Citation: WANG Zhi-Ping, LUO Hong, GAO Li-Hua, WANG Ke-Zhi. Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 754-758. doi: 10.3866/PKU.WHXB20110313 shu

Electrostatically Self-Assembled Films Prepared Using Bipolar Thiophene Hemicyanine and Prussian Blue

1.
1. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China;
2. Jining Teachers College, Jining 012000, Inner Mon lia, P. R. China;
3. School of Chemical and Environmental Engineering, Beijing Technology and Business University, Beijing 100048, P. R. China

Received Date: 30 November 2010
Available Online: 28 January 2011
Fund Project: 国家自然科学基金(20971016, 90922004, 20871011) (20971016, 90922004, 20871011) 中央高校基本科研业务费专项基金, 北京市自然科学基金(2092011) (2092011)

We successfully prepared a novel inorganic-organic hybrid electrostatically self-assembled multilayer film by alternately depositing Prussian blue (PB) and a thiophene-containing hemicyanine. The optical, electrochemical, and photoelectrochemical properties of the as-prepared films were studied by UV-visible absorption spectroscopy, cyclic voltammetry, and photoelectrochemical experiment. Linear increases in the absorbances at 376 and 698 nm with the number of deposited layers, up to at least 8 layers, indicated that film deposition was uniform and reproducible. The PB in the prepared films was found to occur surface-confined rather than diffusion-controlled redox reactions and the peak currents increased with an increase in the number of layers up to 5 layers. Upon irradiation with 100 mW·cm^-2 white light the films exhibited stable and reproducible cathodic photocurrents, which increased as the number of layers increased up to 4 layers. A maximum photocurrent density of 0.28 μA·cm^-2 was found for the four-layer film at a bias voltage of -0.4 V vs the saturated calomel electrode.
- Hemicyanine,
- Self-assembled film,
- Cyclic voltammetry,
- UV-visible spectrum,
- Thiophene,
- Photoelectrochemical property
1. [1]
  
  (1) Decher, G. Science 1997, 277, 1232.
2. [2]
  (2) Zhang, X.; Chen, H.; Zhang, H. Y. Chem. Commun. 2007, 1395.
3. [3]
  (3) Wang, K. Z.; Gao, L. H. Mater. Res. Bull. 2002, 37, 2447.
4. [4]
  (4) Lang, A. D.; Zhai, J.; Huang, C. H.; Gan, L. B.; Zhao, Y. L.; Zhou, D. J.; Chen, Z. D. J. Phys. Chem. B 1998, 102, 1424.
5. [5]
  (5) Yao, Q. H.; Shan, L.; Li, F. Y.; Yin, D. D.; Huang, C. H. Acta Phys. -Chim. Sin. 2003, 19, 635.
6. [6]
  [姚巧红, 单路, 李富有, 尹冬冬, 黄春辉, 物理化学学报, 2003, 19, 635.]
7. [7]
  (6) Wang, K. Z.;?Huang, C. H.; Xu, G. X.; Xu, Y.; Liu, Y. Q.; Zhu, D. B.; Zhao, X. S.; Xie, X. M.; Wu. N. Z. Chem. Mater. 1994, 6, 1986.
8. [8]
  (7) Wang, K. Z.;?Huang, C. H.; Xu, G. X.; Zhao, X. S.; Xia, X. H.; Wu, N. Z.; Xu, L. G.; Li, T. K. Thin Solid Films 1994, 252, 139.
9. [9]
  (8) Wang, K. Z.; Huang, C. H.; Xu, G. X.; Wang, R. J. Polyhedron 1995, 14, 3669.
10. [10]
  (9) Wang, K. Z.; Jiang, W.; Huang, C. H.; Xu, G. X.; Xu, L. G.; Li, T. K.; Zhao, X. S.; Xie, X. M. Chem. Lett. 1995, 1761.
11. [11]
  (10) Wang, K. Z.; Huang, C. H.; Zhou, D. J.; Xu, G. X.; Xu, Y.; Li, Y. Q.; Zhu, D. B.; Zhao, X. S.; Xie, X. M. Solid State Commun. 1995, 93, 189.
12. [12]
  (11) Wang, L. Y.; Wang, K. Z.; Gao, L. H. Acta Chim. Sin. 2003, 61, 1877.
13. [13]
  [王丽颖. 王科志. 高丽华. 化学学报, 2003, 61, 1877.]
14. [14]
  (12) Gao, L. H.; Hu, X. J.; Zheng, D. S.; Guo, Y.; Wang, K. Z. J. Nanosci. Nanotechnol. 2008, 8, 1355.
15. [15]
  (13) Gao, L. H.; Wang, K. Z.; Wang, L. Y. J. Nanosci. Nanotechnol. 2010, 10, 2018.
16. [16]
  (14) Ju, C. C.; Luo, H.; Wang, K. Z. J. Nanosci. Nanotechnol. 2010, 10, 2053.
17. [17]
  (15) Zou, X.; Fan, Y.; Zhuang, M. Y.; Peng, J.; Wang, K. Z. J. Nanosci. Nanotechnol. 2010, 10, 2203.
18. [18]
  (16) Zhang, Y. Q.; Gao, L. H.; Wang, K. Z.; Gao, H. J.; Wang, Y. L. J. Nanosci. Nanotechnol. 2008, 8, 1248.
19. [19]
  (17) Wang, Y. B.; Xia, J. Y.; Gao, L. H.; Wang, K. Z. Chem. J. Chin. Univ. 2007, 28, 1175.
20. [20]
  [王宜冰, 夏即雅, 高丽华, 王科志. 高校化学学报, 2007, 28, 1175.]
21. [21]
  (18) Zhou, X.; Fan, Y.; Zhuang, M. Y.; Peng, J.; Gao, L. H.; Wang, K. Z. Acta Chim. Sin. 2010, 68, 2250.
22. [22]
  [邹旭, 范娅, 庄, 彭景, 高丽华, 王科志. 化学学报, 2010, 68,. 2250.]
23. [23]
  (19) Zhang, Y. Q.; Gao, L. H.; Duan, Z. M.; Wang, K. Z.; Wang, Y. L.; Gao, H. J. Acta Chim. Sin. 2004, 62, 738.
24. [24]
  [张玉琦, 高, 段智明, 王科志, 王业亮, 高鸿均. 化学学报 2004, 62, 738.]
25. [25]
  (20) Mishra, A.; Ma, C. Q.; Baeuerle, P. Chem. Rev. 2009, 109, 1141.
26. [26]
  (21) Karyakin, A. A. Electroanalysis 2001, 13, 813.
27. [27]
  (22) Dei, A. Angew. Chem. Int. Edit. 2005, 44, 1160.
28. [28]
  (23) Ricci, F.; Palleschi, G. Biosens. Bioelectron. 2005, 21, 389.
29. [29]
  (24) Itaya, K.; Uchida, I.; Neff, V. D. Acc.ounts Chem. Res. 1986, 19, 162.
30. [30]
  (25) Robin, M. B. Inorg. Chem. 1962, 1, 337.
31. [31]
  (26) Dostal, A.; Meyer, B.; Scholz, F.; Bond, A. M.; Marken, F.; Shaw, S. J. J. Phys. Chem. 1995, 99, 2096.
1. [1]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
2. [2]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
5. [5]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
6. [6]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
10. [10]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
11. [11]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
12. [12]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
13. [13]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
14. [14]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
15. [15]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
16. [16]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
17. [17]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
18. [18]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
19. [19]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
20. [20]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086

Get Citation

PDF

XML

Metrics

PDF Downloads(1124)
Abstract views(2457)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142