Citation: CHEN Jing-Wei, WANG Xin-Qiang, REN Quan, LI Ting-Bin, YANG Hong-Liang, ZHANG Jing-Nan, LI Guo-Chao. Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 717-721. doi: 10.3866/PKU.WHXB20110340 shu

Third Order Nonlinear Optical Properties of Benzyltriethylamine Bis(2-thioxo-1,3-dithiole-4,5-dithiolato) Aurate(III)

1.
1. Department of Optics, Shandong University, Jinan 250100, P. R. China;
2. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P. R. China;
3. Department of Material Science and Technology, Taishan University, Tai′an 271021, Shandong Province, P. R. China

Received Date: 29 October 2010
Available Online: 21 February 2011
Fund Project: 国家自然科学基金(60778037, 50772059, 11004123) (60778037, 50772059, 11004123) 高等学校全国优秀博士学位论文专项资金(200539) (200539)山东省自然科学基金(ZR2009GQ007)资助项目 (ZR2009GQ007)

We prepared a new crystalline nonlinear optical coordination compound, benzyltriethylamine bis (2-thioxo-1,3-dithiole-4,5-dithiolato) aurate(III) (BTEAADT). A BTEAADT-doped poly(methyl methacrylate) (PMMA) thin film with a mass fraction of 1% was prepared by spin-coating. The third-order nonlinear optical properties of BTEAADT in acetonitrile and a BTEAADT-doped PMMA film were investigated using the laser Z-scan technique with 20 ps pulses at 1064 nm. The linear optical properties of the polymer thin film were also studied. The Z-scan spectra revealed that the polymer thin film sample possessed negative nonlinear refraction and exhibited a similar self-defocusing effect to that found for the solution. In addition, nonlinear absorption was negligible for both systems under the experimental conditions used. The nonlinear refractive index was calculated to be -1.459×10^-18 m²·W^-1 for the solution sample and -3.978×10^-15 m²·W^-1 for the film. These results suggest that this material is a promising candidate for application in nonlinear optical devices such as all-optical switching manufacture at 1064 nm.
- Nonlinear optical property,
- Z-scan,
- Thin film
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