Citation: PENG Yue-Hua, ZHOU Hai-Qing, LIU Xiang-Heng, HE Xiong-Wu, ZHAO Ding, HAI Kuo, ZHOU Wei-Chang, YUAN Hua-Jun, TANG Dong-Sheng. Preparation of Sn₂S₃ One-Dimensional Nanostructure Arrays by Chemical Vapor Deposition[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1249-1253. doi: 10.3866/PKU.WHXB20110430 shu

Preparation of Sn₂S₃ One-Dimensional Nanostructure Arrays by Chemical Vapor Deposition

1.
Key Laboratory of Low-dimensional Quantum Structures and Quantum Control of Ministry of Education, College of Physics and Information Science, Hunan Normal University, Changsha 410081, P. R. China

Received Date: 25 October 2010
Available Online: 14 March 2011
Fund Project: 教育部新世纪优秀人才支持计划(NCET-07-0278) (NCET-07-0278)湖南省杰出青年基金(08JJ1001) (08JJ1001)湖南省自然科学基金(07JJ6009) (07JJ6009)湖南师范大学青年优秀人才培养计划(070623)资助 (070623)

We prepared large-area, vertically aligned Sn₂S₃ one-dimensional nanostructure arrays using tin and sulfur powder as reactants on a lead-plated silicon substrate by chemical vapor deposition (CVD). Scanning electron microscopy (SEM) showed that these Sn₂S₃ nanowires had diameters around 100 nm and lengths of several microns. X-ray diffraction (XRD) results indicated that the obtained Sn₂S₃ nanowires were composed of an orthorhombic phase with very od crystallinity, and grow in the [002] direction. Ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy revealed that they are direct-bandgap semiconductors with a bandgap of 2.0 eV. The growth of Sn₂S₃ nanowires is verned by the vapor-solid (V-S) growth mechanism, and the Pb atoms present in the lattice as substitutional atoms instead of on the tips of nanowires as catalyst particles.
- One-dimensional nanostructure,
- Array,
- Chemical vapor deposition,
- Sn₂S₃,
- Vapor-solid growth mechanism
1. [1]
  
  (1) Zhu, H. L.; Yang, D. R.; Zhang, H. Mater. Lett. 2006, 60, 2686.
2. [2]
  (2) Yue, G. H.; Wang, W.; Wang, L. S.; Wang, X.; Yan, P. X.; Chen, Y.; Peng, D. L. J. Alloy. Compd. 2009, 474, 445.
3. [3]
  (3) Salah, H. B. H.; Bouzouita, H.; Rezig, B. Thin Solid Films 2005, 480-481, 439.
4. [4]
  (4) Hickey, S. G.; Waurisch, C.; Rellinghaus, B.; Eychmuller, A. J. Am. Chem. Soc. 2008, 130, 14978.
5. [5]
  (5) Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
6. [6]
  (6) Khadraoui, M.; Benramdane, N.; Mathieu, C.; Bouzidi, A.; Miloua, R.; Kebbab, Z.; Sahraoui, K.; Desfeux, R. Solid State Commun. 2010, 150, 297.
7. [7]
  (7) López, S.; Granados, S.; Ortíz, A. Semicond. Sci. Technol. 1996, 11, 433.
8. [8]
  (8) Lofersky, J. J. J. Appl. Phys. 1956, 27, 77.
9. [9]
  (9) Hong, S. Y.; Popovitz-Biro, R.; Prior, Y.; Tenne, R. J. Am. Chem. Soc. 2003, 125, 10470.
10. [10]
  (10) An, C. H.; Tang, K. B.; Shen, G. Z.; Wang, C. R.; Yang, Q.; Hai, B.; Qian, Y. T. J. Cryst. Growth 2002, 244, 333.
11. [11]
  (11) Chen, D.; Shen, G. Z.; Tang, K. B.; Liu, Y. K.; Qian, Y. T. Appl. Phys. A 2003, 77, 747.
12. [12]
  (12) Ji, Y. J.; Zhang, H.; Ma, X. Y.; Xu, J.; Yang, D. R. J. Phys.- Condens. Matter 2003, 15, L661.
13. [13]
  (13) Price, L. S.; Parkin, I. P.; Hardy, A. M. E.; Clark, R. J. H.; Hibbert, T. G.; Molloy, K. C. Chem. Mater. 1999, 11, 1792.
14. [14]
  (14) Chen, B.; Xu, X. H.; Wang, F.; Liu, J. J.; Ji, J. Mater. Lett. 2011, 65, 400.
15. [15]
  (15) Zeng, C. L.; Tang, D. S.; Liu, X. H.; Hai, K.; Yang, Y.; Yuan, H. J.; Xie, S. S. Acta Physica Sinica 2007, 56, 6531.
16. [16]
  [曾春来, 唐东升, 刘星辉, 海阔, 羊亿, 袁华军, 解思深. 物理学报, 2007, 56, 6531.]
17. [17]
  (16) Liu, X. H.; Tang, D. S.; Zeng, C. L.; Hai, K.; Xie, S. S. Acta Phys. -Chim. Sin. 2007, 23, 361.
18. [18]
  [刘星辉, 唐东升, 曾春来, 海阔, 解思深. 物理化学学报, 2007, 23, 361.]
19. [19]
  (17) Smith, W.; Zhang, Z. Y.; Zhao, Y. P. J. Vac. Sci. Technol. B 2007, 25, 1875.
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
3. [3]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
4. [4]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
8. [8]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
9. [9]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
10. [10]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
11. [11]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
12. [12]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
13. [13]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
14. [14]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
15. [15]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
16. [16]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
17. [17]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
18. [18]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
19. [19]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
20. [20]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051

Get Citation

PDF

XML

Metrics

PDF Downloads(1437)
Abstract views(2717)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Sn2S3 One-Dimensional Nanostructure Arrays by Chemical Vapor Deposition

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Sn₂S₃ One-Dimensional Nanostructure Arrays by Chemical Vapor Deposition