Citation: GAO Rui, MA Bei-Bei, WANG Li-Duo, SHI Yan-Tao, DONG Hao-Peng, QIU Yong. Photovoltaic Properties and Mechanism Analysis of a Dye/Al₂O₃ Alternating Assembly Structure by Electrochemical Impedance Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 413-418. doi: 10.3866/PKU.WHXB20110234 shu

Photovoltaic Properties and Mechanism Analysis of a Dye/Al₂O₃ Alternating Assembly Structure by Electrochemical Impedance Spectroscopy

1.
Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received Date: 12 October 2010
Available Online: 10 January 2011
Fund Project: 国家自然科学基金(50873055) (50873055)国家重点基础研究发展规划项目(973) (2009CB930602)资助 (973) (2009CB930602)

N3 dye and Al₂O₃ were used to form an alternating assembly structure. The current density-voltage (J-V) characterization showed that this structure improved the performance of dye- sensitized solar cells (DSCs). Electrochemical impedance spectroscopy (EIS) was used to study the internal resistance of this alternating assembly structured DSCs. The results showed that the resistance at the sensitized TiO₂/electrolyte interface decreased as the number of (dye/Al₂O₃) units increased, and the device's conversion efficiency improved significantly. Based on the EIS results, a series of equivalent circuit models were well established to investigate the dye/Al₂O₃ alternating assembly structure theoretically.
- Dye-sensitized solar cell,
- Alternating assembly structure,
- Equivalent circuit model
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沈阳化工大学材料科学与工程学院沈阳 110142

Photovoltaic Properties and Mechanism Analysis of a Dye/Al2O3 Alternating Assembly Structure by Electrochemical Impedance Spectroscopy

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通讯作者: 陈斌, bchen63@163.com

Photovoltaic Properties and Mechanism Analysis of a Dye/Al₂O₃ Alternating Assembly Structure by Electrochemical Impedance Spectroscopy