucas, M.; Mohr, C.; Rodemerck, U.; Brückner, A.; Radnik, J.; Hofmeister, H.; Claus, P. Catal. Today 2002, 72, 63.
13. [13]
  (13) Pei, Y.; Guo, P. J.; Zhu, L. J.; Yan, S. R.; Qiao, M. H.; Fan, K. N. Stud. Surf. Sci. Catal. 2007, 170, 1174.
14. [14]
  (14) Yang, Q. Y.; Zhu, Y.; Tian, L.; Xie, S. H.; Pei, Y.; Li, H.; Li, H. X.; Qiao, M. H.; Fan, K. N. Appl. Catal. A 2009, 369, 67.
15. [15]
  (15) Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc. 1998, 120, 6024.
16. [16]
  (16) Zhang, L. X.; Yu, C. C.; Zhao, W. R.; Hua, Z. L.; Chen, H. R.; Li, L.; Shi, J. L. J. Non-Cryst. Solids 2007, 353, 4055.
17. [17]
  (17) Chastain, J. andbook of X-ray Photoelectron Spectroscopy; Perkin Elmer Corporation: Eden Prairie, 1992; p 182.
18. [18]
  (18) Zanella, R.; Louis, C.; Giorgio, S.; Touroude, R. J. Catal. 2004, 223, 328.
19. [19]
  (19) Bailie, J. E.; Abdullah, H. A.; Anderson, J. A.; Rochester, C. H.; Richardson, N. V.; Hodge, N.; Zhang, J. G.; Burrows, A.; Kiely, C. J.; Hutchings, G. J. Phys. Chem. Chem. Phys. 2001, 3, 4113.
20. [20]
  (20) Mohr, C.; Hofmeister, H.; Radnik, J.; Claus, P. J. Am. Chem. Soc. 2003, 125, 1905.
21. [21]
  (21) Delbecq, F.; Sautet, P. J. Catal. 1995, 152, 217.
1. [1]
  Shuyong Zhang , Shu'e Song . Ideological and Political Case Design of Experiment of Corrosion and Protection Linking with National Major Projects. University Chemistry, 2024, 39(2): 57-60. doi: 10.3866/PKU.DXHX202304078
2. [2]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
5. [5]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
6. [6]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
7. [7]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
8. [8]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
9. [9]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
10. [10]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
11. [11]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
12. [12]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
13. [13]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
14. [14]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
15. [15]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
16. [16]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
17. [17]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
18. [18]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
19. [19]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
20. [20]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019

Get Citation

PDF

XML

Metrics

PDF Downloads(1453)
Abstract views(2209)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Anticorrosion Properties of Nano Anatase TiO2 Films Derived from Sol-Gel and Hydrothermal Crystallization

Metrics

通讯作者: 陈斌, bchen63@163.com

Anticorrosion Properties of Nano Anatase TiO₂ Films Derived from Sol-Gel and Hydrothermal Crystallization