Citation: WANG Yu, YU Gang, CAI Bin, ZHU Yue-Xiang, XIE You-Chang. Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 729-735. doi: 10.3866/PKU.WHXB20110321 shu

Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 12 October 2010
Available Online: 15 February 2011
Fund Project: 国家自然科学基金(20773004) (20773004)国家重点基础研究发展规划项目(973) (2011CB808702)资助 (973) (2011CB808702)

Mesoporous carbon materials with a range of pore sizes were synthesized by a delicately controlled procedure using disordered γ-alumina as template and sucrose as carbon source. Under optimized conditions, the carbon materials had narrow pore size distribution, large surface area (>1000 m²·g^-1), large pore volume (up to 3.82 cm³·g^-1), high mesopore ratio (>99%), and thin pore walls with thickness of 1-2 graphene layers. In the present work, we employed three types of alumina, and investigated the correlation of their texture with that of the resultant carbon materials. A mechanism for the formation of the carbon materials was proposed and tested against experimental data. A carbon sample prepared by this method can approximately duplicate the pore structure of the template, if the carbon layer in the precursor carbon-covered alumina is complete and sufficiently robust. The mesopores of the carbons had two sources, one from the removal of the template particles and the other from the original pores of the template. Calculated pore volumes strongly support the proposed mechanism.
- Mesoporous carbon,
- Thin pore wall,
- Controllable synthesis,
- Disordered template,
- Mechanism,
- Alumina
1. [1]
  
  (1) Han, S. J.; Sohn, K.; Hyeon, T. Chem. Mater. 2000, 12, 3337.
2. [2]
  (2) Hartmann, M.; Vinu, A.; Chandrasekar, G. Chem. Mater. 2005, 17, 829.
3. [3]
  (3) Zhuang, X.; Wan, Y.; Feng, C. M.; Shen, Y.; Zhao, D. Y. Chem. Mater. 2009, 21, 706.
4. [4]
  (4) Joo, S. H.; Choi, S. J.; Oh, I.; Kwak, J.; Liu, Z.; Terasaki, O.; Ryoo, R. Nature 2001, 412, 169.
5. [5]
  (5) Nam, J. H.; Jang, Y. Y.; Kwon, Y. U.; Nam, J. D. Electrochem. Commun. 2004, 6, 737.
6. [6]
  (6) Cui, X. Z.; Shi, J. L.; Zhang, L. X.; Ruan, M. L.; Gao, J. H. Carbon 2009, 47, 186.
7. [7]
  (7) Li, L. X.; Song, H. H.; Chen, X. H. Electrochim. Acta 2006, 51, 5715.
8. [8]
  (8) Wang, D. W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Edit. 2008, 47, 373.
9. [9]
  (9) Xia, K. S.; Gao, Q. M.; Jiang, J. H.; Hu, J. Carbon 2008, 46, 1718.
10. [10]
  (10) Numaoa, S.; Judaia, K.; Nishijoa, J.; Mizuuchib, K.; Nishia, N. Carbon 2009, 47, 306.
11. [11]
  (11) Lu, A. H.; Schüth, F. Adv. Mater. 2006, 18, 1793.
12. [12]
  (12) Lee, J.; Kim, J.; Hyeon, T. Adv. Mater. 2006, 18, 2073.
13. [13]
  (13) Liang, C. D.; Li, Z. J.; Dai, S. Angew. Chem. Int. Edit. 2008, 47, 3696.
14. [14]
  (14) Ryoo, R.; Joo, S. H.; Jun, S. J. Phys. Chem. B 1999, 103, 7743.
15. [15]
  (15) Lee, J.; Yoon, S.; Oh, S. M.; Shin, C. H.; Hyeon, T. Adv. Mater. 2000, 12, 359.
16. [16]
  (16) Jun, S.; Joo, S. H.; Ryoo, R.; Kruk, M.; Jaroniec, M.; Liu, Z.; Ohsuna, T.; Terasaki, O. J. Am. Chem. Soc. 2000, 122, 10712.
17. [17]
  (17) Lu, A. H.; Schmidt, W.; Spliethoff, B.; Schüth, F. Adv. Mater. 2003, 15, 1602.
18. [18]
  (18) Gierszal, K. P.; Jaroniec, M.; Liang, C. D.; Dai, S. Carbon 2007, 45, 2171.
19. [19]
  (19) Kyotani, T.; Tsai, L.; Tomita, A. Chem. Mater. 1995, 7, 1427.
20. [20]
  (20) Parthasarathy, R. V.; Phani, K. L. N.; Martin, C. R. Adv. Mater. 1995, 7, 896.
21. [21]
  (21) Cott, D. J.; Petkov, N.; Morris, M. A.; Platschek, B.; Bein, T.; Holmes, J. D. J. Am. Chem. Soc. 2006, 128, 3920.
22. [22]
  (22) Lin, L.; Wang, P.; Wang, S. R.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C. Carbon 2006, 44, 3120.
23. [23]
  (23) Inagaki, M.; Kato, M.; Morishita, T.; Morita, K.; Mizuuchi, K. Carbon 2007, 45, 1121.
24. [24]
  (24) Zhao, C. R.; Wang, W. K.; Yu, Z. B.; Zhang, H.; Wang, A. B.; Yang, Y. S. J. Mater. Chem. 2010, 20, 976,
25. [25]
  (25) Xu, B.; Peng, L.; Wang, G. Q.; Cao, G. P.; Wu, F. Carbon 2010, 48, 2377.
26. [26]
  (26) Ng, Y. H.; Ikeda, S.; Harada, T.; Park, S.; Sakata, T.; Mori, H.; Matsumura, M. Chem. Mater. 2008, 20, 1154.
27. [27]
  (27) Shi, L. M.; Yao, J. F.; Jiang, J. L.; Zhang, L. X.; Xu, N. P. Microporous Mesoporous Mat. 2009, 122, 294.
28. [28]
  (28) Morishita, T.; Tsumura, T.; Toyoda, M.; Przepiórski, J.; Morawski, A. W.; Konno, H.; Inagaki, M. Carbon 2010, 48, 2690.
29. [29]
  (29) Wang, Y.; Lin, L.; Zhu, B. S.; Zhu, Y. X.; Xie, Y. C. Appl. Surf. Sci. 2008, 254, 6560.
30. [30]
  (30) Groen, J. C.; Peffer, L. A. A.; Pérez-Ramírez, J. Microporous Mesoporous Mat. 2003, 60, 1.
31. [31]
  (31) Lin, L.; Lin, W.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.; Jia, G. Q.; Li, C. Langmuir 2005, 21, 5040.
1. [1]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
2. [2]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
3. [3]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
4. [4]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
5. [5]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
6. [6]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
9. [9]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
12. [12]
  Yajun Jian , Quanguo Zhai , Quan Gu , Shengli Gao . Reconstruction and Practice of the Teaching Content of “Carbon Group Elements” in Inorganic Chemistry to Reflect Comprehensive Education Function. University Chemistry, 2024, 39(11): 96-107. doi: 10.12461/PKU.DXHX202403006
13. [13]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
14. [14]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
15. [15]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
16. [16]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
17. [17]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
18. [18]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
19. [19]
  Tao Wen , Tao Zhang , Changguo Sun , Jinyu Liu . Preparation of Dess-Martin Reagent and Its Application in Oxidizing Cyclohexanol. University Chemistry, 2024, 39(5): 20-26. doi: 10.3866/PKU.DXHX202309055
20. [20]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031

Get Citation

PDF

XML

Metrics

PDF Downloads(1149)
Abstract views(2743)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142