Citation: LIU Zhen-Hai, SHANG Ya-Zhuo, HUANG Yong-Min, PENG Chang-Jun, LIU Hong-Lai. Disassembly of Polyelectrolyte/Surfactants Complex Induced by Macroions[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1135-1142. doi: 10.3866/PKU.WHXB20110406 shu

Disassembly of Polyelectrolyte/Surfactants Complex Induced by Macroions

1.
State Key Laboratory of Chemical Engineering, Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 11 November 2010
Available Online: 1 March 2011
Fund Project: 国家自然科学基金(20706013, 20736002) (20706013, 20736002) 长江学者创新团队(IRT0721) (IRT0721)

The effects of charge number, diameter, surface charge density as well as concentration of macroions on the structure of a polyelectrolyte/surfactants complex were investigated using coarse- grained molecular dynamics simulation. We found that the macroions that had the same charge as the polyelectrolyte had no obvious effect on the structure of the polyelectrolyte/surfactants complex. However, the macroions with opposite charge to the polyelectrolyte can induce the release of surfactant from the polyelectrolyte and even lead to the complete disassembly of the polyelectrolyte/surfactants complex and the formation of a macroion/polyelectrolyte complex. The induction effect increases with an increase in charge number. For microions with the same charge number, smaller microions were found to cause desorption of the surfactant more easily. However the opposite effect was found for the diameter at a fixed charge density. The concentration of macroions also affects the structure of the complex greatly and the surfactants that are released from the polyelectrolyte increase with the macroion concentration and finally a macroion/polyelectrolyte complex with reversed charges is formed.
- Polyelectrolyte,
- Surfactant,
- Complex,
- Disassembly,
- Molecular dynamics simulation
References
1. [1]
  
  (1) ddard, E. D.; Ananthapadmanabhan, K. P. Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, FL, 1993.
2. [2]
  (2) Zhou, S. Q.; Chu B. Adv. Mater. 2000, 12, 545.
3. [3]
  (3) Kwak, J. C. T. Polymer-Surfactant Systems. Marcel Dekker: New York, 1999.
4. [4]
  (4) Chu, D. Y.; Thomas, J. K. Polym. Prepr. 1986, 27, 329.
5. [5]
  (5) Morishima, Y.; Mizusaki M.; Yoshida, K.; Dubin. P. L. Colloids and Surfaces A, Physicochem. Eng. Aspects 1999, 147, 149.
6. [6]
  (6) Kosmella, S.; K?tz, J.; Shirahama, K.; Liu, J. J. Phys. Chem. B 1998, 102, 6459.
7. [7]
  (7) Wang, C.; Tam, K. C. J. Phys. Chem. B 2004, 108, 8976.
8. [8]
  (8) Dubin, P. L.; Oeri, R. J. Colloid Interface Sci. 1983, 95, 453.
9. [9]
  (9) Almgren, M.; Hansson, P.; Mukhtar, E.; Stam, J. V. Langmuir 1992, 8, 2405.
10. [10]
  (10) Yan, P.; Jin, C.; Wang, C.; Ye, J.; Xiao, J. J. Colloid Interface Sci. 2005, 282, 188.
11. [11]
  (11) Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1982, 86, 3866.
12. [12]
  (12) Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1983, 87, 506.
13. [13]
  (13) Malovikova, A.; Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1984, 88, 1930.
14. [14]
  (14) Hansson, P.; Almgren, M. J. Phys. Chem. 1995, 99, 16684.
15. [15]
  (15) Wang, C.; Tam, K. C. Langmuir 2002, 18, 6484.
16. [16]
  (16) Wang, C.; Tam, K. C,; Jenkins, R. D. ; Tan C. B. J. Phys. Chem. B 2003, 107, 4667.
17. [17]
  (17) Langevin, D. Adv. Colloid Interface Sci. 2009, 147-148, 170.
18. [18]
  (18) Trewavas, A. Anal. Biochem. 1967, 21, 324.
19. [19]
  (19) Izumrudov, V. A.; Zhiryakova, M. V.; ulko, A. A. Langmuir 2002, 18, 10348.
20. [20]
  (20) Dias, R. S.; Innerlohinger, J.; Glatter, O.; Miguel, M. G.; Lindman, B. J. Phys. Chem. B 2005, 109, 10458.
21. [21]
  (21) Cardenas, M.; Schillen, K.; Nylander, T. Phys. Chem. Chem. Phys. 2004, 6,1603.
22. [22]
  (22) Dias, R.; Melnikov, S. M.; Lindman, B. Miguel, M. Langmuir 2000, 16, 9577.
23. [23]
  (23) Smith, P.; Lynden-Bell, R. M.; Smith, W. Phys. Chem. Chem. Phys. 2000, 2, 1305.
24. [24]
  (24) Zabner, J. Adv. Drug Deliver. Rev. 1997, 27, 17.
25. [25]
  (25) Miguel, M. G.; Pais, A. A. C. C.; Dias, R. S.; Leal, C.; Rosa, M.; Lindman B. Colloids and Surfaces A-Physicochem. Eng. Aspects 2003, 228, 43.
26. [26]
  (26) Dias, R. S.; Pais, A. A. C. C.; Miguel, M. G.; Lindman, B. Colloids and Surfaces A-Physicochem. Eng. Aspects 2004, 250, 115.
27. [27]
  (27) Zhao, X.; Shang, Y.; Liu, H.; Hu, Y. J. Colloid Interface Sci. 2007, 314, 478.
28. [28]
  (28) Evans, D. F.; Wennerstrom, H. The Colloidal Domain. 2nd ed.; Wiley-VCH: New York, 1999.
29. [29]
  (29) Nguyen, T. T.; Shklovskii, B. I. J. Chem. Phys. 2001, 114, 5905.
30. [30]
  (30) Cooper, C. L.; Dubin, P. L.; Kayitmazer, A. B.; Turksen, S. Curr. Opin. Colloid Interface Sci. 2005, 10, 52.
31. [31]
  (31) Linse, P.; Jonsson, M. J. Chem. Phys. 2001, 115, 3406.
32. [32]
  (32) Wallin, T.; Linse, P. Langmuir 1996, 12, 305.
33. [33]
  (33) Wallin, T.; Linse, P. J. Phys Chem. 1996, 100, 17873.
34. [34]
  (34) Wallin, T.; Linse, P. J. Phys. Chem. B 1997, 101, 5506.
35. [35]
  (35) Savariar, E. N.; Ghosh S.; nzález, D. C.; Thayumanavan, S. J. Am. Chem. Soc. 2008, 130, 5416.
36. [36]
  (36) Darden, T.; York, D.; Pedersen, L. J. Phys Chem. 1993, 98, 10089.
37. [37]
  (37) von Ferber, C.; L?wen, H. Faraday Discuss. 2005,?128, 389.
38. [38]
  (38) ldraich, M.; Schwartz, J. R.; Burns, J. L. Colloids and Surfaces A-Physicochemi. Eng. Aspects 1997, 125, 231.
39. [39]
  (39) Guillot, S.; Delsanti, M.; Desert, S.; Langevin, D. Langmuir 2003, 19, 230.
1. [1]
  
  (1) ddard, E. D.; Ananthapadmanabhan, K. P. Interactions of Surfactants with Polymers and Proteins; CRC Press: Boca Raton, FL, 1993.
2. [2]
  (2) Zhou, S. Q.; Chu B. Adv. Mater. 2000, 12, 545.
3. [3]
  (3) Kwak, J. C. T. Polymer-Surfactant Systems. Marcel Dekker: New York, 1999.
4. [4]
  (4) Chu, D. Y.; Thomas, J. K. Polym. Prepr. 1986, 27, 329.
5. [5]
  (5) Morishima, Y.; Mizusaki M.; Yoshida, K.; Dubin. P. L. Colloids and Surfaces A, Physicochem. Eng. Aspects 1999, 147, 149.
6. [6]
  (6) Kosmella, S.; K?tz, J.; Shirahama, K.; Liu, J. J. Phys. Chem. B 1998, 102, 6459.
7. [7]
  (7) Wang, C.; Tam, K. C. J. Phys. Chem. B 2004, 108, 8976.
8. [8]
  (8) Dubin, P. L.; Oeri, R. J. Colloid Interface Sci. 1983, 95, 453.
9. [9]
  (9) Almgren, M.; Hansson, P.; Mukhtar, E.; Stam, J. V. Langmuir 1992, 8, 2405.
10. [10]
  (10) Yan, P.; Jin, C.; Wang, C.; Ye, J.; Xiao, J. J. Colloid Interface Sci. 2005, 282, 188.
11. [11]
  (11) Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1982, 86, 3866.
12. [12]
  (12) Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1983, 87, 506.
13. [13]
  (13) Malovikova, A.; Hayakawa, K.; Kwak, J. C. T. J. Phys. Chem. 1984, 88, 1930.
14. [14]
  (14) Hansson, P.; Almgren, M. J. Phys. Chem. 1995, 99, 16684.
15. [15]
  (15) Wang, C.; Tam, K. C. Langmuir 2002, 18, 6484.
16. [16]
  (16) Wang, C.; Tam, K. C,; Jenkins, R. D. ; Tan C. B. J. Phys. Chem. B 2003, 107, 4667.
17. [17]
  (17) Langevin, D. Adv. Colloid Interface Sci. 2009, 147-148, 170.
18. [18]
  (18) Trewavas, A. Anal. Biochem. 1967, 21, 324.
19. [19]
  (19) Izumrudov, V. A.; Zhiryakova, M. V.; ulko, A. A. Langmuir 2002, 18, 10348.
20. [20]
  (20) Dias, R. S.; Innerlohinger, J.; Glatter, O.; Miguel, M. G.; Lindman, B. J. Phys. Chem. B 2005, 109, 10458.
21. [21]
  (21) Cardenas, M.; Schillen, K.; Nylander, T. Phys. Chem. Chem. Phys. 2004, 6,1603.
22. [22]
  (22) Dias, R.; Melnikov, S. M.; Lindman, B. Miguel, M. Langmuir 2000, 16, 9577.
23. [23]
  (23) Smith, P.; Lynden-Bell, R. M.; Smith, W. Phys. Chem. Chem. Phys. 2000, 2, 1305.
24. [24]
  (24) Zabner, J. Adv. Drug Deliver. Rev. 1997, 27, 17.
25. [25]
  (25) Miguel, M. G.; Pais, A. A. C. C.; Dias, R. S.; Leal, C.; Rosa, M.; Lindman B. Colloids and Surfaces A-Physicochem. Eng. Aspects 2003, 228, 43.
26. [26]
  (26) Dias, R. S.; Pais, A. A. C. C.; Miguel, M. G.; Lindman, B. Colloids and Surfaces A-Physicochem. Eng. Aspects 2004, 250, 115.
27. [27]
  (27) Zhao, X.; Shang, Y.; Liu, H.; Hu, Y. J. Colloid Interface Sci. 2007, 314, 478.
28. [28]
  (28) Evans, D. F.; Wennerstrom, H. The Colloidal Domain. 2nd ed.; Wiley-VCH: New York, 1999.
29. [29]
  (29) Nguyen, T. T.; Shklovskii, B. I. J. Chem. Phys. 2001, 114, 5905.
30. [30]
  (30) Cooper, C. L.; Dubin, P. L.; Kayitmazer, A. B.; Turksen, S. Curr. Opin. Colloid Interface Sci. 2005, 10, 52.
31. [31]
  (31) Linse, P.; Jonsson, M. J. Chem. Phys. 2001, 115, 3406.
32. [32]
  (32) Wallin, T.; Linse, P. Langmuir 1996, 12, 305.
33. [33]
  (33) Wallin, T.; Linse, P. J. Phys Chem. 1996, 100, 17873.
34. [34]
  (34) Wallin, T.; Linse, P. J. Phys. Chem. B 1997, 101, 5506.
35. [35]
  (35) Savariar, E. N.; Ghosh S.; nzález, D. C.; Thayumanavan, S. J. Am. Chem. Soc. 2008, 130, 5416.
36. [36]
  (36) Darden, T.; York, D.; Pedersen, L. J. Phys Chem. 1993, 98, 10089.
37. [37]
  (37) von Ferber, C.; L?wen, H. Faraday Discuss. 2005,?128, 389.
38. [38]
  (38) ldraich, M.; Schwartz, J. R.; Burns, J. L. Colloids and Surfaces A-Physicochemi. Eng. Aspects 1997, 125, 231.
39. [39]
  (39) Guillot, S.; Delsanti, M.; Desert, S.; Langevin, D. Langmuir 2003, 19, 230.
1. [1]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
2. [2]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
3. [3]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
4. [4]
  Zhi Zhou , Yu-E Lian , Yuqing Li , Hui Gao , Wei Yi . New Insights into the Molecular Mechanism Behind Clinical Tragedies of “Cephalosporin with Alcohol”. University Chemistry, 2025, 40(3): 42-51. doi: 10.12461/PKU.DXHX202403104
5. [5]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
7. [7]
  Zhenming Xu , Yibo Wang , Zhenhui Liu , Duo Chen , Mingbo Zheng , Laifa Shen . Experimental Design of Computational Materials Science and Computational Chemistry Courses Based on the Bohrium Scientific Computing Cloud Platform. University Chemistry, 2025, 40(3): 36-41. doi: 10.12461/PKU.DXHX202403096
8. [8]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
9. [9]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
10. [10]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
11. [11]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
12. [12]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
13. [13]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
14. [14]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
15. [15]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
16. [16]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
17. [17]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
18. [18]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
19. [19]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
20. [20]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028

Get Citation

PDF

XML

Metrics

PDF Downloads(1233)
Abstract views(3086)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Disassembly of Polyelectrolyte/Surfactants Complex Induced by Macroions

References

Metrics

通讯作者: 陈斌, bchen63@163.com