Citation:
ZHANG Qiu-Mei, SHI Zhi-Cong, LI Yi-Xiao, GAO Dan, CHEN Guo-Hua, YANG Yong. Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica,
;2011, 27(02): 267-274.
doi:
10.3866/PKU.WHXB20110217
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We review recent research on fluorophosphate and orthosilicate cathode materials for lithium ion batteries. Emphasis is placed on the relationship between structures, methods of preparation and properties of the cathode materials. We especially focus on factors leading to an improvement in their electrochemical performance. Trends of research into fluorophosphate and orthosilicate cathode materials are also discussed.
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Keywords:
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Lithium ion battery
, - Cathode material,
- Fluorophosphate,
- Orthosilicate
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[1]
(1) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359.
-
[2]
(2) Nanjundaswamy, K. S.; Padhi, A. K.; odenough, J. B.; Okada, S.; Ohtsuka, H.; Arai, H.; Yamaki, J. Solid State Ionics 1996, 92, 1.
-
[3]
(3) Padhi, A. K.; Nanjundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188.
-
[4]
(4) Padhi, A. K.; Nanjundaswamy, K. S.; Masquelier, C.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 2581.
-
[5]
(5) Shi, Z. C.; Yang, Y. Progress in Chemistry 2005, 17, 604.
-
[6]
[施志聪, 杨勇. 化学进展, 2005, 17, 604.]
-
[7]
(6) Okada, S.; Sawa, S.; Egashira, M.; Yamaki, J.; Tabuchi, M.; Kageyama, H.; Konishi, T.; Yoshino, A. J. Power Sources 2001, 97/98, 430.
-
[8]
(7) Masao, Y.; Atsuo, Y.; Yuki, T. J. Electrochem. Soc. 2004, 151, A1352.
-
[9]
(8) Barker, J.; Saidi, M. Y.; Swoyer, J. Lithium metal fluorophosphate materials and preparation thereoy: US Patent, 6387568, 2002-05-14.
-
[10]
(9) Makimura, Y.; Cahill, L. S.; Iriyama, Y.; ward, G. R.; Nazar, L. F. Chem. Mater. 2008, 20, 4240.
-
[11]
(10) Barker, J.; Cover, R. K. B.; Burns, P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2005, 152, A1776.
-
[12]
(11) Ramesh, T. N.; Lee, K. T.; Ellis, B. L.; Nazar, L. F. Electrochem. Solid-State Lett. 2010, 13, A43.
-
[13]
(12) Recham, N.; Chotard, J. N.; Jumas, J. C.; Laffont, L.; Armand, M.; Tarascon, J. M. Chem. Mater. 2010, 22, 1142.
-
[14]
(13) Ellis, B. L.; Makahnouk,W. R. M.; Makimura, Y.; Toghill, K.; Nazar, L. F. Nat. Mater. 2007, 10, 749.
-
[15]
(14) Barker, J.; Cover, R. K. B.; Burns ,P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Power Sources 2005, 146, 516.
-
[16]
(15) Beitone, L.; Guillou, N.; Millange, F.; Loiseau, T.; Férey, G. Solid State Sci. 2002, 4, 1061.
-
[17]
(16) Yang, G.; Ying, J. R.; Gao, J.; Jiang, C. Y.;Wan, C. R. Rare Metal Materials and Engineering 2008, 37, 936.
-
[18]
[杨改, 应 皆荣, 高剑, 姜长印, 万春荣. 稀有金属材料与工程. 2008, 37, 936.]
-
[19]
(17) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2003, 150, A1394.
-
[20]
(18) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2004, 151, A1670.
-
[21]
(19) Koksbang, R.; Barker, J.; Shi, H.; Saidi, M. Y. Solid State Ionics 1996, 84, 1.
-
[22]
(20) Barker, J.; Saidi, M. Y.; ver, R. K. B.; Burns, P.; Bryan, A. J. Power Sources 2007, 174, 927.
-
[23]
(21) Li, Y. Z.; Zhou, X.; Ren, J. X.; Gao, X. P.; Yan, J. Chinese Journal of Inorganic Chemistry 2006, 22, 477.
-
[24]
[李宇展, 周霞, 任俊霞, 高学平, 闫杰. 无机化学学报, 2006, 22, 477.]
-
[25]
(22) Zhong, S. K.; Yin, Z. L.;Wang, Z. X.; Chen, Q. Y. Chinese Journal of Applied Chemistry 2007, 24, 278.
-
[26]
[钟胜奎, 尹周 澜, 王志兴, 陈启元. 应用化学, 2007, 24, 278.]
-
[27]
(23) Yin, S. C.; Herle, P. S.; Higgins, A.; Taylor, N. J.; Makimura, Y.; Nazar, L. F. Chem. Mater. 2006, 18, 1745.
-
[28]
(24) Yin, S. C.; Grondey, H.; Strobel, P.; Huang, H.; Nazar, L. F. J. Am. Chem. Soc., 2003, 125, 326.
-
[29]
(25) Poojary, D. M.; Clearfield, A.; Timofeeva, V. A.; Sigaryov, S. E. Solid State Ionics 1994, 73, 75.
-
[30]
(26) Wu, S. Q.; Zhu, Z. Z.; Yang, Y.; Hou, Z. F. Comput. Mater. Sci. 2009, 44, 1243.
-
[31]
(27) Armand, M. Lithium Insertion Electrode Materials Based on Orthosilicate Derivatives. US Patent 6085015, 2000-07-04.
-
[32]
(28) Nytén, A.; Abouimrane, A.; Armand, M.; Gustafsson, T.; Thomas, J. O. Electrochem. Commun. 2005, 7, 156.
-
[33]
(29) Nytén, A.; Stjerndahl, M.; Rensmo, H.; Siegbahn, H.; Armand, M.; Gustafsson, T.; Edström, K.; Thomas, J. O. J. Mater. Chem. 2006, 16, 3483.
-
[34]
(30) Nytén, A.; Kamali, S.; Nytén, L.; Gustafsson, T.; Thomas, J. O. J. Mater. Chem. 2006, 16, 2266.
-
[35]
(31) Larsson, P.; Ahuja, R.; Nytén, A.; Thomas, J. O. Electrochem. Commun. 2006, 8, 797.
-
[36]
(32) Dominko, R.; Conte, D. E.; Hanzel, D.; Gaberscek, M.; Jamnik, J. J. Power Sources 2008, 178, 842.
-
[37]
(33) ng, Z. L.; Li, Y. X.; He, G. N.; Li, J.; Yang, Y. Electrochem. Solid State Lett. 2008, 11, A60.
-
[38]
(34) Zuo, P. J.;Wang, Z. B.; Yin, G. P.; Cheng, X. Q.; Du, C. Y.; Xu, Y. H.; Shi, P. F. Materials Review 2009, 23, 28.
-
[39]
[左朋建, 王振 波, 尹鸽平, 程新群, 杜春雨, 徐宇虹, 史鹏飞. 材料导报, 2009, 23, 28.]
-
[40]
(35) Dominko, R.; Bele, M.; Gaberscek, M.; Meden, A.; Remskar, M.; Jamnik, J. Electrochem. Commun. 2006, 8, 217.
-
[41]
(36) Kokalj, A.; Dominko, R.; Mali, G.; Meden, A.; Gaberscek, M.; Jamnik, J. Chem. Mater. 2007, 19, 3633.
-
[42]
(37) ng, Z. L. Study of Polyanion Orthosilicates as Cathode Materials for Lithium Ion Batteries. Ph.D. Dissertation, Xiamen University, Xiamen, 2007.
-
[43]
[龚正良. 聚阴离子型硅酸盐锂离 子电池正极材料研究(D). 厦门: 厦门大学, 2007.]
-
[44]
(38) Chung, S. Y.; Bloking, J. T.; Chiang, Y. M. Nat. Mater. 2002, 1, 123.
-
[45]
(39) Moskon, J.; Dominko, R.; Gaberscek, M.; Cerc-Korosec, R.; Jamnik, J. J. Power Sources 2007, 174, 683.
-
[46]
(40) Li,Y. X.; ng, Z. L.; Yang, Y. J. Power Sources 2007, 174, 528.
-
[47]
(41) Yang, Y.; Fang, H. S.; Li, L. P.; Yan, G. F.; Li, G. S. Rare Metal Materials and Engineering 2008, 37, 1085.
-
[48]
[杨勇, 方海升, 李 莉萍, 闫国丰, 李广社. 稀有金属材料与工程, 2008, 37, 1085.]
-
[49]
(42) Yang, Y.; Li, Y. X.; ng, Z. L. Synthesis of Li2MnxFe1-xSiO4/C Composite Material as Cathode Materials for Rechargeable Lithium Batteries: CN Patent CN1803608, 2006-07-19.
-
[50]
[杨勇, 李益孝, 龚正良. 可充锂电池用硅酸锰铁锂/碳复合正极材料 及其制备方法: 中国, CN1803608(P). 2006-07-19.]
-
[51]
(43) ng, Z. L.; Li, Y. X.; Yang, Y. Electrochem. Solid State Lett. 2006, 9, A542.
-
[52]
(44) ng, Z. L.; Li, Y. X.; Yang, Y. J. Power Sources 2007, l74, 524.
-
[53]
(45) West, A. R.; Glasser, F. P. J. Solid State Chem. 1972, 4, 20
-
[54]
(46) Wu, S. Q.; Zhang, J. H.; Zhu, Z. Z.; Yang, Y. Curr. Appl. Phys. 2007, 7, 611.
-
[55]
(47) Wu, S. Q.; Zhu, Z. Z.; Yang, Y.; Hou, Z. F. Trans. Nonferrous. Met. Soc. China 2009, 19, 182.
-
[56]
(48) Dompablo, M. E. A.; Armand, M.; Tarascon, J. M.; Amador, U. Electrochem. Commun. 2006, 8, 1292.
-
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