Citation: ZHUO Zu-Liang, ZHANG Fu-Jun, XU Xiao-Wei, WANG Jian, LU Li-Fang, XU Zheng. Photovoltaic Performance Improvement of P3HT:PCBM Polymer Solar Cells by Annealing Treatment[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 875-880. doi: 10.3866/PKU.WHXB20110414 shu

Photovoltaic Performance Improvement of P3HT:PCBM Polymer Solar Cells by Annealing Treatment

1.
Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, P. R. China

Received Date: 13 December 2010
Available Online: 3 March 2011
Fund Project: 国家自然科学基金(10804006, 60576016) (10804006, 60576016) 北京交通大学红果园人才计划, 国家重点基础研究发展规划(973) (2010CB327704) (973) (2010CB327704) 国家杰出青年基金(60825407)，北京市自然科学基金(1102028) (60825407)，北京市自然科学基金(1102028) 高等学校学科创新引智计划(B08002) (B08002)高等学校基本科研业务基金(2011JBM123)资助项目 (2011JBM123)

Several polymer solar cells consisting of ITO/PEDOT:PSS/P3HT:PCBM/Al (indium tin oxide/ poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/poly(3-hexylthiophene):[6,6]-phenyl C61-butyric acid methyl ester/aluminum cathode) were fabricated by spin coating. The influence of annealing temperature on the performance of the polymer solar cells was studied using absorption spectra, photoluminescence spectra, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and atomic force microscopy (AFM). These devices were treated at 120 °C for 10 min in an ambient atmosphere and the best power conversion efficiency (PCE) of 2.00% was obtained at an open circuit voltage (V_oc) of 0.64 V, a short circuit current density (J_sc) of 10.25 mA·cm^-2, and a fill factor (FF) of 38.1%. The intensities of the absorption peaks at 560 and 610 nm increased because of the increased absorption π→π^* transition of P3HT after annealing treatment. XRD spectra showed that the intensity of the diffraction peaks at (100) for P3HT increased 1.8 times by comparison with that of the cells that did not under annealing treatment. The P3HT:PCBM phase separation increased markedly after annealing treatment, which is valuable for exciton dissociation. FTIR results also showed that the polymer materials did not deteriorate during the annealing treatment process.
- Polymer solar cells,
- Phase separation,
- Exciton,
- Power conversion efficiency,
- Annealing treatment
1. [1]
  
  (1) Yu, G.; Gao, J.; Hummelen, J. C.; Wudl, F.; Heeger, A. J. Science 1995, 570, 1789.
2. [2]
  (2) Lin, C.; Lin, E. Y.; Tsai, F. Y. Adv. Funct. Mater. 2010, 20, 834.
3. [3]
  (3) Troshin, P. A.; Hoppe, H.; Renz, J.; Egginger, M.; Mayorova, J. Y.; ryochev, A. E.; Peregudov, A. S.; Lyubovskaya, R. N.; bsch, G.; Sariciftci, N. S.; Razumov, V. F. Adv. Funct. Mater. 2009, 19, 779.
4. [4]
  (4) You, H. L.; Zhang, C. F. Chin. Phys. B 2009, 18, 2096.
5. [5]
  (5) Yu, H. Z.; Peng, J. B.; Zhou, X. M. Acta Phys. Sin. 2008, 57, 3898.
6. [6]
  [於黄忠, 彭俊彪, 周晓明. 物理学报, 2008, 57, 3898.]
7. [7]
  (6) He, Y. J.; Chen, H. Y.; Hou, J. H.; Li, Y. F. J Am. Chem. Soc. 2010, 132, 1377.
8. [8]
  (7) Li, Y. W.; Liu, P. Y.; Hou, L. T.; Wu, B. Acta Phys. Sin. 2010, 59, 1248.
9. [9]
  [李艳武, 刘彭义, 侯林涛, 吴冰. 物理学报, 2010, 59, 1248.]
10. [10]
  (8) Zhang, F. J.; Sun, F. Y.; Shi, Y. Z.; Zhuo, Z. L.; Lu, L. F.; Zhao, D. W.; Xu, Z.; Wang, Y. S. Energy Fuels 2010, 24, 3739.
11. [11]
  (9) Zhang, F. J.; Zhao, D. W.; Zhuo, Z. L.; Wang, H.; Xu, Z.; Wang, Y. S. Sol. Energy Mater. Sol. Cells 2010, 94, 2416.
12. [12]
  (10) Tong, X.; Lassiter, B. E.; Forrest, S. R. Org. Electron. 2010, 11, 705.
13. [13]
  (11) Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T. Q.; Dante, M.; Heeger, A. J. Science 2007, 317, 5835.
14. [14]
  (12) Chen, H. Y.; Hou, J.; Zhang, S.; Liang, Y.; Yang, G.; Yang, Y.; Yu, L.; Wu, Y.; Li, G. Nat. Photon. 2009, 3, 649.
15. [15]
  (13) Sun, X. W.; Zhao, D. W.; Ke, L.; Kyaw, A. K. K.; Lo, G. Q.; Kwong, D. L. Appl. Phys. Lett. 2010, 97, 053303.
16. [16]
  (14) Zhang, F. J.; Xu, Z.; Zhao, D. W.; Zhao, S. L.; Jiang, W. W.; Yuan, G. C.; Song, D.; Wang, Y. S.; Xu, X. R. J. Phys. D: Appl. Phys. 2007, 40, 4485.
17. [17]
  (15) Cheng, C. H.; Wang, J.; Du, G. T.; Shi, S. H.; Du, Z. J.; Fan, Z. Q.; Bian, J. M.; Wang, M. S. Appl. Phys. Lett. 2010, 97, 083305.
18. [18]
  (16) Brabec, C. J.; wrisanker, S.; Halls, J. J. M.; Laird, D.; Jia, S. J.; Williams, S. P. Adv. Mater. 2010, 22, 3839.
19. [19]
  (17) Hu, Z. J.; Gesquiere, A. J. Chem. Phys. Lett. 2009, 476, 51.
20. [20]
  (18) Sundarrajan, S.; Murugan, R.; Nair, A. S.; Ramakrishna, S. Mater Lett. 2010, 64, 2369.
21. [21]
  (19) Bisquert, J.; Garcia-Belmonte, G.; Munar, A.; Sessolo, M.; Soriano, A.; Bolink, H. J. Chem. Phys. Lett. 2008, 465, 57.
22. [22]
  (20) Bartholomew, G. P.; Heeger, A. J. Adv. Funct. Mater. 2005, 15, 677.
23. [23]
  (21) Kim, J. Y.; Lee, K.; Coates, N. E.; Moses, D.; Nguyen, T. Q.; Dante, M.; Heeger, A. J. Science 2007, 317, 222.
24. [24]
  (22) Liao, H. H.; Chen, L. M.; Xu, Z.; Li, G.; Yang, Y. Appl. Phys. Lett. 2008, 92, 173303.
25. [25]
  (23) Guo, T. F.; Wen, T. C.; Pakhomov, G. L.; Chin, X. G.; Liou, S. H.; Yeh, P. H.; Yang, C. H. Thin Solid Films 2008, 516, 3138.
26. [26]
  (24) Feng, Z. H.; Hou, Y. B.; Shi, Q. M.; Liu, X. J.; Teng, F. Chin. Phys. B 2010, 19, 098601.
27. [27]
  (25) Zhang, F.; Vollmer, A.; Zhang, J.; Xu, Z.; Rabe, J. P.; Koch, N. Org. Electron. 2007, 8, 606.
28. [28]
  (26) Bao, Z. N.; Dodabalapur, A.; Lovinger, A. J. Appl. Phys. Lett. 1996, 69, 4108.
29. [29]
  (27) Nunzi, J. M. Labo POMA, Angers, France, 2002, pp 197-224.
30. [30]
  (28) Jain, A.; Kapoor, A. Sol. Energy Mater. Sol. Cells 2005, 86, 197.
1. [1]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
2. [2]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
5. [5]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
6. [6]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
7. [7]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
8. [8]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
9. [9]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
10. [10]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
11. [11]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2311021-. doi: 10.3866/PKU.WHXB202311021
12. [12]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
13. [13]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
14. [14]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
15. [15]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
18. [18]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
19. [19]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
20. [20]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014

Get Citation

PDF

XML

Metrics

PDF Downloads(2983)
Abstract views(4175)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142