Citation: ZHANG Qiu-Mei, SHI Zhi-Cong, LI Yi-Xiao, GAO Dan, CHEN Guo-Hua, YANG Yong. Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(02): 267-274. doi: 10.3866/PKU.WHXB20110217 shu

Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries

ZHANG Qiu-Mei ¹ ,
SHI Zhi-Cong ^1,2, ,
LI Yi-Xiao ³ ,
GAO Dan ¹ ,
CHEN Guo-Hua ² ,
YANG Yong ^3,

1.
1. State Key Laboratory for Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning Province, P. R. China;
2. Center for Green Products and Process Technologies, Guangzhou HKUST Fok Ying Tung Research Institute, Guangzhou 511458, P. R. China;
3. State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 29 July 2010
Available Online: 29 December 2010
Fund Project: 高等学校博士学科点专项科研基金(20090041120020) (20090041120020)中央高校基本科研业务费专项资金(DUT10JN06)资助项目 (DUT10JN06)

We review recent research on fluorophosphate and orthosilicate cathode materials for lithium ion batteries. Emphasis is placed on the relationship between structures, methods of preparation and properties of the cathode materials. We especially focus on factors leading to an improvement in their electrochemical performance. Trends of research into fluorophosphate and orthosilicate cathode materials are also discussed.
- Lithium ion battery,
- Cathode material,
- Fluorophosphate,
- Orthosilicate
1. [1]
  
  (1) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359.
2. [2]
  (2) Nanjundaswamy, K. S.; Padhi, A. K.; odenough, J. B.; Okada, S.; Ohtsuka, H.; Arai, H.; Yamaki, J. Solid State Ionics 1996, 92, 1.
3. [3]
  (3) Padhi, A. K.; Nanjundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188.
4. [4]
  (4) Padhi, A. K.; Nanjundaswamy, K. S.; Masquelier, C.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 2581.
5. [5]
  (5) Shi, Z. C.; Yang, Y. Progress in Chemistry 2005, 17, 604.
6. [6]
  [施志聪, 杨勇. 化学进展, 2005, 17, 604.]
7. [7]
  (6) Okada, S.; Sawa, S.; Egashira, M.; Yamaki, J.; Tabuchi, M.; Kageyama, H.; Konishi, T.; Yoshino, A. J. Power Sources 2001, 97/98, 430.
8. [8]
  (7) Masao, Y.; Atsuo, Y.; Yuki, T. J. Electrochem. Soc. 2004, 151, A1352.
9. [9]
  (8) Barker, J.; Saidi, M. Y.; Swoyer, J. Lithium metal fluorophosphate materials and preparation thereoy: US Patent, 6387568, 2002-05-14.
10. [10]
  (9) Makimura, Y.; Cahill, L. S.; Iriyama, Y.; ward, G. R.; Nazar, L. F. Chem. Mater. 2008, 20, 4240.
11. [11]
  (10) Barker, J.; Cover, R. K. B.; Burns, P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2005, 152, A1776.
12. [12]
  (11) Ramesh, T. N.; Lee, K. T.; Ellis, B. L.; Nazar, L. F. Electrochem. Solid-State Lett. 2010, 13, A43.
13. [13]
  (12) Recham, N.; Chotard, J. N.; Jumas, J. C.; Laffont, L.; Armand, M.; Tarascon, J. M. Chem. Mater. 2010, 22, 1142.
14. [14]
  (13) Ellis, B. L.; Makahnouk,W. R. M.; Makimura, Y.; Toghill, K.; Nazar, L. F. Nat. Mater. 2007, 10, 749.
15. [15]
  (14) Barker, J.; Cover, R. K. B.; Burns ,P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Power Sources 2005, 146, 516.
16. [16]
  (15) Beitone, L.; Guillou, N.; Millange, F.; Loiseau, T.; Férey, G. Solid State Sci. 2002, 4, 1061.
17. [17]
  (16) Yang, G.; Ying, J. R.; Gao, J.; Jiang, C. Y.;Wan, C. R. Rare Metal Materials and Engineering 2008, 37, 936.
18. [18]
  [杨改, 应皆荣, 高剑, 姜长印, 万春荣. 稀有金属材料与工程. 2008, 37, 936.]
19. [19]
  (17) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2003, 150, A1394.
20. [20]
  (18) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2004, 151, A1670.
21. [21]
  (19) Koksbang, R.; Barker, J.; Shi, H.; Saidi, M. Y. Solid State Ionics 1996, 84, 1.
22. [22]
  (20) Barker, J.; Saidi, M. Y.; ver, R. K. B.; Burns, P.; Bryan, A. J. Power Sources 2007, 174, 927.
23. [23]
  (21) Li, Y. Z.; Zhou, X.; Ren, J. X.; Gao, X. P.; Yan, J. Chinese Journal of Inorganic Chemistry 2006, 22, 477.
24. [24]
  [李宇展, 周霞, 任俊霞, 高学平, 闫杰. 无机化学学报, 2006, 22, 477.]
25. [25]
  (22) Zhong, S. K.; Yin, Z. L.;Wang, Z. X.; Chen, Q. Y. Chinese Journal of Applied Chemistry 2007, 24, 278.
26. [26]
  [钟胜奎, 尹周澜, 王志兴, 陈启元. 应用化学, 2007, 24, 278.]
27. [27]
  (23) Yin, S. C.; Herle, P. S.; Higgins, A.; Taylor, N. J.; Makimura, Y.; Nazar, L. F. Chem. Mater. 2006, 18, 1745.
28. [28]
  (24) Yin, S. C.; Grondey, H.; Strobel, P.; Huang, H.; Nazar, L. F. J. Am. Chem. Soc., 2003, 125, 326.
29. [29]
  (25) Poojary, D. M.; Clearfield, A.; Timofeeva, V. A.; Sigaryov, S. E. Solid State Ionics 1994, 73, 75.
30. [30]
  (26) Wu, S. Q.; Zhu, Z. Z.; Yang, Y.; Hou, Z. F. Comput. Mater. Sci. 2009, 44, 1243.
31. [31]
  (27) Armand, M. Lithium Insertion Electrode Materials Based on Orthosilicate Derivatives. US Patent 6085015, 2000-07-04.
32. [32]
  (28) Nytén, A.; Abouimrane, A.; Armand, M.; Gustafsson, T.; Thomas, J. O. Electrochem. Commun. 2005, 7, 156.
33. [33]
  (29) Nytén, A.; Stjerndahl, M.; Rensmo, H.; Siegbahn, H.; Armand, M.; Gustafsson, T.; Edström, K.; Thomas, J. O. J. Mater. Chem. 2006, 16, 3483.
34. [34]
  (30) Nytén, A.; Kamali, S.; Nytén, L.; Gustafsson, T.; Thomas, J. O. J. Mater. Chem. 2006, 16, 2266.
35. [35]
  (31) Larsson, P.; Ahuja, R.; Nytén, A.; Thomas, J. O. Electrochem. Commun. 2006, 8, 797.
36. [36]
  (32) Dominko, R.; Conte, D. E.; Hanzel, D.; Gaberscek, M.; Jamnik, J. J. Power Sources 2008, 178, 842.
37. [37]
  (33) ng, Z. L.; Li, Y. X.; He, G. N.; Li, J.; Yang, Y. Electrochem. Solid State Lett. 2008, 11, A60.
38. [38]
  (34) Zuo, P. J.;Wang, Z. B.; Yin, G. P.; Cheng, X. Q.; Du, C. Y.; Xu, Y. H.; Shi, P. F. Materials Review 2009, 23, 28.
39. [39]
  [左朋建, 王振波, 尹鸽平, 程新群, 杜春雨, 徐宇虹, 史鹏飞. 材料导报, 2009, 23, 28.]
40. [40]
  (35) Dominko, R.; Bele, M.; Gaberscek, M.; Meden, A.; Remskar, M.; Jamnik, J. Electrochem. Commun. 2006, 8, 217.
41. [41]
  (36) Kokalj, A.; Dominko, R.; Mali, G.; Meden, A.; Gaberscek, M.; Jamnik, J. Chem. Mater. 2007, 19, 3633.
42. [42]
  (37) ng, Z. L. Study of Polyanion Orthosilicates as Cathode Materials for Lithium Ion Batteries. Ph.D. Dissertation, Xiamen University, Xiamen, 2007.
43. [43]
  [龚正良. 聚阴离子型硅酸盐锂离子电池正极材料研究(D). 厦门: 厦门大学, 2007.]
44. [44]
  (38) Chung, S. Y.; Bloking, J. T.; Chiang, Y. M. Nat. Mater. 2002, 1, 123.
45. [45]
  (39) Moskon, J.; Dominko, R.; Gaberscek, M.; Cerc-Korosec, R.; Jamnik, J. J. Power Sources 2007, 174, 683.
46. [46]
  (40) Li,Y. X.; ng, Z. L.; Yang, Y. J. Power Sources 2007, 174, 528.
47. [47]
  (41) Yang, Y.; Fang, H. S.; Li, L. P.; Yan, G. F.; Li, G. S. Rare Metal Materials and Engineering 2008, 37, 1085.
48. [48]
  [杨勇, 方海升, 李莉萍, 闫国丰, 李广社. 稀有金属材料与工程, 2008, 37, 1085.]
49. [49]
  (42) Yang, Y.; Li, Y. X.; ng, Z. L. Synthesis of Li₂Mn_xFe_1-xSiO₄/C Composite Material as Cathode Materials for Rechargeable Lithium Batteries: CN Patent CN1803608, 2006-07-19.
50. [50]
  [杨勇, 李益孝, 龚正良. 可充锂电池用硅酸锰铁锂/碳复合正极材料及其制备方法: 中国, CN1803608(P). 2006-07-19.]
51. [51]
  (43) ng, Z. L.; Li, Y. X.; Yang, Y. Electrochem. Solid State Lett. 2006, 9, A542.
52. [52]
  (44) ng, Z. L.; Li, Y. X.; Yang, Y. J. Power Sources 2007, l74, 524.
53. [53]
  (45) West, A. R.; Glasser, F. P. J. Solid State Chem. 1972, 4, 20
54. [54]
  (46) Wu, S. Q.; Zhang, J. H.; Zhu, Z. Z.; Yang, Y. Curr. Appl. Phys. 2007, 7, 611.
55. [55]
  (47) Wu, S. Q.; Zhu, Z. Z.; Yang, Y.; Hou, Z. F. Trans. Nonferrous. Met. Soc. China 2009, 19, 182.
56. [56]
  (48) Dompablo, M. E. A.; Armand, M.; Tarascon, J. M.; Amador, U. Electrochem. Commun. 2006, 8, 1292.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
8. [8]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
12. [12]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
13. [13]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
14. [14]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
15. [15]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
16. [16]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
17. [17]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
18. [18]
  Zhongbin Pan , Shijie Huang , Yunjie Luo , Hongzhen Xie . Design of a Comprehensive Experiment for Determining Permanganate Index (COD_Mn) in Drinking Water. University Chemistry, 2024, 39(7): 354-360. doi: 10.12461/PKU.DXHX202311040
19. [19]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
20. [20]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100

Get Citation

PDF

XML

Metrics

PDF Downloads(2771)
Abstract views(4105)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142