Citation: YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling, CAO Dian-Xue. Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 615-619. doi: 10.3866/PKU.WHXB20110317 shu

Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam

1.
College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, P. R. China

Received Date: 15 October 2010
Available Online: 28 January 2011
Fund Project: 国家自然科学基金(20973048) (20973048)中央高校基金(HEUCF101004)资助项目 (HEUCF101004)

We prepared an electrode consisting of NiCo₂O₄ nanowire arrays that stand freely on nickel foam by a template-free growth method. Its morphology was determined by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The phase structure of the nanowires was analyzed by X-ray diffraction (XRD). The supercapacitance of the electrode was investigated by cyclic voltammetry, galvanostatic charge-discharge testing, and electrochemical impedance spectroscopy. The results showed that the nanowires were nearly vertical grow on and densely cover the nickel foam substrate. The nanowires have diameters around 500-1000 nm and lengths up to around 10 μm. The NiCo₂O₄ nanowire arrays have a specific capacitance of 741 F·g^-1 and this value is 655 F·g^-1 after 420 charge-discharge cycles. Electrochemical impedance spectroscopy measurements showed that the charge transfer resistance was only 0.33 Ω and this increased by only 0.06 Ω after 420 cycles.
- NiCo₂O₄,
- Nanowire array,
- Template-free growth method,
- Nickel foam,
- Surpercapacitor
1. [1]
  
  1 Burke, A. Electrochim. Acta 2007, 53, 1083.
2. [2]
  2 Kotz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483.
3. [3]
  3 Burke, A. J. Power Sources 2000, 91, 37.
4. [4]
  4 Zhang, Y.; Feng, H.; Wu, X.; Wang, L.; Zhang, A.; Xia, T.; Dong, H.; Li, X.; Zhang, L. Inter. J. Hydrog. Energy 2009, 34, 4889.
5. [5]
  5 Simon, P.; tsi, Y. Nat. Mater. 2008, 7, 845.
6. [6]
  6 Tian, Y.; Yan, J. W.; Liu, X. X.; Xu, R.; Yi, B. L. Acta Phys. -Chim. Sin. 2010, 26, 2151.
7. [7]
  [田颖, 阎景旺, 刘小雪, 薛荣, 衣宝廉. 物理化学学报, 2010, 26, 2151].
8. [8]
  7 Nam, K. T.; Kim, D. W.; Yoo, P. J.; Chiang, C. Y.; Meethong, N.; Hammond, P. T.; Chiang, Y. M.; Belcher, A. M. Science 2006, 312, 885.
9. [9]
  8 Li, Y.; Tan, B.; Wu, Y. J. Am. Chem. Soc. 2006, 128, 14258.
10. [10]
  9 Li, Y.; Tan, B.; Wu, Y. Nano Lett. 2008, 8, 265.
11. [11]
  10 Gao, Y. Y.; Chen, S. L.; Cao, D. X.; Wang, G. L.; Yin, J. L. J. Power Sources 2010, 195, 1757.
12. [12]
  11 Wang, G.; Cao, D.; Yin, C.; Gao, Y.; Yin, J.; Cheng, L. Chem. Mater. 2009, 21, 5112.
13. [13]
  12 Li, Y.; Tan, B.; Wu, Y. Chem. Mater. 2008, 20, 2602.
14. [14]
  13 Li, Y.; Hasin, P.; Wu, Y. Adv. Mater. 2010, 22, 1926.
15. [15]
  14 Wu, G.; Li, N.; Zhou, D. R.; Mitsuo, K.; Xu, B. Q. J. Solid State Chem. 2004, 177, 3682.
16. [16]
  15 Hu, C. C.; Lee, Y. S.; Wen, T. C. Mater. Chem. Phys. 1997, 48, 246.
17. [17]
  16 Cui, B.; Lin, H.; Li, J.B.; Li, X.; Yang, J.; Tao, J. Adv. Funct. Mater. 2008, 18, 1441.
18. [18]
  17 Singh, R. N.; Koenig, J. F.; Poillerat, G.; Chartier, P. J. Electrochem. Soc. 1990, 137, 1408.
19. [19]
  18 Chi, B.; Lin, H.; Li, J.; Wang, N.; Yang, J. Inter. J. Hydrog. Energy 2006, 31, 1210.
1. [1]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
6. [6]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
7. [7]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
8. [8]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
9. [9]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
10. [10]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
11. [11]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
12. [12]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
13. [13]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
14. [14]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
15. [15]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
16. [16]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
17. [17]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
18. [18]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040
19. [19]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
20. [20]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

Get Citation

PDF

XML

Metrics

PDF Downloads(2415)
Abstract views(3006)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam

Metrics

通讯作者: 陈斌, bchen63@163.com

Supercapacitance of NiCo₂O₄ Nanowire Arrays Grown on Nickel Foam