Citation: LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min. Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 620-626. doi: 10.3866/PKU.WHXB20110331 shu

Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance

1.
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong Province, P. R. China

Received Date: 7 October 2010
Available Online: 17 February 2011
Fund Project: 山东省优秀中青年科学家科研奖励基金(BS2009NJ014) (BS2009NJ014)山东省科技攻关项目(2009GG10007006)资助 (2009GG10007006)

Several microporous carbons were prepared by polyfurfuryl alcohol-impregnation and impregnation-acetonitrile chemical vapor deposition (CVD) using zeolite HY as a template, denoted as PFA carbons and AN carbons, respectively. These were used as electrode materials for supercapacitors. X-ray diffraction (XRD) patterns show that the structural regularity of the zeolite was well-replicated by the carbon structures prepared by impregnation-CVD. X-ray photoelectron spectroscopy (XPS) confirmed that the AN carbons possess abundant nitrogen-containing groups because of the CVD of acetonitrile. The prepared carbons were typical microporous materials as determined by N₂ adsorption/desorption test and they had a high BET surface area and narrow pore size distribution. Electrochemical tests showed that the AN carbons had higher capacitance because of their evident pseudo-capacitance from the nitrogen- containing groups. AN8 had a high capacitance up to 210 F·g^-1. The capacitance retention ratio of the AN carbons were determined to its electric conductivity and mesoporosity.
- HY zeolite,
- Microporous carbon material,
- Chemical vapor deposition,
- Supercapacitor,
- Templating method
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