Citation: XU Jun-Ke, SHEN Li-Hong, ZHOU Wei, MA Jian-Xin. Mechanism of Biogas Reforming for Hydrogen Production over Ni-Co Bimetallic Catalyst[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 697-704. doi: 10.3866/PKU.WHXB20110309 shu

Mechanism of Biogas Reforming for Hydrogen Production over Ni-Co Bimetallic Catalyst

XU Jun-Ke ^1,2 ,
SHEN Li-Hong ² ,
ZHOU Wei ^1,3 ,
MA Jian-Xin ^1,3,

1.
1. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 201804, P. R. China;
2. Shanghai Baoshan Environmental Monitoring Station, Shanghai 201901, P. R. China;
3. School of Automotive Engineering, Tongji University, Shanghai 201804, P. R. China

Received Date: 27 September 2010
Available Online: 27 January 2011
Fund Project: 科技部国际合作重点项目(2007DFC61690) (2007DFC61690)汉高同济教席(081591)资助 (081591)

Ni-Co bimetallic catalysts supported on commercial γ-Al₂O₃ modified with La₂O₃ were prepared by conventional incipient wetness impregnation for biogas reforming. The catalysts were characterized using temperature-programmed hydrogenation (TPH), temperature-programmed oxygenation (TPO), temperature-programmed surface reaction (TPSR), temperature-programmed desorption (TPD), and a pulse experiment. During biogas reforming the surface carbon species on Ni-Co/La₂O₃-γ-Al₂O₃ originated mainly from the cracking of CH₄ and the contribution of CO₂ was insignificant. Cracking of CH₄ results in three carbon species of C_α, C_β, and C_γ, which have different reaction activities. During the reaction, the amount of C_α decreased but C_β and C_γ increased. In addition, C_γ could be changed into inactive graphite carbon. The activation of CH₄ and CO₂ was mutually promoted in the reforming reaction. It was revealed that the controlling step for biogas reforming over the Ni-Co/La₂O₃-γ-Al₂O₃ catalyst could be the reaction of the surface species of O with C to form CO or with CH_x to give CH_xO followed by the formation of CO and adsorbed H.
- Nickel,
- Cobalt,
- Bimetallic catalyst,
- Biogas reforming,
- Hydrogen production,
- Mechanism
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