Citation: LI Yun-Xia, WEI Zi-Dong, ZHAO Qiao-Ling, DING Wei, ZHANG Qian, CHEN Si-Guo. Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 858-862. doi: 10.3866/PKU.WHXB20110411 shu

Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction

LI Yun-Xia ¹ ,
WEI Zi-Dong ^1,2, ,
ZHAO Qiao-Ling ¹ ,
DING Wei ¹ ,
ZHANG Qian ^1,2 ,
CHEN Si-Guo ^1,2

1.
1. State Key Laboratory of Power Transmission Equipment & System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China;
2. School of Material Science and Engineering, Chongqing University, Chongqing, 400044, P. R. China

Received Date: 20 September 2010
Available Online: 3 March 2011
Fund Project: 国家自然科学基金(20806096, 20906107, 20936008) (20806096, 20906107, 20936008) 重庆市政教育委员会(kjzh 08103) (kjzh 08103) 重庆大学211工程三期创新人才培养建设计划研究生开放实验室(S-09013) (S-09013)中央高校基本科研业务(CDJXS10221141, 11132229)资助项目 (CDJXS10221141, 11132229)

Graphene (Gr) is synthesized by the direct reduction of tetrachloroethylene with sodium in paraffin oil rather than by the intermediate steps of oxidized graphite ( ) and oxidized graphene (GrO). Gr is used as support for the subsequent deposition of Pt nanoparticles and the catalytic behavior during oxygen reduction (OR) on the as-prepared Pt/Gr is studied. The structure, morphology, composition, and surface properties of the as-prepared Pt/Gr catalysts were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and electrochemical measurements. We found that the Pt nanoparticles with a mean particle size of 3.1 nm were well-dispersed on the Gr. The onset potential of the oxygen reduction on the Pt/Gr electrode shifted to the positive direction by 24 mV compared with the electrode made from commercial Pt/C catalysts (Johnson-Matthey Co. JM-Pt/C). The exchange current density of the OR on the Pt/Gr electrode was found to be 1×10^-3 mA·cm^-2, which is 2.5 times as that of the electrode made from the JM-Pt/C catalysts.
- Graphene,
- Platinum,
- Oxygen reduction,
- Fuel cell,
- Electrocatalysis
1. [1]
  
  (1) Ralph, T. R.; Hogarth, M. P. Platinum Metal Rev. 2002, 46, 3.
2. [2]
  (2) Li, L.; Chen, S. G.; Qi, X. Q.; Wang, Y. Q.; Ji, M. B.; Li, L. L.; Wei, Z. D. Electrochemistry, 2009, 15, 403.
3. [3]
  [李莉, 陈四国, 齐学强, 王耀琼, 季孟波, 李兰兰, 魏子栋. 电化学, 2009, 15, 403.]
4. [4]
  (3) Shen, J. F.; Hu, Y. Z.; Li, C.; Qin, C.; Ye, M. X. Electrochim. Acta 2008, 53, 7276.
5. [5]
  (4) Cai, K. D.; Yin, G. P.; Wang, J. J.; Lu, L. L. Energy Fuels. 2009, 23, 903.
6. [6]
  (5) Yang, S. D.; Zhang, X. G.; Huang, J. S.; Sun, J. Y. Acta Phys- Chim. Sin. 2007, 23, 1224.
7. [7]
  [杨苏东, 张校刚, 黄建书, 孙景玉. 物理化学学报, 2007, 23, 1224.]
8. [8]
  (6) Rhee, C. K.; Kim, B. J.; Ham, C.; Kim, Y. J.; Song, K.; Kwon, K. Langmuir 2009, 25, 7140.
9. [9]
  (7) Wang, Z. B.; Zuo, P. J.; Wang, G. J.; Du, C. Y.; Yin, G. P. J. Phys. Chem. C 2008, 112, 6582.
10. [10]
  (8) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science 2004, 306, 666.
11. [11]
  (9) Geim, A. K.; Novoselov, K. S. Nat Mater. 2007, 6, 183.
12. [12]
  (10) Williams, J. R.; DiCarlo, L.; Marcus, C. M. Science 2007, 317, 638.
13. [13]
  (11) Service, R. F. Science 2009, 324, 875.
14. [14]
  (12) Kim, K. S.; Zhao, Y.; Jang, H.; Lee, S. Y.; Kim, J. M.; Kim, K. S.; Ahn, J. H.; Kim, P.; Choi, J. Y.; Hong, B. H. Nature 2009, 457, 706.
15. [15]
  (13) Yoo, E.; Okata, T.; Akita, T.; Kohyama, M.; Nakamura, J.; Honma, I. Nano Lett. 2009, 9, 2255.
16. [16]
  (14) Pasricha, R.; Gupta, S.; Srivastava, A. K. Small 2009, 5, 2253.
17. [17]
  (15) Huang, Y.; Chen, Y. S. Sci China Ser B: Chem. 2009, 39, 887.
18. [18]
  [黄毅, 陈永胜. 中国科学B辑: 化学, 2009, 39, 887.]
19. [19]
  (16) Wen, Z. L.; Yang, S. D.; Song, Q. J.; Hao, L. Acta Phys.-Chim. Sin. 2010, 26, 1570.
20. [20]
  [温祝亮, 杨苏东, 宋启军, 郝亮, 张. 物理化学学报, 2010, 26, 1570.]
21. [21]
  (17) Chen, G. H.; Wu, D. J.; Weng, W. G.; Lu, I. R.; Wang, P. P.; Chen, X. F. Carbon. 2004, 42, 753.
22. [22]
  (18) Li, Y.; Wang, J. Y. Preparation of Graphene. CN Patent 10 146 2719A, 2009-06-24.
23. [23]
  [李彦, 王金泳. 石墨烯的制备方法:中国, CN 101462719A
24. [24]
  [P]. 2009-06-24.]
25. [25]
  (19) Yi, B. L. Fuel Cells-Principles, Technology and Application: Chemical Industry Press: Beijing, 2003; pp 162-167.
26. [26]
  [衣宝廉. 燃料电池-原理、技术、应用. 北京: 化学工版社, 2003: 162-167.]
27. [27]
  (20) Ioroi, T.; Kitazwa, N.; Yasuda, K.; Yamanoto, Y.; Takenaka, H. J. Appl. Electrochem. 2001, 31, 1179.
28. [28]
  (21) Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.; Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008, 146, 351.
29. [29]
  (22) Chen, S. G.; Wei, Z. D.; Li, H.; Li, L. Chem. Commun. 2010, 46, 8782.
30. [30]
  (23) Wei, Z. D.; Ran, H. B.; Liu, X. A.; Liu, Y.; Sun, C. X.; Chan, S. H.; Shen, P. K. Electrochim. Acta 2006, 51, 3091.
31. [31]
  (24) Liao, C.; Wei, Z. D.; Ji, M. B.; Li, L.; Tan, Y.; Liao, M. J. J. Phys. Chem. C 2009, 113, 5705.
32. [32]
  (25) Sharma, S.; Ganguly, A.; Papakonstantinou, P.; Miao, X. P.; Li, M. X.; Hutchison, J. L.; Delichatsions, M.; Ukleja, S. J. Phys. Chem. C 2010, 114, 19459.
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
3. [3]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
6. [6]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
7. [7]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
8. [8]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
9. [9]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
10. [10]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
11. [11]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
12. [12]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
13. [13]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
14. [14]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
17. [17]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
18. [18]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
19. [19]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
20. [20]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046

Get Citation

PDF

XML

Metrics

PDF Downloads(4564)
Abstract views(4829)
HTML views(86)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142