Citation: ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun. Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 455-460. doi: 10.3866/PKU.WHXB20110228 shu

Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior

1.
1. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China;
2. Institute of Chemical Industry of Forest Products, Nanjing 210042, P. R. China

Received Date: 20 September 2010
Available Online: 5 January 2011
Fund Project: 国家重点基础研究发展计划(973) (2007CB209703) (973) (2007CB209703)江苏省生物质能源与材料重点实验室(2010M001)资助项目 (2010M001)

Porous carbons were prepared by the carbonization of water soluble chitosan and they were then used to synthesize porous C/NiO composites. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and nitrogen adsorption-desorption experinents were used to characterize the structure and morphology of the products. The results showed that the mesopore-rich composites consisted of NiO crystallites and porous carbon. The electrochemical properties of the porous C/NiO composites were studied by cyclic voltammetry (CV) and galvanostatic charge/discharge measurements. We found that compared with porous carbon, the composites showed superior electrochemical capacitive performance. When the mass ratio of nickel to carbon was 2:20, the composite had a large specific capacitance of 355 F·g^-1 at a current density of 0.1 A·g^-1 and excellent cyclability with a capacity retention of about 99% after 1500 cycles.
- Supercapacitor,
- Chitosan,
- Porous carbon,
- Nickel oxide
1. [1]
  
  (1) Du Pasquier, A.; Plitz, I.; Gural, J.; Badway, F.; Amatucci, G. G. J. Power Sources 2004, 136, 160.
2. [2]
  (2) Cuentas-Galle s, A. K.; Lira-Cantu, M.; Casan-Pastor, N.; mez-Romero, P. Adv. Funct. Mater. 2005, 15, 1125.
3. [3]
  (3) Frackowiak, E. Phys. Chem. Chem. Phys. 2007, 9, 1774.
4. [4]
  (4) Frackowiak, E.; Beguin, F. Carbon 2001, 39, 937.
5. [5]
  (5) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157, 11.
6. [6]
  (6) Liang, C. D.; Li, Z. J.; Dai, S. Angew. Chem. Int. Edit. 2008, 47, 2. (7) Huwe, H.; Froba, M. Carbon 2007, 45, 304.
7. [7]
  (8) Li, H. F.; Zhu, S. M.; Wang, R. D. Microporous Mesoporous Mat. 2006, 89, 196.
8. [8]
  (9) Yao, W. L.; Wang, J. L.; Yang, J.; Du, G. D. J. Power Sources 2008, 176, 369.
9. [9]
  (10) Zhang, L. L.; Zhao, X. S. Chem. Soc. Rev. 2009, 38, 2520.
10. [10]
  (11) Wang, T.; He, J. P.; Zhang, C. X.; Zhou, J. H.; Guo, Y. X.; Chen, X.; Di, Z. Y.; Sun, D.; Wang, D. J. Acta Phys. -Chim. Sin. 2008, 24, 2314.
11. [11]
  [王涛, 何建平, 张传香, 周建华, 郭云霞, 陈秀, 狄志勇, 孙盾, 王道军. 物理化学学报, 2008, 24, 2314.]
12. [12]
  (12) Zheng, Y. Z.; Zhang, M. L. Mater. Lett. 2007, 61, 3967.
13. [13]
  (13) Xing, W.; Li, F.; Yan, Z. F.; Lu, G. Q. J. Power Sources 2004, 134, 324.
14. [14]
  (14) Yu, C.; Zhang, L.; Shi, J.; Zhao, J.; Gao, J.; Yan, D. Adv. Funct. Mater. 2008, 18, 1544.
15. [15]
  (15) Zheng, Y. Z.; Ding, H. Y.; Zhang, M. L. Mater. Res. Bull. 2009, 44, 403.
16. [16]
  (16) White, R. J.; Antonietti, M.; Titirici, M. M. J. Mater. Chem. 2009, 19, 8645.
17. [17]
  (17) Liu, H. J.; Wang, X. M.; Cui, W. J.; Dou, Y. Q.; Zhao, D. Y.; Xia, Y. Y. J. Mater. Chem. 2010, 20, 4223.
18. [18]
  (18) Raymundo-pinero, E.; Cadek, M.; Beguin, F. Adv. Funct. Mater. 2009, 19, 1.
19. [19]
  (19) Wang, Y. G.; Xia, Y. Y. Electrochim. Acta 2006, 51, 3223.
20. [20]
  (20) Yuan, C. Z.; Xiong, S. L.; Zhang, X. G.; Shen, L. F.; Zhang, F.; Gao, B.; Su, L. H. Nano Res. 2009, 2, 722.
21. [21]
  (21) Chmiola, J.; Yushin, G.; tsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Science 2006, 313, 1760.
22. [22]
  (22) Levie, D. R. Electrochim. Acta. 1963, 8, 751.
23. [23]
  (23) Austin, L. G.; Gagnon, E. G. J. Electrochem. Soc. 1973, 120, 251.
24. [24]
  (24) Yuan, C. Z.; Zhang, X. G.; Su, L. H.; Gao, B.; Shen, L. F. J. Mater. Chem. 2009, 19, 5772.
25. [25]
  (25) Duan, H.; Liu, K. Y.; Zhang, Y.; Zheng, H.; Li, A. S. Chin. J. Inorg. Chem. 2009, 25, 243.
26. [26]
  [段浩, 刘开宇, 张莹, 郑禾, 李傲生. 无机化学学报, 2009, 25, 243.]
27. [27]
  (26) Justin, P.; Meher, S. K.; Rao, G. R. J. Phys. Chem. C 2010, 114, 5203.
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沈阳化工大学材料科学与工程学院沈阳 110142