Citation: LI Yun-Xia, WEI Zi-Dong, ZHAO Qiao-Ling, DING Wei, ZHANG Qian, CHEN Si-Guo. Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction[J]. Acta Physico-Chimica Sinica, ;2011, 27(04): 858-862. doi: 10.3866/PKU.WHXB20110411 shu

Preparation of Pt/Graphene Catalyst and Its Catalytic Performance for Oxygen Reduction

LI Yun-Xia ¹ ,
WEI Zi-Dong ^1,2, ,
ZHAO Qiao-Ling ¹ ,
DING Wei ¹ ,
ZHANG Qian ^1,2 ,
CHEN Si-Guo ^1,2

1.
1. State Key Laboratory of Power Transmission Equipment & System Security and New Technology, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, P. R. China;
2. School of Material Science and Engineering, Chongqing University, Chongqing, 400044, P. R. China

Received Date: 20 September 2010
Available Online: 3 March 2011
Fund Project: 国家自然科学基金(20806096, 20906107, 20936008) (20806096, 20906107, 20936008) 重庆市政教育委员会(kjzh 08103) (kjzh 08103) 重庆大学211工程三期创新人才培养建设计划研究生开放实验室(S-09013) (S-09013)中央高校基本科研业务(CDJXS10221141, 11132229)资助项目 (CDJXS10221141, 11132229)

Graphene (Gr) is synthesized by the direct reduction of tetrachloroethylene with sodium in paraffin oil rather than by the intermediate steps of oxidized graphite ( ) and oxidized graphene (GrO). Gr is used as support for the subsequent deposition of Pt nanoparticles and the catalytic behavior during oxygen reduction (OR) on the as-prepared Pt/Gr is studied. The structure, morphology, composition, and surface properties of the as-prepared Pt/Gr catalysts were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and electrochemical measurements. We found that the Pt nanoparticles with a mean particle size of 3.1 nm were well-dispersed on the Gr. The onset potential of the oxygen reduction on the Pt/Gr electrode shifted to the positive direction by 24 mV compared with the electrode made from commercial Pt/C catalysts (Johnson-Matthey Co. JM-Pt/C). The exchange current density of the OR on the Pt/Gr electrode was found to be 1×10^-3 mA·cm^-2, which is 2.5 times as that of the electrode made from the JM-Pt/C catalysts.
- Graphene,
- Platinum,
- Oxygen reduction,
- Fuel cell,
- Electrocatalysis
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