Citation: MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui. Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 893-899. doi: 10.3866/PKU.WHXB20110431 shu

Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 17 November 2010
Available Online: 14 March 2011
Fund Project: 教育部新世纪优秀人才计划(NCET-08-0075)资助项目 (NCET-08-0075)

Manganese dioxide (MnO₂) was synthesized using a fluid phase method with potassium permanganate and manganous acetate as precursors. The obtained MnO₂ was treated thermally at different temperatures. The structural transformation of MnO₂, its electrochemical behavior as an electrode material for use in a supercapacitor were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), N2 physical adsorption, thermogravimetry (TG), cyclic voltammetry, and galvanostastic charge-discharge. The results indicate that the synthesized MnO₂ can be assigned to its α phase and that it possesses a mesoporous feature with a high surface area of up to 253 m²·g^-1. After a low temperature thermal treatment (<350 °C), the manganese oxide retained its α-MnO₂ crystal structure and its specific surface area was found to be approximately 170 m²·g^-1. The specific capacitance of the single electrode increased from 267 F·g^-1 for untreated MnO₂ to 286 F·g^-1 for the sample treated at 250 °C. However, high temperature thermal treatment (>450 °C) results in a transformation of the manganese oxide structure to α-Mn₂O₃ and then to α-Mn₃O₄. Additionally, the surface area reduced to ca 30 m²·g^-1 and this lead to a dramatic decrease in the specific capacitance of manganese oxide. The electrochemical cycling stability of manganese oxide improved noticeably after low temperature thermal treatment and the electrode retained a od rate performance at a scan rate of 50 mV·s^-1.
- Manganese dioxide,
- Supercapacitor,
- Electrode material,
- Thermal treatment
1. [1]
  
  (1) Miller, J. R.; Simon, P. Science 2008, 321, 651.
2. [2]
  (2) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Kluwer Academic Plenum Publishers: New York, 1999.
3. [3]
  (3) Zheng, J. P.; Cygan, P. J.; Jow, T. R. J. Electrochem. Soc. 1995, 142(8): 2699.
4. [4]
  (4) Brousse, T.; Taberna, P. L.; Crosnier, O.; Dugas, Romain.; Guillemet, P.; Scudeller, Y.; Zhou, Y. K.; Favier, F.; Bélanger, D.; Simon, P. J.Power Sources. 2007, 173, 633.
5. [5]
  (5) Brousse, T.; Toupin, M.; Dugas, R.; Athouël, L.; Crosiner, O.; Bélanger, D. Electrochem. Soc. 2006, 153, A2171.
6. [6]
  (6) Toupin, M.; Brousse, T.; Belanger, D. Chem. Mater. 2004, 16, 3184.
7. [7]
  (7) Jones, D. J.; Wortham, E.; Rozière, J.; Favier, F.; Pascal, J. L.; Monconduit, L. Phys. Chem. Solids. 2004, 65, 235.
8. [8]
  (8) Chin, S. F.; Pang, S. C.; Anderson, M. A. Electrochem. Soc. 2000, 147, A379.
9. [9]
  (9) Pang, S. C.; Anderson, M. A.; Chapman, T. W. Electrochem. Soc. 2002, 149, A379.
10. [10]
  (10) Shinomiya, T.; Gupta, V.; Miura, N. Electrochim Acta 2006, 51, 4412.
11. [11]
  (11) Qu, D.; Shi, H. J.Power. Source. 1998, 74, 99.
12. [12]
  (12) Qu, D. J. Power Sources. 2002, 109, 403.
13. [13]
  (13) Xia, X. Battery Bimonthly 2006, 36, 195.
14. [14]
  [夏熙. 电池, 2006, 36, 195.]
15. [15]
  (14) Wagner, C. D.; Riggs, W. M.; Muilenberg, G. E. Handbook of X-Ray Photoelectron Spectroscopy－A Reference Book of Standard Data for Use in X-Ray Photoelectron Spectroscopy, Perkin-Elmer Corporation and Physical Electronics Division Publishers: Eden Prairie, Minn, 1979.
16. [16]
  (15) Tian, Y.; Yan, J.W.; Liu, X. X.; Xue, R.;Yi, B. L. Acta Phys.-Chim. Sin. 2010, 26(8), 2151.
17. [17]
  [田颖, 阎景旺, 刘小雪, 薛荣, 衣宝廉. 物理化学学学报, 2010, 26(8), 2151.]
18. [18]
  (16) Kozawa, A. The manuel of Manganese Dioxide; Sichuan Science and Technology Press: Chen Du, 1994: 79-80; translated by Xia, Y.
19. [19]
  [Kozawa, A. 二氧化锰手册. 夏熙, 译. 成都: 四川科技出版社, 1994: 79-80.]
20. [20]
  (17) Liu , K. C.; Anderson, M. A. J. Electrochem. Soc. 1996, 143, 124.
21. [21]
  (18) Subramanian, V.; Zhu, H.; Wei, B. J. Power Sources 2006, 159, 361.
1. [1]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
9. [9]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
10. [10]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
11. [11]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
12. [12]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
13. [13]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
14. [14]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
15. [15]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
16. [16]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
17. [17]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
20. [20]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040

Get Citation

PDF

XML

Metrics

PDF Downloads(1669)
Abstract views(2415)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142