Citation: LIU Jia, YANG Hao-Tian, ZHANG Jing-Bo, ZHOU Xiao-Wen, LIN Yuan. Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 408-412. doi: 10.3866/PKU.WHXB20110237 shu

Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells

LIU Jia ^1,2 ,
YANG Hao-Tian ^1,2 ,
ZHANG Jing-Bo ¹ ,
ZHOU Xiao-Wen ¹ ,
LIN Yuan ^1,

1.
1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 15 October 2010
Available Online: 12 January 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2006CB202605) (973) (2006CB202605) 国家高技术研究发展规划(863)(2007AA05Z439) (863)(2007AA05Z439)国家自然科学基金(20973183)资助 (20973183)

We prepared rutile TiO₂ powders of od crystallinity by hydrolyzing a Ti(OC4H9)4 precursor at room temperature and by reprecipitation. X-ray diffraction (XRD) revealed that higher acidity, lower temperature, and specific amounts of Cl^- as a medium result in rutile TiO₂. This rutile TiO₂ has an irregular rice-like structure. After adding the P105 (EO₃₇PO₅₆EO₃₇) tri-block copolymer as a structural agent, the rutile TiO₂ aggregated to form rough 350 nm spheres. These rough spheres have a greatly enhanced light harvesting efficiency and improved energy conversion efficiency in dye-sensitized solar cells. This is due to their high light scattering effect and larger surface area (109.5 m²·g^-1). By adding these large rutile spheres at a mass fraction of 25% to the over-layer of a TiO₂ film composed of ~20 nm TiO₂ particles as light scattering centers, the energy conversion efficiency of the dye-sensitized solar cells (DSSC) was 7.27%. This is a 17% increase in conversation efficiency compared with the DSSC based on a TiO₂ photoanode without these rough rutile spheres.
- Dye-sensitized solar cell,
- TiO₂,
- Rutile,
- Scattering layer
1. [1]
  
  (1) Carp, O.; Huisman, C. L.; Reller, A. Prog. Solid State Chem. 2004, 32, 33.
2. [2]
  (2) Linsebigler, A. L.; Lu, G. Q.; Yates, J. T. Chem. Rev. 1995, 95, 735.
3. [3]
  (3) Diebold, U. Surf. Sci. Rep. 2003, 48, 53.
4. [4]
  (4) Cao, Y. Q.; Long, H. J.; Chen, Y. M.; Cao, Y. Acta Phys. -Chim. Sin. 2009, 25, 1088.
5. [5]
  [曹永强, 龙绘锦, 陈咏梅, 曹亚安. 物理化学学报, 2009, 25, 1088.]
6. [6]
  (5) Gribb, A. A.; Banfield, J. F. Am. Mineral. 1997, 82, 717.
7. [7]
  (6) Park, N. G.; van de Lagemaat, J. J. Phys. Chem. B 2000, 104, 8989.
8. [8]
  (7) Eiji, H.; Shinobu, F.; Keita, K.; Hiroaki, I. J. Am. Chem. Soc. 2004, 126, 7790.
9. [9]
  (8) Terabe, K.; Kato, K.; Miyazaki, H.; Yamaguchi, S.; Imai, A.; Iguchi, Y. J. Mater. Sci. 1994, 29, 1617.
10. [10]
  (9) Slunecko, J.; Kosec, M.; Holc, J.; Drazic, G. J. J. Am. Ceram. Soc. 1998, 81, 1121.
11. [11]
  (10) Zhao, W. K.; Fang, Y. L.; Dong, Q. H. Acta Phys. -Chim. Sin. 1998, 14, 424.
12. [12]
  [赵文宽, 方佑龄, 董庆华. 物理化学学报, 1998, 14, 424.]
13. [13]
  (11) Yin, S.; Hasegawa, H.; Sato, T. Chem. Lett. 2002, 15, 564.
14. [14]
  (12) Wang, C. C.; Ying, J. Y. Chem. Mater. 1999, 11, 3113.
15. [15]
  (13) Fang, J. X.; Ding, B. J.; Yang, Z. M. Solid State Phenom. 2007, 121-123, 311.
16. [16]
  (14) Bao, X. W.; Zhang, J. L.; Liang, X. H.; Huang, J. Z., Zhang, L. Z. Acta Phys. -Chim. Sin. 2005, 21, 69.
17. [17]
  [鲍兴旺, 张金龙, 梁学海, 黄家祯, 张利中. 物理化学学报, 2005, 21, 69.]
18. [18]
  (15) Zhao, W. K.; Fang, Y. L. Acta Phys. -Chim. Sin. 2002, 18, 368.
19. [19]
  [赵文宽, 方佑龄. 物理化学学报, 2002, 18, 368.]
20. [20]
  (16) Wu, L. Z.; Zhi, J. F. Acta Phys. -Chim. Sin. 2007, 23, 1173.
21. [21]
  [吴良专, 只金芳. 物理化学学报, 2007, 23, 1173.]
22. [22]
  (17) Sarmimala, H.; Carmen, V.; Rainer, K.; Herman, S.; Andreas, H. Solar Energy Materials & Solar Cells 2006, 90, 1176.
23. [23]
  (18) Liu, J.; Yang, H. T.; Tan, W. W.; Zhou, X. W.; Lin, Y. Electrochim. Acta 2010, 56, 396.
24. [24]
  (19) Zhou, Y. F.; Xiang, W. C.; Chen, S.; Fang, S. B.; Zhou, X. W.; Zhang, J. B.; Lin, Y. Chem. Commun. 2009, No. 26, 3895.
25. [25]
  (20) Xiang, W. C.; Zhou, Y. F.; Yin, X.; Zhou, X. W.; Fang, S. B.; Lin, Y. Electrochim. Acta 2009, 54, 4186.
26. [26]
  (21) Wu, M. M.; Lin, G.; Chen, D. H.; Wang, G. G.; He, D.; Feng, S. H.; Xu, R. R. Chem. Mater. 2002, 14, 1974.
27. [27]
  (22) Cheng, H.; Ma, J.; Zhao, Z.; Qi, L. Chem. Mater. 1995, 7, 663.
28. [28]
  (23) Yin, S.; Hasegawa, H.; Maeda, D.; Ishitsuka, M.; Sato, T. J. Photochem. Photobio. A: Chem. 2004, 163, 1.
29. [29]
  (24) Li, G.; Gray, K. A. Chem. Mater. 2007, 19, 1143.
30. [30]
  (25) Yang, L.; Lin, Y.; Jia, J. J. Power. Sources 2008, 182, 370.
31. [31]
  (26) Soler-Illia, G. J. D. A.; Crepaldi, E. L.; Grosso, D.; Sanchez, C. Curr. Opin. Colloid Interface Sci. 2003, 8, 109.
1. [1]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
2. [2]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
5. [5]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
6. [6]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
11. [11]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
12. [12]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
13. [13]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
14. [14]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
15. [15]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
16. [16]
  Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
17. [17]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
18. [18]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
19. [19]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
20. [20]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

Get Citation

PDF

XML

Metrics

PDF Downloads(2193)
Abstract views(2725)
HTML views(44)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Room Temperature Synthesis of Rutile TiO2 and Its Application in Dye-Sensitized Solar Cells

Metrics

通讯作者: 陈斌, bchen63@163.com

Room Temperature Synthesis of Rutile TiO₂ and Its Application in Dye-Sensitized Solar Cells