Citation: GAO Rui, MA Bei-Bei, WANG Li-Duo, SHI Yan-Tao, DONG Hao-Peng, QIU Yong. Photovoltaic Properties and Mechanism Analysis of a Dye/Al2O3 Alternating Assembly Structure by Electrochemical Impedance Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 413-418. doi: 10.3866/PKU.WHXB20110234 shu

Photovoltaic Properties and Mechanism Analysis of a Dye/Al2O3 Alternating Assembly Structure by Electrochemical Impedance Spectroscopy

  • Received Date: 12 October 2010
    Available Online: 10 January 2011

    Fund Project: 国家自然科学基金(50873055) (50873055)国家重点基础研究发展规划项目(973) (2009CB930602)资助 (973) (2009CB930602)

  • N3 dye and Al2O3 were used to form an alternating assembly structure. The current density-voltage (J-V) characterization showed that this structure improved the performance of dye- sensitized solar cells (DSCs). Electrochemical impedance spectroscopy (EIS) was used to study the internal resistance of this alternating assembly structured DSCs. The results showed that the resistance at the sensitized TiO2/electrolyte interface decreased as the number of (dye/Al2O3) units increased, and the device's conversion efficiency improved significantly. Based on the EIS results, a series of equivalent circuit models were well established to investigate the dye/Al2O3 alternating assembly structure theoretically.

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