Citation: FAN Min, LI Guo-Bao, WANG Dong-Wei, JIN Tou-Nan, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 990-994. doi: 10.3866/PKU.WHXB20110428 shu

Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions

1.
1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. College of Material Science and Engineering, Beijing University of Technology, Beijing 100022, P. R. China;
3. National Center for Nanoscience and Technolgy, Beijing 100190, P. R. China

Received Date: 27 December 2010
Available Online: 11 March 2011
Fund Project: 国家自然科学基金(20771008) (20771008) 北京市教委重点基金(KM201010005019) (KM201010005019)科技部重大研究计划(2010CB833103)资助项目 (2010CB833103)

Solid solutions of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) were synthesized by a traditional solid state reaction and characterized by powder X-ray diffraction. The solutions crystallize in the P4mm space group at room temperature. Differential scanning calorimetry (DSC) measurements were performed to obtain phase transition temperatures (T_c) for the samples, and these were found to decrease with an increase in the amount of doped Tb and Mn. The temperature dependent dielectric constant shows a peak close to the T_c, indicating that the corresponding phase transition is a ferroelectric phase transition. Magnetic measurements indicate that a paramagnetic to antiferromagnetic phase transition occurs at 25 and 29 K for Pb_1-xTb_xTi_1-xMn_xO₃ with x=0.08 and x=0.10, respectively.
- Solid-state reaction,
- PbTiO₃,
- Phase transition,
- Ferroelectrics,
- TbMnO₃
1. [1]
  
  (1) Jaffe, B.; Cook, W. R.; Jaffe, H. Piezoelectric Ceramics; New York: Academic, 1971.
2. [2]
  (2) Uchino, K. Ferroelectric Devices; New York: Marcel Dekker, 2000.
3. [3]
  (3) Scott, J. F.; Araujo, C. A. Science 1989, 246, 1400.
4. [4]
  (4) Qi, T. T.; Grinberg, I.; Rappe, A. M. Phys. Rev. B 2010, 82, 134113.
5. [5]
  (5) Datta, K.; Walker, D.; Thomas, P. A. Phys. Rev. B 2010, 82, 144108.
6. [6]
  (6) Li, F.; Zhang, S. J.; Xu, Z.; Wei, X. Y.; Luo, J.; Shrouty, T. R. J. Am. Ceram. Soc. 2010, 93, 2731.
7. [7]
  (7) Wu, J. G.; Zhu, J. L.; Xiao, D. Q.; Zhu, J. G.; Tan, J. Z.; Zhang, Q. L. Thin Solid Films 2008, 517, 1005.
8. [8]
  (8) Hu, P. H.; Chen, J.; Deng, J. X.; Xing, X. R. J. Am. Chem. Soc. 2010, 132, 1925.
9. [9]
  (9) Chen, J. G.; Qi, Y. F.; Shi, G. Y.; Yu, S. W.; Cheng, J. R. IEEE Trans. Ultrason. Ferroelectr. Freq. Control. 2009, 56, 1820.
10. [10]
  (10) Huang, W.; Jiang, S. W.; Li, Y. R.; Zhu, J.; Zhang, Y.; Wei, X. H.; Zeng, H. Z. Thin Solid Films 2006, 500, 138.
11. [11]
  (11) Sun, C.; Wang, J. G.; Kang, H. J.; Chen, J.; Kim, M. J.; Xing, X. R. Dalton Trans. 2010, 39, 9952.
12. [12]
  (12) Kaneshiro, J.; Uesu, Y. Jpn. J. Appl. Phys. 2010, 49, 09me02.
13. [13]
  (13) Pontes, D. S. L.; Lon , E.; Pontes, F. M.; Pereira-Da-Silva, M. A.; da Silva, J. H. D.; Chiquito, A. J.; Pizani, P. S. J. Sol-Gel Sci. Technol. 2010, 55, 151.
14. [14]
  (14) Birks, E.; Dunce, M.; Antonova, M.; Sternberg, A. Physica Status Solidi C-Current Topics in Solid State Physics 2009, 6, 2737.
15. [15]
  (15) Amorin, H.; Jimenez, R.; Ricote, J.; Hungria, T.; Castro, A.; Alguero, M. Journal of Physics D-Applied Physics 2010, 43, 285401.
16. [16]
  (16) Mastelaro, V. R.; Mascarenhas, Y. P.; Neves, P. P.; Mir, M.; Doriguetto, A. C.; Michalowicz, A.; Moscovici, J.; Lente, M. H.; Eiras, J. A. J. Appl. Phys. 2010, 107, 114103.
17. [17]
  (17) Li, H. M.; Zhou, Y. Y.; Tian ,Y. F.; Li, X. D.; Guo, H. L.; Xiao, D. Q.; Zhu, J. G. Appl. Surf. Sci. 2010, 257, 1407.
18. [18]
  (18) Rai, R.; Kholkin, A. L.; Sharma, S. J. Alloy. Compd. 2010, 506, 815
19. [19]
  (19) Ranjan, R.; Raju, K. A. Phys. Rev. B 2010, 82, 054119.
20. [20]
  (20) Wang, J.; Neaton, J. B.; Zheng, H.; Nagarajan, V.; Ogale, S. B.; Liu, B.; Viehland, D.; Vaithyanathan, V.; Schlom, D. G.; Waghmare, U. V.; Spaldin, N. A.; Rabe, K. M.; Wuttig, M.; Ramesh, R. Science 2003, 299, 1719.
21. [21]
  (21) Kimura, T.; to, T.; Shintani, H.; Ishizaka, K.; Arima, T.; Tokura Y. Nature 2003, 426, 55.
22. [22]
  (22) Larson. A. C.; von Dreele, R. B. Report LAUR 86-748 Los Alamos National Laboratory, 1985.
23. [23]
  (23) Rietveld, H. M. J. Appl. Crystallogr. 1969, 2, 65.
24. [24]
  (24) Vegard, L. Z. Physics 1921, 5, 17.
25. [25]
  (25) Vegard, L. Z. Kristallogr. 1928, 67, 239.
26. [26]
  (26) Jaffc, B.; Roth, R. S.; Marzullo, S. J. Res. Nat. Bur. Stand. 1955, 55, 239.
27. [27]
  (27) Yu, H. C.; Ren, W.; Ye, Z. G. IEEE Trans. Ultrason. Ferroelectr. Freq. Control. 2010, 57, 2177.
28. [28]
  (28) Dwight, K.; Menyuk, N. Phys. Rev. 1960, 119, 1470.
1. [1]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
2. [2]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
3. [3]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
4. [4]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
5. [5]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
8. [8]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
9. [9]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
10. [10]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
11. [11]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
12. [12]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
13. [13]
  . . University Chemistry, 2024, 39(3): 0-0.
14. [14]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
15. [15]
  . 第41卷第3期封面和目次. Acta Physico-Chimica Sinica, 2025, 41(3): -.
16. [16]
  Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou . Fe³⁺ ion quantification with reusable bioinspired nanopores. Chinese Chemical Letters, 2025, 36(2): 110428-. doi: 10.1016/j.cclet.2024.110428
17. [17]
  . . University Chemistry, 2025, 40(3): 0-0.
18. [18]
  Liyong DU , Yi LIU , Guoli YANG . Preparation and triethylamine sensing performance of ZnSnO₃/NiO heterostructur. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 729-740. doi: 10.11862/CJIC.20240404
19. [19]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
20. [20]
  Jisheng Liu , Junli Chen , Xifeng Zhang , Yin Wu , Xin Qi , Jie Wang , Xiang Gao . Red blood cell membrane-coated FLT3 inhibitor nanoparticles to enhance FLT3-ITD acute myeloid leukemia treatment. Chinese Chemical Letters, 2024, 35(9): 109779-. doi: 10.1016/j.cclet.2024.109779

Get Citation

PDF

XML

Metrics

PDF Downloads(999)
Abstract views(2485)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Characterization of Pb1-xTbxTi1-xMnxO3 (0≤x≤0.10) Solid Solutions

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Characterization of Pb_1-xTb_xTi_1-xMn_xO₃ (0≤x≤0.10) Solid Solutions