Citation: YE Bin, GAO Cai, LIU Xiang-Nong, YANG Suo, JIANG Bin. Effect of Annealing Conditions on Enthalpy Relaxation Parameters of D-Sorbitol Glass[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1031-1038. doi: 10.3866/PKU.WHXB20110419 shu

Effect of Annealing Conditions on Enthalpy Relaxation Parameters of D-Sorbitol Glass

1.
School of Mechanical and Automotive Engineering, Hefei University of Technology, Hefei 230009, P. R. China

Received Date: 8 November 2010
Available Online: 8 March 2011
Fund Project: 国家自然科学基金(20803016) (20803016)安徽省自然科学基金(070414163)资助项目 (070414163)

We studied the enthalpy relaxation dynamics of amorphous D-sorbitol by differential scanning calorimetry (DSC). A series of specific heat capacities (C_p(T)) for D-sorbitol were measured upon heating of 10 K·min^-1. The samples were subjected to thermal treatment involving isothermal annealing with different annealing time (t_a). A new phenomenological model by Gómez Ribelles (the GR model) of enthalpy relaxation based on the evolution of configurational entropy was used to simulate the experimental data to verify the applicability of the GR model to small molecular glass. The results indicated that a single set of GR model parameters only reproduced the corresponding experimental C_p(T) curve of D-sorbitol fairly well. It failed to find a set of GR model parameters as the material constant independent of the thermal history. In contrast with other phenomenological models, some parameters of the GR model remained unchanged. The model parameter sets obtained under longer annealing time show better predictive ability. In contrast to the continuous cooling process for D-sorbitol, the ratio between the mean value of the limit state parameter (δ) and the increment of specific heat capacity at T_g (ΔC_p(T_g)) apparently increases, but the increase is less than that of polymers. The results brought into question if the metastable limit state introduced by the GR model applied to small molecular glass systems.
- Enthalpy relaxation,
- Differential scanning calorimetry,
- Configurational entropy,
- D-sorbitol,
- Glass transition,
- Isothermal annealing,
- Fragility
1. [1]
  
  (1) Lebrun, N.; van Miltenburg, J.C. J. Alloy. Compd. 2001, 320, 320.
2. [2]
  (2) Hodge, I. M. J. Non-Cryst. Solids 1994, 169, 211.
3. [3]
  (3) Hutchinson, J. M.; Kumar, P. Thermochim. Acta 2002, 391, 197.
4. [4]
  (4) Cameron, N. R.; Cowie, J.M.G.; Ferguson, R.; McEwan, I. Polymer 2000, 41, 725.
5. [5]
  (5) Tool, A. Q. J. Am. Ceram. Soc. 1946, 29, 240.
6. [6]
  (6) Narayanaswamy, O. S.; J. Am. Ceram. Soc. 1971, 54, 491.
7. [7]
  (7) Moynihan, C.T.; Easteal, A. J.; DeBolt, M. A.; Tucker, J. J. Am. Ceram. Soc. 1976, 59, 12.
8. [8]
  (8) Adam, G.; Gibbs, J. H. J. Chem. Phys. 1965, 43, 139.
9. [9]
  (9) Hodge, I. M. Macromolecules 1987, 20, 2897.
10. [10]
  (10) Gómez Ribelles, J. L.; Monleón Pradas, M. Macromolecules 1995, 28, 5867.
11. [11]
  (11) Gómez Ribelles, J. L.; Monleón Pradas, M.; Vidaurre Garayo, A.; Romero Colomer, F.; Más Estellés, J.; Mese-guer Dueñas, J. M. Macromolecules 1995, 28, 5878.
12. [12]
  (12) Gómez Ribelles, J. L.; Monleón Pradas, M.; Vidaurre Garayo, A.; Romero Colomer, F.; Más Estellés, J.; Meseguer Dueñas, J. M. Polymers 1997, 38, 963.
13. [13]
  (13) Meseguer Dueñas, J. M.; Vidaurre Garayo, A.; Romero Colomer, F.; Más Estellés, J.; Gómez Ribelles, J. L.; Monleón Pradas, M. J. Polym. Sci. Part B: Polym. Phys.1997, 35, 2201.
14. [14]
  (14) Gómez Ribelles, J. L.; Vidaurre Garayo, A.; Cowie, J. M. G.; Ferguson, R.; Harris, S.; McEwen, I. J. Polymers 1998, 40, 183.
15. [15]
  (15) Cowie, J. M. G.; Harris, S.; Gómez Ribelles, J. L.; Meseguer, J. M.; Romero, F.; Torregrosa, C. Macromolecules 1999, 32, 4430.
16. [16]
  (16) Tanaka, Y. Polym. J. 2009, 41, 125.
17. [17]
  (17) Théneau, C.; Salmerôn Sánchez, M.; Rodríguez Hernández, J. C.; Monleón Pradas, M.; Saiter, J. M.; Gómez Ribelles, J. L. Eur. Phys. J. E 2007, 24, 69.
18. [18]
  (18) Mano, J. F.; Gómez Ribelles, J. L.; Alves, N. M.; Salmerôn Sánchez, M. Polymer 2005, 46, 8258.
19. [19]
  (19) Alves, N. M.; Gómez Ribelles, J. L.; Manoa, J. F. Polymer 2005, 46, 491.
20. [20]
  (20) Salmerôn Sánchez, M.; Touzé, Y.; Saiter, A.; Saiter, J. M.; Gómez Ribelles, J. L. Colloid Polym. Sci. 2005, 283, 711.
21. [21]
  (21) Andreozzi, L.; Autiero, C.; Faetti, M.; Galli, G.; Giordano, M.; Zulli, F. Macromol. Rapid Commun. 2008, 29, 928.
22. [22]
  (22) Hernández Sánchez, F.; Meseguer Dueñas, J. M.; Gómez Ribelles, J. L. J. Therm. Anal. Cal. 2003, 72, 631.
23. [23]
  (23) Gao, C.; Chen, K. S.; Ye, B.;Yang, S.; Liu, X. N.; Jiang, B. Acta Chim. Sin. (Accepted).
24. [24]
  [高才, 陈开松, 叶斌, 杨锁, 刘向农, 江斌, 化学学报, 已录用.]
25. [25]
  (24) Gibbs, J. H.; DiMarzio, E. A. J. Chem. Phys. 1958, 28, 373.
26. [26]
  (25) Hodge, I.M.; Berens, A.R. Macromolecules 1982, 15, 762.
27. [27]
  (26) Nedler, J. A.; Mead, R. Comput. J. 1965, 7, 308.
28. [28]
  (27) Gao, C.; Yang, S.; Liu, X. N.; Wang, T. J.; Jiang, B. Acta Phys.-Chim. Sin. 2010, 55, 453.
29. [29]
  [高才, 杨锁, 刘向农, 王铁军, 江斌. 物理化学学报, 2010, 55, 453.]
30. [30]
  (28) Duvvuri, K.; Richert, R. J. Phys. Chem. B 2004, 108, 10451.
31. [31]
  (29) Huang, D.; MacKenna, G. B. J. Chem. Phys. 2001, 114, 5621.
32. [32]
  (30) Gómez Ribelles, J. L.; Ribes Greus, A.; Diaz Calleja, R. Polymer 1990, 31, 223.
33. [33]
  (31) Moynihan, C. T.; Crichton, S. N.; Opalka, S. M. J. Non-Cryst. Solids 1991, 131-133, 420.
34. [34]
  (32) Romero Colomer, F.; G6mez Ribelles, J. L. Polymer 1989, 30, 849.
35. [35]
  (33) Hodge, I. M. J. Non-Cryst. Solids 1991, 131-133, 435.
36. [36]
  (34) Andreozzi, L.; Faetti, M.; Giordano, M.; Palazzuoli, D. J. Non- Cryst. Solids 2003, 332, 229.
37. [37]
  (35) Andreozzi, L.; Faetti, M.; Zulli, F.; Giordano, M. Eur. Phys. J. B 2004, 41, 383.
38. [38]
  (36) Andreozzi, L.; Faetti, M.; Giordano, M.; Palazzuoli, D. Macromolecules 2002, 35, 9049.
39. [39]
  (37) Brunacci, A.; Cowie, J. M. G.; Ferguson, R. Macromolecules 1996, 29, 7976.
40. [40]
  (38) Angell, C. A. Science 1995, 267, 1924.
41. [41]
  (39) Ediger, M. D.; Angell, C. A.; Nagel, S. R. J. Chem. Phys. 1996, 100, 13200.
42. [42]
  (40) Wungtana rna, R.; Schmidst, S. J. Thermochim. Acta 2001, 369, 95.
43. [43]
  (41) Williams, M. L.; Landel, R. F.; Ferry, J. D. J. Am. Chem. Soc. 1955, 77, 3701.
44. [44]
  (42) Gao, C.; Wang, T. J.; Liu, X. N.; Zhou, G. Y.; Hua, T. C. Chin. J. Chem. Phys. 2007, 20, 258.
1. [1]
  Qingcui Yang , Wen Liu , Li Cao , Chen Tang , Bing Xu , Jie Zhao . For Entropy Hurts: Life Thrives on Negative Entropy. University Chemistry, 2024, 39(9): 151-156. doi: 10.12461/PKU.DXHX202402029
2. [2]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
3. [3]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
4. [4]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
5. [5]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
6. [6]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
7. [7]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
8. [8]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
9. [9]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043
10. [10]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
11. [11]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
12. [12]
  Ling Zhang , Jing Kang . Turn Waste into Valuable: Preparation of High-Strength Water-Based Adhesives from Polymethylmethacrylate Wastes: a Comprehensive Chemical Experiments. University Chemistry, 2024, 39(2): 221-226. doi: 10.3866/PKU.DXHX202306075
13. [13]
  Naiying Fan , Chuanli Qin , Guo Zhang , Bin Wang , Yan Wang , Bing Zheng , Yichun Qu , Zhiyao Sun , Guanghui An . Case Design of Course Ideological and Political Education in Chemical Experiment Safety: the Safe Use of Common Laboratory Instruments and Glassware. University Chemistry, 2024, 39(2): 242-247. doi: 10.3866/PKU.DXHX202309061
14. [14]
  Hongsheng Tang , Yonghe Zhang , Dexiang Wang , Xiaohui Ning , Tianlong Zhang , Yan Li , Hua Li . A Wonderful Journey through the Kingdom of Hazardous Chemicals. University Chemistry, 2024, 39(9): 196-202. doi: 10.12461/PKU.DXHX202403098
15. [15]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
16. [16]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
17. [17]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
18. [18]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
19. [19]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
20. [20]
  Yanxin Wang , Hongjuan Wang , Yuren Shi , Yunxia Yang . Application of Python for Visualizing in Structural Chemistry Teaching. University Chemistry, 2024, 39(3): 108-117. doi: 10.3866/PKU.DXHX202306005

Get Citation

PDF

XML

Metrics

PDF Downloads(1123)
Abstract views(2318)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142