Citation: WANG Zhi-Ping, LUO Hong, GAO Li-Hua, WANG Ke-Zhi. Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 754-758. doi: 10.3866/PKU.WHXB20110313 shu

Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue

1.
1. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China;
2. Jining Teachers College, Jining 012000, Inner Mon lia, P. R. China;
3. School of Chemical and Environmental Engineering, Beijing Technology and Business University, Beijing 100048, P. R. China

Received Date: 30 November 2010
Available Online: 28 January 2011
Fund Project: 国家自然科学基金(20971016, 90922004, 20871011) (20971016, 90922004, 20871011) 中央高校基本科研业务费专项基金, 北京市自然科学基金(2092011) (2092011)

We successfully prepared a novel inorganic-organic hybrid electrostatically self-assembled multilayer film by alternately depositing Prussian blue (PB) and a thiophene-containing hemicyanine. The optical, electrochemical, and photoelectrochemical properties of the as-prepared films were studied by UV-visible absorption spectroscopy, cyclic voltammetry, and photoelectrochemical experiment. Linear increases in the absorbances at 376 and 698 nm with the number of deposited layers, up to at least 8 layers, indicated that film deposition was uniform and reproducible. The PB in the prepared films was found to occur surface-confined rather than diffusion-controlled redox reactions and the peak currents increased with an increase in the number of layers up to 5 layers. Upon irradiation with 100 mW·cm^-2 white light the films exhibited stable and reproducible cathodic photocurrents, which increased as the number of layers increased up to 4 layers. A maximum photocurrent density of 0.28 μA·cm^-2 was found for the four-layer film at a bias voltage of -0.4 V vs the saturated calomel electrode.
- Hemicyanine,
- Self-assembled film,
- Cyclic voltammetry,
- UV-visible spectrum,
- Thiophene,
- Photoelectrochemical property
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