Citation: XIANG Mei, HE Chang-Cheng, WANG Hui-Liang. Magnetic Polyacrylamide/Fe3O4 Nanocomposite Hydrogel with High Mechanical Strength[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1267-1272. doi: 10.3866/PKU.WHXB20110429
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Polyacrylamide (PAAm) hydrogels with very high mechanical strength were prepared using radiation-peroxidized micelles that were formed by surfactant molecules as initiating and crosslinking centers. PAAm/Fe3O4 nanocomposite hydrogels were obtained by introducing Fe3O4 nanoparticles into PAAm hydrogels through an in situ chemical co-precipitation method. Scanning electron microscopy (SEM) investigations showed that the nanoparticles were homogeneously distributed and the particles were about 30 nm in size. X-ray diffraction (XRD) analysis showed that the obtained nanoparticles were spinel Fe3O4. The PAAm/Fe3O4 nanocomposite hydrogels showed superparamagnetism. The ferrogels also had od mechanical properties, the elongation at break of some gels could be as high as 1200% and the maximum tensile strength was about 0.10 MPa, and they exhibited very od shape recoverability.
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Keywords:
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Hydrogel
, - Fe3O4,
- Magnetism,
- Mechanical strength
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