Citation: ZHOU Li-Min, SHANG Chao, LIU Zhi-Rong. Acid Dye Adsorption Properties of Ethylenediamine-Modified Magnetic Chitosan Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 677-682. doi: 10.3866/PKU.WHXB20110314 shu

Acid Dye Adsorption Properties of Ethylenediamine-Modified Magnetic Chitosan Nanoparticles

1.
1. State Key Laboratory Breeding Base of Nuclear Resources and Environment, East China Institute of Technology, Nanchang 330013, P. R. China;
2. Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Fuzhou 344000, Jiangxi Province, P. R. China

Received Date: 8 December 2010
Available Online: 28 January 2011
Fund Project: 江西省科技支撑项目(2009BSB08600) (2009BSB08600)江西省教育厅科技项目(GJJ10494)资助 (GJJ10494)

Ethylenediamine-modified magnetic chitosan nanoparticles (EMCN) were prepared and used for the adsorption of Acid Orange 7 (AO7) and Acid Orange 10 (AO10) from aqueous solutions. Magnetic chitosan nanoparticles were prepared by adding a basic precipitant NaOH solution to a W/O microemulsion system containing cyclohexane/n-hexanol, chitosan and ferrous salt. This was then modified with ethylenediamine to increase the amine content and to improve the adsorption capacity. Transmission electron microscopy showed that the EMCN was essentially monodispersed and had a main particle size distribution of 15-40 nm. Adsorption experiments indicated that the maximum adsorption capacity was at a pH of 4.0 for AO7 and a pH of 3.0 for AO10. Because of the small diameter and the high surface reactivity of EMCN, the adsorption equilibrium for both dyes was reached very quickly. The equilibrium experiments fitted the Langmuir isotherm model well and the maximum adsorption capacities of 3.47 and 2.25 mmol·g^-1 were obtained for AO7 and AO10, respectively. We estimated the thermodynamic parameters and accordingly the adsorption process was found to be spontaneous and exothermic. Additionally, we regenerated EMCN with an NH⁴OH/NH⁴Cl solution (pH 10.0) and the regenerated material was used to readsorb the dyes.
- Adsorption,
- Chitosan,
- Magnetic nanoparticle,
- Ethylenediamine,
- Acid dye
1. [1]
  
  (1) Zollinger, H. Colour Chemistry -Synthesis, Properties of Organic Dyes and Pigments; VCH Publishers: New York, 1987; pp 28-35.
2. [2]
  (2) Lin, S. H.; Peng, C. F. Water Res. 1994, 28, 277.
3. [3]
  (3) McMullan, G.; Meehan, C.; Conneely, A.; Kirby, N.; Robinson, T.; Nigam, P.; Banat, I. M.; Marchant, R.; Smyth, W. F. Appl . Microbiol. Biotechnol. 2001, 56, 81.
4. [4]
  (4) Liu, D.; Xu, Y. M. Acta Phys. -Chim. Sin. 2008, 24, 1584.
5. [5]
  [刘鼎许宜铭. 物理化学学报, 2008, 24, 1584.]
6. [6]
  (5) Jiang, R.; Zhu, H. Y.; Li, X. D.; Xiao, L. Chem. Eng. J. 2009, 152, 537.
7. [7]
  (6) Kamari, A.; Wan, N. W.; Chong, M. Y.; Cheah, M. L. Desalination 2009, 249, 1180.
8. [8]
  (7) Zhu, H. Y.; Jiang, R.; Xiao, L. Appl. Clay Sci. 2010, 48, 522.
9. [9]
  (8) Crini, G.; Badot, P. M. Prog. Polym. Sci. 2008, 33, 399.
10. [10]
  (9) Kyzas, G. Z.; Lazaridis, N. K. J. Colloid Interface Sci. 2009, 331, 32.
11. [11]
  (10) Singha, V.; Sharma, A. K.; Tripathi, D. N.; Sanghi R. J. Hazard. Mater. 2009, 161, 955.
12. [12]
  (11) Konaganti,V.; Kota, R.; Patil, S.; Madras, G. Chem. Eng. J. 2010, 158, 393.
13. [13]
  (12) Elkholy, S.; Khalil, K. D.; Elsabee, M. Z.; Ewels, M. J. Appl. Polm. Sci. 2007, 103, 1651.
14. [14]
  (13) Chang, Y. C.; Chang, S. W.; Chen, D. H. React. Funct. Polym. 2006, 66, 335.
15. [15]
  (14) Zhi, J.; Wang, Y.; Lu, Y.; Ma, J.; Luo, G. React. Funct. Polym. 2006, 66, 1552.
16. [16]
  (15) Atia, A. A. Hydrometallurgy 2005, 80, 13.
17. [17]
  (16) Latha,G. A.; George, K. B.; Kannan, G. K.; Ninan, N. K. J. Appl. Polm. Sci. 1991, 43, 1159.
18. [18]
  (17) Ramnani, S. P.; Sabharwal, S. React. Funct. Polym. 2006, 66, 902.
19. [19]
  (18) Chen, A. H.; Chen, S. M. J. Hazard. Mater. 2009, 172, 1111.
20. [20]
  (19) Varma, A. J.; Deshpande, S. V.; Kennedy, J. F. Carbohydr. Polym. 2004, 55, 77.
21. [21]
  (20) Qi, L.; Xu, Z. Colloids Surf. A 2004, 251, 186.
22. [22]
  (21) Tellinghuisen, J. Biophys. Chem. 2006, 120, 114.
1. [1]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
2. [2]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
3. [3]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
4. [4]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
5. [5]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
6. [6]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
7. [7]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
8. [8]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
9. [9]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
10. [10]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
11. [11]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
12. [12]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
13. [13]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
14. [14]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
15. [15]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
16. [16]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
17. [17]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
18. [18]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
19. [19]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
20. [20]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061

Get Citation

PDF

XML

Metrics

PDF Downloads(1267)
Abstract views(3501)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142