Citation: SUN Lei, LIU Ai-Xin, HUANG Hong-Ying, TAO Xiao-Jun, ZHAO Yan-Bao, ZHANG Zhi-Jun. Preparation and Antibacterial Properties of Water-Soluble Ag Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 722-728. doi: 10.3866/PKU.WHXB20110235
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Water-soluble surface modified silver nanoparticles were synthesized by liquid phase reduction with tannic acid as the reductant and polyvinyl pyrrolidone (PVP) as the surface modification agent. The structure and morphology of the as-synthesized powders were investigated by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), ultraviolet-visible (UV-Vis) absorption spectroscopy, and Fourier-transform infrared (FTIR) spectrometry. The antibacterial activity of the water- soluble Ag nanoparticles against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) was investigated by broth dilution. The stable dispersion duration of the as-synthesized Ag nanoparticles in water was also determined. A mechanism for PVP modified Ag nanoparticle formation is proposed. The results show that the as-synthesized PVP modified Ag nanoparticles have a face-centered cubic crystalline structure. The average diameter of the Ag nanoparticles ranges from 15 to 17 nm. The as- synthesized powders have od solubility in water over a long period of time. PVP modified Ag nanoparticles exhibit od antibacterial properties against E. coli and S. aureus. This simple and mild preparation method can be easily increased to an industrial scale process and, therefore, PVP modified Ag nanoparticles are potentially a new type of antibacterial.
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