Citation: ZHANG Qi-Bo, HUA Yi-Xin. Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 655-663. doi: 10.3866/PKU.WHXB20110339 shu

Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution

  • Received Date: 20 October 2010
    Available Online: 21 February 2011

    Fund Project: 国家自然科学基金(50864009, 50904031) (50864009, 50904031)高等学校博士学科点专项科研基金(20070674001)资助项目 (20070674001)

  • The effects of three newly synthesized alkylimidazolium based ionic liquids: 1-butyl-3- methylimidazolium hydrogen sulfate ([BMIM]HSO4), 1-hexyl-3-methylimidazolium hydrogen sulfate ([HMIM]HSO4), and 1-octyl-3-methylimidazolium hydrogen sulfate ([OMIM]HSO4), on the corrosion inhibition of copper in 0.5 mol·L-1 H2SO4 solution were investigated using potentiodynamic polarization and electrochemical impedance spectroscopy. All the measurements show that these alkylimidazolium ionic liquids are excellent inhibitors for copper in sulfuric acid media and the effectiveness of these inhibitors decreases as follows: [OMIM]HSO4>[HMIM]HSO4>[BMIM]HSO4 at the same concentration. Potentiodynamic polarization studies indicate that the three inhibitors are mixed type inhibitors and that both the cathodic and anodic processes of copper corrosion are suppressed. The electrochemical impedance results were evaluated using an equivalent circuit in which two constant phase elements (CPE) were offered for these systems with two time constants. Changes in impedance parameters (charge transfer resistance and double layer capacitance) with the addition of the inhibitors also suggest that these imidazolium based molecules act by adsorbing at the copper/solution interface. The adsorption of these imidazolium based compounds on the copper surface in an acidic solution is found to fit the Langmuir adsorption isotherm. Thermodynamic calculations reveal that the adsorption of inhibitors on the metal surface occurs by a physisorption-based mechanism involving a spontaneous process.

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    1. [1]

      (1) Tavakoli, H.; Shahrabi, T.; Hosseini, M. G. Mater. Chem. Phys. 2008, 109, 281.

    2. [2]

      (2) Elmorsi, M. A.; Hassanein, A. M. Corrosion Sci. 1999, 41, 2337.

    3. [3]

      (3) Gassa, L. M.; Ribotta, S. B.; Folquer, M. E.; Vilche, J. R. Corrosion 1998, 54, 179.

    4. [4]

      (4) Zucchi, F.; Grassi, V.; Frignani, A.; Trabanelli, G. Corrosion Sci. 2004, 46, 2853.

    5. [5]

      (5) Walker, R. Corrosion 1973, 29, 290.

    6. [6]

      (6) Walker, R. Corrosion 1975, 31, 97.

    7. [7]

      (7) Kuron, D.; Rother, H. J.; Graefen, H. Werkst. Korros. 1981, 32, 409.

    8. [8]

      (8) Zhao, Y. S.; Pang, Z. Z. Acta Phys. -Chim. Sin. 2003, 19, 419.

    9. [9]

      [赵永生, 庞正智, 物理化学学报, 2003, 19, 419.]

    10. [10]

      (9) Wang, X. Q.; Liu, R. Q.; Zhu, L. Q.; ng, J. W. Acta Phys. -Chim. Sin. 2007, 23, 21.

    11. [11]

      [王献群, 刘瑞泉, 朱丽琴, 宫建伟. 物理化学学报, 2007, 23, 21.]

    12. [12]

      (10) Scendo, M.; Poddebniak, D.; Malyszko, J. J. Appl. Electrochem. 2003, 33, 287.

    13. [13]

      (11) Quraishi, M. A.; Ansari, F. A. J. Appl. Electrochem. 2006, 36, 309.

    14. [14]

      (12) Quraishi, M. A.; Rafiquee, M. Z. A.; Saxena, N.; Khan, S. J. Corrosion Sci. Eng. 2006, 10.

    15. [15]

      (13) El Rehim, S. S. A.; Hassan, H. H.; Amin, M. A. Mater. Chem. Phys. 2003, 78, 337.

    16. [16]

      (14) Bentiss, F.; Traisnel, M.; Chaibi, N.; Mernari, B.; Vezin, H.; Lagrenee, M. Corrosion Sci. 2002, 44, 2271.

    17. [17]

      (15) Lebrini, M.; Lagrenee, M.; Vezin, H.; Gengembre, L.; Bentiss, F. Corrosion Sci. 2005, 47, 485.

    18. [18]

      (16) Li, S. L.; Wang, Y. G.; Chen, S. H.; Yu, R.; Lei, S. B.; Ma, H. Y.; Liu, D. X. Corrosion Sci. 1999, 41, 1769.

    19. [19]

      (17) Scendo, M. Corrosion Sci. 2008, 50, 2070.

    20. [20]

      (18) Stupnišek-Lisac, E.; Gazivoda, A.; Modzarac, M. Electrochim. Acta 2002, 47, 4189.

    21. [21]

      (19) Scendo, M. Corrosion Sci. 2007, 49, 2985.

    22. [22]

      (20) El-Maksoud, S. A. A. Electrochim. Acta 2004, 49, 4205.

    23. [23]

      (21) Forsyth, S. A.; Pringle, J. M.; MacFarlane, D. R. Aust. J. Chem., 2004, 57, 113.

    24. [24]

      (22) Earle, M. J.; Seddon, K. R. Ionic Liquids: Green Solvents for the Future; Pure Appl. Chem. ACS Publications: Washington, DC, 2000.

    25. [25]

      (23) Ashassi-Sorkhabi, H.; Eshaghi, M. Mater. Chem. Phys. 2009, 114, 267.

    26. [26]

      (24) Likhanova, N. V.; Dominguez-Aguilar, M. A.; Olivares-Xometl, O.; Nava-Entzana, N.; Arce, E.; Dorantes, H. Corrosion Sci. 2010, 52, 2088.

    27. [27]

      (25) Zhang, Q. B.; Hua, Y. X. Electrochim. Acta 2009, 54, 1881.

    28. [28]

      (26) Zhang, Q. B.; Hua, Y. X. Mater. Chem. Phys. 2010, 119, 57.

    29. [29]

      (27) Zhang, Q. B.; Hua, Y. X. J. Appl. Electrochem. 2009, 39, 261.

    30. [30]

      (28) Zhang, Q. B.; Hua, Y. X. J. Appl. Electrochem. 2009, 39, 1185.

    31. [31]

      (29) Bentiss, F.; Lagrenee, M.; Traisnel, M.; Mernari, B.; Elattari, H. J. Hetrocycl. Chem. 1999, 36, 149.

    32. [32]

      (30) Tripathy, B. C.; Das, S. C.; Singh, P.; Hefter, G. T.; Misra, V. N. J. Electroanal. Chem. 2004, 565, 49.

    33. [33]

      (31) Stupnisek-Lisac, E.; Podbrscek, S.; Soric, T. J. Appl. Electrochem. 1994, 24, 779.

    34. [34]

      (32) ncalves, R. S.; Azambuja, D. S.; Lucho, A. M. S. Corrosion Sci. 2002, 44, 467.

    35. [35]

      (33) Popova, A.; Raicheva, S.; Sokolova, E.; Christov, M. Langmuir 1996, 12, 2083.

    36. [36]

      (34) Hsu, C. H.; Mansfeld, F. Corrosion 2001, 57, 747.

    37. [37]

      (35) Oquzie, E. E.; Li, Y.; Wang, F. H. J. Colloid Interface Sci. 2007, 310, 90.

    38. [38]

      (36) Khaled, K. F.; Hackerman, N. Electrochim. Acta 2004, 49, 485.

    39. [39]

      (37) Behpour, M.; Ghoreishi, S. M.; Soltani, N.; Salavati-Niasari, M. Corrosion Sci. 2009, 51, 1073.

    40. [40]

      (38) Hosseini, M.; Mertens, S. F. L.; Ghorbani, M.; Arshadi, M. R. Mater. Chem. Phys. 2003, 78, 800.

    41. [41]

      (39) Elkadi, L.; Mernari, B.; Traisnel, M.; Bentiss, F.; Lagrenee, M. Corrosion Sci. 2000, 42, 703.

    42. [42]

      (40) Yan, Y.; Li, W. H.; Cai, L. K.; Hou, B. R. Electrochim. Acta 2008, 53, 5953.

    43. [43]

      (41) Ashassi-Sorkhabi, H.; Shaabani, B.; Seifzadeh, D. Appl. Surf. Sci. 2005, 239, 154.

    44. [44]

      (42) Hermas, A. A.; Morad, M. S.;Wahdan, M. H. J. Appl. Electrochem. 2004, 34, 95.

    45. [45]

      (43) Abd El Rehim, S. S.; Hassan, H. H.; Amin, M. A. Mater. Chem. Phys. 2001, 70, 64.

    46. [46]

      (44) Saleh, M. M. Mater. Chem. Phys. 2006, 98, 83.

    47. [47]

      (45) Saleh, M. R.; Din, A. M. S. E. Corrosion Sci. 1972, 12, 689.

    48. [48]

      (46) Maayta, A. K.; Al-Rawashdeh, N. A. F. Corrosion Sci. 2004, 46, 1129.

    49. [49]

      (47) Lagrenée, B. M.; Bouanisb, M. M.; Traisnelc, M.; Bentiss, F. Corrosion Sci. 2002, 44, 573.

    50. [50]

      (48) Cases, J. M.; Villieras, F. Langmuir 1992, 8, 1251.

    51. [51]

      (49) Abiola, O. K.; Oforka, N. C. Mater. Chem. Phys. 2004, 83, 315.

    52. [52]

      (50) mma, G. K.; Wahdan, M. H. Mater. Chem. Phys. 1995, 39, 209.

    53. [53]

      (51) Smyrl, W. H.; Bockris, J. O. M.; Conway, B. E.; Yeager, E.; White, R. E. Comprehensive Treatise of Electrochemistry; Plenum Press: New York, 1981, Vol. 4.

    54. [54]

      (52) Ma, H. Y.; Chen, S. H.; Yin, B. S.; Zhao, S. Y.; Liu, X. Q. Corrosion Sci. 2003, 45, 867.

    55. [55]

      (53) Quraishi, M. A.; Rafiquee, M. Z. A.; Khan, S.; Saxena, N. J. Appl. Electrochem. 2007, 37, 1153.


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