Citation: JIANG Jin-Qiang, QIANG Jing, NI Zhong-Bin, SONG Xiao-Qing, ZHANG Hong-Wu, LIU Xiao-Ya, CHEN Ming-Qing. Synthesis and Solution Properties of the Photo-Sensitive Telechelic Polymer——Coumarin-Containing Poly(4-vinylpyridine)[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 664-670. doi: 10.3866/PKU.WHXB20110238 shu

Synthesis and Solution Properties of the Photo-Sensitive Telechelic Polymer——Coumarin-Containing Poly(4-vinylpyridine)

1.
School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 6 September 2010
Available Online: 13 January 2011
Fund Project: 国家自然科学基金(20704017, 50973044) (20704017, 50973044) 江苏青蓝工程和中央高校基本科研业务费专项资金(JUSRP31003)资助项目 (JUSRP31003)

A novel photo-sensitive telechelic polymer——coumarin-containing poly(4-vinylpyridine) (C- P4VP) was prepared using 4-vinylpyridine as a monomer, azodiiso-butyronile (AIBN) as an initiator, and coumarin-containing disulfides (C-S-S-C) as a chain transfer agent in the presence of tributylphosphine (Bu₃P)/H₂O. The polymer was characterized by Fourier transform infrared (FTIR) spectroscopy, ¹H nuclear magnetic resonance (¹H-NMR), and gel permeation chromatography (GPC). We found that the telechelic polymer can form polymer micelles in aqueous solutions at various pH values (pH=3-6). Additionally, when lowering the acidity of the aqueous solution, the polymer micelles gradually compacted and the degree of coumarin photo-dimerization decreased initially and then increased within a similar irradiation time.
- Micelle,
- Poly(4-vinylpyridine),
- Tributylphosphine,
- Coumarin,
- Photo-dimerization
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