Citation: MA Yan-Hui, ZHAO Hui-Ling, TANG Sheng-Jie, HU Jun, LIU Hong-Lai. Synthesis of Micro/Mesoporous Composites and Their Application as CO₂ Adsorbents[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 689-696. doi: 10.3866/PKU.WHXB20110335 shu

Synthesis of Micro/Mesoporous Composites and Their Application as CO₂ Adsorbents

1.
Laboratory for Advanced Materials οf Ministry of Education, Department of Chemistry, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 21 September 2010
Available Online: 18 February 2011
Fund Project: 国家自然科学基金(20736002, 20776045) (20736002, 20776045) 国家高技术研究发展计划(863)(2008AA062302) (863)(2008AA062302)长江学者创新团队(IRT0721)资助项目 (IRT0721)

We synthesized a series of micro/mesoporous composites of S-β-MCM41(c), P-β-MCM41(c), P-ZSM-MCM41(c), P-ZSM-C through a two-step crystallization process. During this process, the microporous zeolite precursor solution (S) or the zeolite powder (P) was first synthesized and treated with NaOH solution with different concentration (c), and then the mesopores were induced by hexadecyltrimethyl- ammoniumbromide (CTAB) as a soft template or mesoporous carbon as a hard template. The effects of the type of inorganic precursor, the base concentration, and the type of mesoporous template on the structure and property of the micro/mesoporous composites were investigated. The results of X-ray diffraction (XRD), transmission electron microscopy (TEM), and nitrogen adsorption-desorption isotherms showed that the products contained micropores and mesopores, simultaneously. The CO₂ adsorption capacities of these micro/mesoporous composites were obviously improved compared to the pure microporous or mesoporous materials. Among them, P-ZSM-MCM41(2) had the highest CO₂ adsorption capacity of 1.51 mmol·g^-1, which was almost twice that of the original ZSM-5.
- Micro/mesoporous composite material,
- CO₂ adsorption,
- Dual-template,
- Two-step crystallization,
- Basic solution concentration
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Micro/Mesoporous Composites and Their Application as CO2 Adsorbents

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Synthesis of Micro/Mesoporous Composites and Their Application as CO₂ Adsorbents