Citation:
XIANG Mei, HE Chang-Cheng, WANG Hui-Liang. Magnetic Polyacrylamide/Fe3O4 Nanocomposite Hydrogel with High Mechanical Strength[J]. Acta Physico-Chimica Sinica,
;2011, 27(05): 1267-1272.
doi:
10.3866/PKU.WHXB20110429
-
Polyacrylamide (PAAm) hydrogels with very high mechanical strength were prepared using radiation-peroxidized micelles that were formed by surfactant molecules as initiating and crosslinking centers. PAAm/Fe3O4 nanocomposite hydrogels were obtained by introducing Fe3O4 nanoparticles into PAAm hydrogels through an in situ chemical co-precipitation method. Scanning electron microscopy (SEM) investigations showed that the nanoparticles were homogeneously distributed and the particles were about 30 nm in size. X-ray diffraction (XRD) analysis showed that the obtained nanoparticles were spinel Fe3O4. The PAAm/Fe3O4 nanocomposite hydrogels showed superparamagnetism. The ferrogels also had od mechanical properties, the elongation at break of some gels could be as high as 1200% and the maximum tensile strength was about 0.10 MPa, and they exhibited very od shape recoverability.
-
Keywords:
-
Hydrogel
, - Fe3O4,
- Magnetism,
- Mechanical strength
-
-
-
-
[1]
(1) Jin, S. P.; Liu, M. Z.; Chen, S. L.; Bian, F. L.; Chen, Y.; Wang, B.; Zhan, F. L.; Liu, S. X. Acta Phys. -Chim. Sin. 2007, 23, 438.
-
[2]
[金淑萍, 柳明珠, 陈世兰, 卞凤玲, 陈 勇, 王 斌, 詹发禄, 刘守信. 物理化学学报, 2007, 23, 438.]
-
[3]
(2) Chen, L. Intelligent Polymeric Materials; Chemical Industry Press: Beijing, 2005; p 60.
-
[4]
[陈 莉. 智能高分子材料. 北京: 化学工业出版社, 2005: 60.]
-
[5]
(3) Liu, T. Y.; Hu, S. H.; Liu, K. H.; Liu, D. M.; Chen, S. Y. J. Magn. Magn. Mater. 2006, 304, e397.
-
[6]
(4) Qin, J.; Asempah, I.; Laurent, S.; Fornara, A.; Muller, R. N.; Muhammed, M. Adv. Mater. 2009, 21, 1.
-
[7]
(5) Ramanujan, R. V.; Lao, L. L. Smart. Mater. Struct. 2006, 15, 952.
-
[8]
(6) Ding, X. B.; Sun, Z. H.; Wan, G. X.; Jiang, Y. Y. Acta Polym. Sin. 2000, No. 1, 9.
-
[9]
[丁小斌, 孙宗华, 万国祥, 江英彦. 高分子学报, 2000, No. 1, 9.]
-
[10]
(7) Xiang, M.; Zheng, Z. W.; Wang, H. L.; He, C. C. Chin. Polym. Bull. 2010, No. 3, 16.
-
[11]
[相 梅, 郑志伟, 汪辉亮, 贺昌城. 高分子通报, 2010, No. 3, 16.]
-
[12]
(8) Okumura, Y.; Ito, K. Adv. Mater. 2001, 13, 485.
-
[13]
(9) Haraguchi, K.; Takehisa, T. Adv. Mater. 2002, 14, 1120.
-
[14]
(10) ng, J. P.; Katsuyama, Y.; Kurokawa, T.; Osada, Y. Adv. Mater. 2003, 15, 1155.
-
[15]
(11) Huang, T.; Xu, H. G.; Jiao, K. X.; Zhu, L. P.; Brown, H. R.; Wang, H. L. Adv. Mater. 2007, 19, 1622.
-
[16]
(12) He, C. C.; Jiao, K. X.; Zhang, X.; Xiang, M.; Li, Z. Y.; Wang, H. L. Soft Matter. DOI:10.1039/C0SM01149E.
-
[17]
(13) Zhang, J. G.; Xu, S. Q.; Kumacheva, E. J. J. Am. Chem. Soc. 2004, 126, 7908.
-
[1]
-
-
-
[1]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[2]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[3]
Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
-
[4]
Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe3O4. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
-
[5]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[6]
Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
-
[7]
Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
-
[8]
Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
-
[9]
Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
-
[10]
Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe3O4 heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
-
[11]
Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe3O4/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
-
[12]
Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
-
[13]
Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
-
[14]
Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
-
[15]
Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
-
[16]
Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
-
[17]
Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
-
[18]
Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
-
[19]
Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
-
[20]
Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe3O4 dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
-
[1]
Metrics
- PDF Downloads(1383)
- Abstract views(2832)
- HTML views(41)