Citation: ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long. Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 705-710. doi: 10.3866/PKU.WHXB20110311 shu

Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke

1.
1. Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, P. R. China;
2. Technology Center, China Tobacco of Zhejiang Industrial Company, Hangzhou 310008, P. R. China

Received Date: 13 October 2010
Available Online: 27 January 2011
Fund Project: 国家重点基础研究重大项目计划(973)(2010CB732300) (973)(2010CB732300)上海市自然科学基金(09ZR1408200)资助 (09ZR1408200)

Pd-Cu/activated carbon catalysts were prepared by wetness impregnation and their performance in the room-temperature catalytic oxidation of the pulse reaction of carbon monoxide were investigated using simulated cigarette smoke gas consisting of 4.4 CO-4.2 H₂O-19.2 O₂-72.2 He (volume fraction, %). The effect of different activated carbon supports on catalytic performance was investigated in detail. The results show that at room temperature the order of catalytic performance for CO oxidation is: the catalyst supported on coconut activated carbon (CAC)2+ and Pd⁰ are also present on the surfaces of the CAC and WAC catalysts but only Pd²⁺ is present on the surface of the SAC catalysts, which results in better catalytic activity for SAC than that of the CAC and WAC catalysts. When the ternary composite filter was prepared by inserting the catalyst between the cigarette filter and the acetate filter rod, the smoking tests showed that the amount of CO in the main cigarette smoke decreased noticeably. The SAC catalyst reduced CO by 25.4% when the amount of Pd in the catalyst increased to 3.4% (w).
- Cigarette smoke,
- Carbon monoxide,
- Room-temperature catalytic oxidation,
- Activated carbon
1. [1]
  
  (1) Chen, M. S.; odman, D. W. Science 2004, 306, 252.
2. [2]
  (2) Campbell, C. T. Science 2004, 306, 234.
3. [3]
  (3) Shelef, M.; McCabe, R. W. Catal. Today 2000, 62, 35.
4. [4]
  (4) Twigg, M. V. Appl. Catal. B 2007, 70, 2.
5. [5]
  (5) Xie, X.; Li, Y.; Liu, Z. Q.; Haruta, M.; Shen, W. Nature 2009, 458, 746.
6. [6]
  (6) Qiao, B.; Liu, L.; Zhang, J.; Deng, Y. J. Catal. 2009, 261, 241.
7. [7]
  (7) Li, S.; Liu, G.; Lian, H.; Jia, M.; Zhao, G.; Jiang, D.; Zhang, W. Catal. Commun. 2008, 9, 1045.
8. [8]
  (8) Antonio, G. C.; Gabriela, D.; Rodolfo, Z.; Humberto, R.; Patricia, S.; José, M. S. J. Phys. Chem. C 2009, 113, 9710.
9. [9]
  (9) Dyakonov, A. J. Appl. Catal. B 2003, 45, 257.
10. [10]
  (10) Zhang, Y. Q.; Gu, Z. T.; Zhuang, L.; Wang, L. Y. Cu-Pd Modified Activated Carbon Fiber Composite Filter. CN Patent 2803014, 2005-04-14.
11. [11]
  [张玉清, 顾中铸, 庄磊, 王力友. 铜钯基改性活性炭纤维复合过滤嘴. 中国, CN2803014
12. [12]
  [P]. 2005-04-14]
13. [13]
  (11) Zhang, Y. Q.; Zhuang, L.; Gu, Z. T. Synthesis of Modified Activated Carbon Fiber for Cigarette Filtration and Abatement of Hazardous Substance. CN Patent 1692848, 2005-06-20.
14. [14]
  [清, 庄磊, 顾中铸. 用于卷烟过滤降害的改性活性炭纤其制备方法. 中国, CN1692848
15. [15]
  [P]. 2005-06-20]
16. [16]
  (12) Park, E. D.; Lee, J. S. J. Catal. 2000, 193, 5.
17. [17]
  (13) Gurrath, M.; Kuretzky, T.; Boehm, H. P.; Okhlopkova, L. B.; Lisitsyn, A. S.; Likholobov, V. A. Carbon 2000, 38, 1241.
18. [18]
  (14) Okhlopkova, L. B.; Lisitsyn, A. S.; Likholobov, V. A.; Gurrath, M.; Boehm, H. P. Appl. Catal. A 2000, 204, 229.
19. [19]
  (15) Park, E. D.; Lee, J. S. J. Catal. 1998, 180, 123.
20. [20]
  (16) Yamamoto, Y.; Matsuzaki, T.; Ohdan, K.; Okamoto, Y. J. Catal. 1996, 161, 577.
21. [21]
  (17) Izatt, R. M.; Eatough, D.; Christensen, J. J. J. Chem. Soc. 1967, 1301.
22. [22]
  (18) Wu, J. C. S.; Chang, T. Y. Catal. Today 1998, 44, 111.
23. [23]
  (19) Park, E. D.; Choi, S. H.; Lee, J. S. J. Phys. Chem. B 2000, 104, 5586.
24. [24]
  (20) Deevi, S.; Ettireddy, P. R. Catalysts to Reduce Carbon Monoxide Such As in the Mainstream Smoke of a Cigarett. WO. Pat. Appl. PCT/IB2007/001775, 2007.
1. [1]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
6. [6]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
7. [7]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
8. [8]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
9. [9]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
10. [10]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
11. [11]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
12. [12]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
13. [13]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
14. [14]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
15. [15]
  Yutao Lu , Jing Wu . Rebirth from the Flames: Unveiling the “Chemical Secrets” of Fire Smoke. University Chemistry, 2024, 39(9): 208-213. doi: 10.12461/PKU.DXHX202401001
16. [16]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
17. [17]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
18. [18]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
19. [19]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
20. [20]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085

Get Citation

PDF

XML

Metrics

PDF Downloads(1160)
Abstract views(2440)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142